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MCAT Chemistry
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Subjects
:
mcat
,
science
Instructions:
Answer 50 questions in 15 minutes.
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Match each statement with the correct term.
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This is a study tool. The 3 wrong answers for each question are randomly chosen from answers to other questions. So, you might find at times the answers obvious, but you will see it re-enforces your understanding as you take the test each time.
1. Mixture of 2 or more substances that distills at a constant temperature and with constant composition - even though seperately the components have different boiling points
Ion product
Formula weight
effective nuclear charge
Azeotrope
2. The sum of the exponents in a rate law - where each exponent provides the reaction order with respect to its reactants
chemical reaction
Reaction order
Hydrogen bonding
actinide series
3. The tendency for an atom to attract electrons to itself when it is chemically combined with another element
Rate determining step
Planck's Constant
Atomic absorption Spectra
Electronegativity
4. A set of spectral lines that appear in the visible light region when a hydrogen atom undergoes a transition from energy levels n>2 to n=2.
Electronegativity
Group 7A
Balmer series
Effective nuclear charge
5. The number of atoms in exactly 12 g of pure 12c and equal to 6.022 x 10^23 is called
Effusion
Avagadros number
effective nuclear charge
gram equivalent weight
6. One - half of the distance between the center of identical atoms that are not bonded together. Since effective nuclear charge increases when moving from left to right each additional electron is pulled more strogly toward the nucleus.
atomic theory
Common ion effect
atomic radius
Percent yield
7. Orbitals of equal energy are each occupied by one electron before any orbital is occupied by a second electron - and all electrons in singly occupied orbitals must have the same spin
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8. Where half of the acid is neutralized by the base on a titration curveAn acid dissociation constant - Ka - (also known as acidity constant - or acid - ionization constant) is a quantitative measure of the strength of an acid in solution. It is the eq
Vapor pressure
Intermolecular forces
Half equivalence point
Formal Charge
9. (chemistry) a substance formed by chemical union of two or more elements or ingredients in definite proportion by weight
Theoretical yield
compound
Group 4A
heisenberg uncertainty principle
10. A chemical reaction involving the transfer of one or more electrons from one reactant to another; also called oxidation - reduction reaction.
redox reaction
Group 5A
Neutron
Strong acid
11. Acids defined as electron - pair acceptors and bases as electron - pair donors.
atomic theory
electromagnetic energy of photons emmited from electrons at ground state
Lewis definition
Molality
12. (physics) the smallest discrete quantity of some physical property that a system can possess (according to quantum theory) E=hf
quantum
subshell
Solubility Product Constant
Group 3A
13. A pair of equal and opposite electric charges or magnetic poles separated by a small distance
Dipole
Solute
Principle quantum number
Phase diagram
14. 4 valence electrons +4 - -4 ions. - Carbon Group can form covalent bonds with nonmetals. Only carbon forms strong pi bonds
Group 4A
d orbital
Emperical Formula
Pauli exclusion principle
15. Named after their cation and anion
empirical formula
ionic cmpound
Mass number
electron configuration
16. An atom or group of atoms that has a positive or negative charge
Ion
The bohr model
atomic radius
Half equivalence point
17. A naturally occurring or synthetic compound consisting of large molecules made up of a linked series of repeated simple monomers
gram equivalent weight
solvation
polymer
Rydberg constant
18. When a solute is dissolved in a solvent - it will dissociate until reaching an equilibrium point at which the rate of dissociation equals the rate of precipitation of the solute - regardless of any additional solute introduced into the mixture
Water dissociation Constant
Solution equilibrium
Henry's Law
Solubility Product Constant
19. The lowest allowable energy state of an atom
The bohr model
molecule
Ground state
Percent composition
20. Charge assigned to an atom in a molecule or polyatmic ion - calculated by (# valence electrons) - (# 1/2 bonding electrons) - (# nonbonding electrons). Molecules containing atoms with lower formal charges tend to be more stable than those with higher
lewis base
Formal Charge
pH
Chemical Kinetics
21. Property of the elements that can be predicted from the arrangement of the periodic table
redox reaction
STP
periodic trends
Effusion
22. The amount of a substance that contains as many particles as there are atoms in exactly 12g of carbon -12
effective nuclear charge
mole
law of constant composition
Neutron
23. Common definition of acids as proton (H+) donors and bases as proton acceptors
Covalent Bond
Bronsted - Lowry definition
energy state
Titration
24. A model of acids and bases which an acid is hydrogen ion donor and base is a hydrogen ion acceptor.
Theoretical yield
Rydberg constant
Bronsted Lowry
s orbital
25. The formation of one or more covalent bonds between an electron pair donor and an electron pair acceptor
Bronsted - Lowry definition
Lewis acid base reaction
Bronsted Lowry
azimuthal quantum number
26. The molar solubility of one salt is reduced when another salt - having a common ion is brought into the same solution
Combination Reaction
Common ion effect
Percent yield
angular momentum in the bohr model
27. The ratio of the actual yield to the theoretical yield for a chemical reaction expressed as a percentage; a measure of the efficiency of a reaction
Percent yield
Effective nuclear charge
sigma bond
Hydrogen bonding
28. Expression of auto - ionization of water into H+ and OH- at a certain temperature - given by the product of the ions' molar concentrations. Denoted by Kw and equal to 10-
Alkaline earths
Water dissociation Constant
Activation energy
Solute
29. A graph of pressure versus temperature that shows the conditions under which the phases of a substance exist
molecular weight
Lyman series
Phase diagram
Graham's Law
30. A set of frequencies of electromagnetic waves given off by atoms of an element; consists of a series of fine lines of individual colors
pi bonds
Group 7A
atomic emission spectrum
amorphous solid
31. When dipoles are dissolved in a solution where ions are present ions wil arrange themselves with the opposite charged end of the dipole.
Dispersion Forces
Raoult's Law
Ion dipole interactions
Bronsted - Lowry definition
32. Chalcogens - - Oxide O
Group 6A
periodic trends
Ground state
sigma bond
33. Systematic pairing of a deprotonated species (base) with its protonated form (conjugate acid). Conjugates appear on opposite sides of a chemical equation.
Group 5A
Conjugate acids and Bases
Group 6A
lewis base
34. A subdivision of an energy level in an atom. They are divided into orbitals.
lewis base
Dipole
subshell
Spin quantum number
35. Having characteristics of both an acid and a base and capable of reacting as either
electromagnetic energy of photons emmited from electrons at ground state
Half equivalence point
Group 4A
Amphoteric
36. An emperimentally determined mathmatical expression showing the rate of a reaction as a function of the concentration of its reactants
Titration
Nucleus
quanta
Rate law
37. The solubility of a gas in a liquid is directly proportional to the partial pressure of that gas on the surface of the liquid
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38. At a constant pressure - the volume of an ideal gas is directly proportinal to its temperature: V (a) T
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39. (chemistry) the sum of the relative atomic masses of the constituent atoms of a molecule
Rate determining step
Diffusion
molecular weight
pI
40. The molar amount of a solute that can dissolve in 1L of solvent until equilibrium - saturation - is reached
Percent composition
Molar solubility
decomposition reaction
Water dissociation Constant
41. Region in a molecule where atomic orbitals overlap - resulting in either a stable low - energy bonding orbital or an unstable high - energy antibonding orbital.
Solubility Product Constant
Formal Charge
mole
Molecular orbital
42. Set of spectral lines appearing in the UV region when a hydrogen atom undergoes a transition from energy levels n>1 to n=1.
Proton
Group 4A
Lyman series
Molarity
43. 1913 - Niels Bohr - said that electrons formed specific layers instead or random ones - said atoms atoms absorb and give off energy when the electrons move from one shell to another
The bohr model
Alkaline earths
Planck's Constant
theoretical yield
44. A chemical bond that involves sharing a pair of electrons between atoms in a molecule
Graham's Law
Covalent Bond
quantum
Diffusion
45. The pressure exerted by a vapor in equilibrium with its liquid or solid phase
Buffer
Rate law
Balmer series
Vapor pressure
46. The area of chemistry that is concerned with reaction rates and reaction mechanisms
electron affinity
Molality
STP
Chemical Kinetics
47. Redox reaction - in which the same species is both oxidized and reduced.
Planck's Constant
Bronsted - Lowry definition
ionic cmpound
Disproportionation
48. The center of the atom which contains the protons and neutrons; in cells - structure that contains the cell's genetic material (DNA) and controls the cell's activities
percent composition
actinide series
Nucleus
Lewis structure
49. The hypothetical equation showing only the species that is oxidized or reduced in a redox reaction and the correct number of electrons transferred between the species in the complete - balanced equation.
Intermolecular forces
Redox Half Reaction
Molar solubility
Molarity
50. An element in an 'A' group in the periodic table; as a group these elements display a wide range of physical and chemical properties. In their atoms - the s and p sublevels in the highest occupied energy level are partially filled
representative elements
Collision theory of chemical Kinetics
Arrhenius Definition
Group 5A
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