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MCAT Chemistry
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Subjects
:
mcat
,
science
Instructions:
Answer 50 questions in 15 minutes.
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Match each statement with the correct term.
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This is a study tool. The 3 wrong answers for each question are randomly chosen from answers to other questions. So, you might find at times the answers obvious, but you will see it re-enforces your understanding as you take the test each time.
1. Region in a molecule where atomic orbitals overlap - resulting in either a stable low - energy bonding orbital or an unstable high - energy antibonding orbital.
Rydberg constant
Acid dissociation constant
Molecular orbital
Noble gases
2. An uncharged molecule with a single unpaitred electron in its outer ring - very unstable - exists for only about 10 seconds
Free radical
Dispersion Forces
STP
law of constant composition
3. A chemical bond in which one atom loses an electron to form a positive ion and the other atom gains to electron to form a negative ion
Ionic Bond
Reaction mechanism
Diprotic Base
Bronsted Lowry
4. A fundamental constant - h - that relates the energy of light quanta to their frequency: h = 6.6 X 10^-34 joule
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5. A concentration unit of a solution expressed as moles of solute dissolved per liter of solution
lewis base
Alkaline earths
physical reaction
Molarity
6. Specifies the specific orbital in which the electron is most likely to be found. - Third quantum number - designated as ml. Describes a particular orbital within a subshell where an electron is very likely to be found. Possible values are integers in
percent composition
subshell
Magnetic quantum number
Group 2A
7. States that it is impossible to determine simultaneously both the position and momentum of an electron or any other particle
pi bonds
atomic radius
heisenberg uncertainty principle
Conjugate acids and Bases
8. Orbitals of equal energy are each occupied by one electron before any orbital is occupied by a second electron - and all electrons in singly occupied orbitals must have the same spin
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9. A physical property of a solution that depends on the number - but not the identity - of the disswolved solute particles; example properties include vapor pressure lowering - boiling point elevation - osmotic pressure - and frezzing point depression
electron affinity
Colligative properties
subshell
Balmer series
10. A naturally occurring or synthetic compound consisting of large molecules made up of a linked series of repeated simple monomers
redox reaction
polymer
London forces
Free radical
11. Structure that occurs when it is possible to draw two or more valid electron dot structures that have the same number of electron pairs for a molecule or ion
crystalline solid
empirical formula
Henderson Hasselbalch Equation
Resonance structure
12. The amount of a substance that contains as many particles as there are atoms in exactly 12g of carbon -12
mole
Reaction order
Dispersion Forces
indicator
13. An atom - radical - or molecule that has gained or lost one or more electrons and has a negative or positive charge
Solubility Product Constant
Magnetic quantum number
Ion
Neutron
14. The quantum number that has only two possible values - +1/2 and -1/2 - which indicate the two fundamental spin states of an electron in an orbital
Spin quantum number
Ion
indicator
Electronegativity
15. Having characteristics of both an acid and a base and capable of reacting as either
Ionization energy
Group 6A
Amphoteric
pH
16. 4 valence electrons +4 - -4 ions. - Carbon Group can form covalent bonds with nonmetals. Only carbon forms strong pi bonds
s orbital
Formal Charge
quanta
Group 4A
17. A structural formula in which electrons are represented by dots; dot pairs or dashes between two atomic symbols represent pairs in covalent bonds.
Lewis structure
Molecular orbital
Ion
Planck's Constant
18. PH=pka+log[base/acid] Used in titration based problems that relates the pH or pOH of a solution to the pK and the ratio of the dissociated species.
azimuthal quantum number
Lewis acid base reaction
Free radical
Henderson Hasselbalch Equation
19. An atom or group of atoms that has a positive or negative charge
Noble gases
Reaction order
Planck's Constant
Ion
20. Spectrum of certain absorbed wavelengths of light corresponding to an atom's spectrum of emitted frequencies of light. Unique to each element. AAS can be used to indentify an element.
Ion
Atomic absorption Spectra
molecular weight
Lewis acid base reaction
21. (physics) the smallest discrete quantity of some physical property that a system can possess (according to quantum theory) E=hf
Alkaline earths
quantum
Emperical Formula
Ionization energy
22. The hypothetical equation showing only the species that is oxidized or reduced in a redox reaction and the correct number of electrons transferred between the species in the complete - balanced equation.
crystalline solid
Acid dissociation constant
Group 4A
Redox Half Reaction
23. PH of a molecule at which it contains no net electric charge - isoelectric point.
Water dissociation Constant
pI
redox reaction
Network covalent
24. Resulting positive nuclear charge an outer electron senses after accounting for the shielding effect of inner core electrons. Abbreviated as Z(eff). Increases from left to right - and bottom to top on the Periodic Table.
Water dissociation Constant
The bohr model
Effective nuclear charge
Free radical
25. A reaction where a compound does Not change its molecular structure.
Group 5A
physical reaction
Effective nuclear charge
Spin quantum number
26. A horizontal row of elements in the periodic table
Molecular orbital
single displacement reaction
Period
Buffer
27. A chemical reaction involving the transfer of one or more electrons from one reactant to another; also called oxidation - reduction reaction.
s orbital
Theoretical yield
Redox Half Reaction
redox reaction
28. The amount of energy that reactants must absorb before a chemical reaction will start; also called free energy of activation.
subshell
Activation energy
electron affinity
Redox Half Reaction
29. Temperature is constant; effusion and temperature are proportional to the square root of their masses
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30. Rare earth element group (elements 58-71)
Half equivalence point
electron configuration
lathanide series
Intermolecular forces
31. Defined acids as subtsances that produced H ions in water - while bases produced OH ions. When they reacted together - H and OH neutralise to make water
Arrhenius Definition
Group 2A
electron affinity
Lewis acid base reaction
32. The intermolecular force in which a hydrogen atom that is bonded to a highly electronegative atom is attracted to an unshared pair of electrons of an electronegative atom in a nearby molecule
Solute
Alkaline earths
hydrogen bonding
theoretical yield
33. 5 different orbitals shaped like clover leaves and max electrons is 10
d orbital
und's rule
quantum numbers
Graham's Law
34. A graph of pressure versus temperature that shows the conditions under which the phases of a substance exist
Decomposition reaction
Concentration
Molar solubility
Phase diagram
35. The ways in which electrons are arranged in various orbitals around the nuclei of atoms
Rate law
actinide series
electron configuration
Ion dipole interactions
36. Sol - a chemical process in which solvent molecules and molecules or ions of the solute combine to form a compound
Group 6A
solvation
redox reaction
Charles and Gay Lussac's Law
37. An equilibrium expression used to measure weak - acid strength - given by the ratio of the product of the products' molar concentrations to the product of the reactants' molar concentrations - with each term raised to the power of its stoichiometric
Solvent
Azeotrope
Ground state
Acid dissociation constant
38. A definite stable energy that a physical system can have
Rydberg constant
energy state
Group 7A
Solvent
39. A reaction in which two or more substances combine to form a single substance A+B>>>>>>>C
atomic emission spectrum
Combination Reaction
und's rule
Ion dipole interactions
40. Simplest whole # ration of atoms in a compound
law of constant composition
Theoretical yield
Emperical Formula
chemical reaction
41. The amount of product that can be made in a chemical reaction based on the amount of limiting reactant
Buffer
Theoretical yield
polymer
electron affinity
42. A solution in which water is the solvent
Electronegativity
Molality
Common ion effect
Aqueous Solution
43. Solids in which the particles are arranged in a repeating - 3- D pattern - has a specific melting point - classified as ionic network covalent - metallic or molecular.
Triple point
crystalline solid
Lewis structure
d orbital
44. Gram equivalent weight of solute per liter of solution - often denoted by N.
Decomposition reaction
pI
Charles and Gay Lussac's Law
Normality
45. Play- by- play showing the individual steps of a reaction - including the formation and destruction of any reaction intermediates that may occur.
Reaction mechanism
Half equivalence point
Henderson Hasselbalch Equation
crystalline solid
46. A subdivision of an energy level in an atom. They are divided into orbitals.
subshell
Noble gases
redox reaction
Diffusion
47. At a constant pressure - the volume of an ideal gas is directly proportinal to its temperature: V (a) T
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48. The average distance between the nuclei of two bonded atoms
Normality
bond length
Noble gases
electromagnetic energy of photons emmited from electrons at ground state
49. Nh/2p The angular momentum changes only in discete amounts with respect to the quantum number. Also E=- R_h/n^2
angular momentum in the bohr model
pI
Group 1A
redox reaction
50. The process by which a gas escapes from one container to another at lower pressure through a tiny hole in the container.
Aqueous Solution
Proton
Effusion
molecular weight
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