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MCAT Chemistry
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Subjects
:
mcat
,
science
Instructions:
Answer 50 questions in 15 minutes.
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Match each statement with the correct term.
Don't refresh. All questions and answers are randomly picked and ordered every time you load a test.
This is a study tool. The 3 wrong answers for each question are randomly chosen from answers to other questions. So, you might find at times the answers obvious, but you will see it re-enforces your understanding as you take the test each time.
1. The intermolecular force in which a hydrogen atom that is bonded to a highly electronegative atom is attracted to an unshared pair of electrons of an electronegative atom in a nearby molecule
Network covalent
periodic trends
Amphoteric
hydrogen bonding
2. Product of the molar concentrations of dissociated ions in solution at saturation - where each ion is raised to the power of its stoichiometric coefficient. Denoted Ksp.
Henderson Hasselbalch Equation
Solubility Product Constant
Group 7A
Group 6A
3. A physical property of a solution that depends on the number - but not the identity - of the disswolved solute particles; example properties include vapor pressure lowering - boiling point elevation - osmotic pressure - and frezzing point depression
Disproportionation
periodic trends
Lewis acid base reaction
Colligative properties
4. The amount of energy that reactants must absorb before a chemical reaction will start; also called free energy of activation.
Concentration
pH
Activation energy
Alkaline earths
5. A measured amount of a solution of unknown concentration is added to a known volume of a second solution until the reaction between them is just complete
Activation energy
Combination Reaction
Titration
Rate determining step
6. Structure that occurs when it is possible to draw two or more valid electron dot structures that have the same number of electron pairs for a molecule or ion
Solute
Reaction order
Dipole Dipole interaction
Resonance structure
7. The tendency for an atom to attract electrons to itself when it is chemically combined with another element
electromagnetic energy of photons emmited from electrons at ground state
Electronegativity
Rydberg constant
effective nuclear charge
8. Systematic pairing of a deprotonated species (base) with its protonated form (conjugate acid). Conjugates appear on opposite sides of a chemical equation.
polymer
Conjugate acids and Bases
Colligative properties
electron affinity
9. The formation of one or more covalent bonds between an electron pair donor and an electron pair acceptor
lewis base
Lewis acid base reaction
Le chateliers Principle
Henderson Hasselbalch Equation
10. A reaction where a compound does Not change its molecular structure.
physical reaction
London forces
molecular weight
decomposition reaction
11. A subdivision of an energy level in an atom. They are divided into orbitals.
Ground state
Amphoteric
subshell
London forces
12. A horizontal row of elements in the periodic table
Decomposition reaction
Percent yield
Period
law of constant composition
13. Solids in which the particles are arranged in a repeating - 3- D pattern - has a specific melting point - classified as ionic network covalent - metallic or molecular.
Noble gases
mole
molecular weight
crystalline solid
14. A reaction in which two or more substances combine to form a single substance A+B>>>>>>>C
Reaction order
periodic trends
compound
Combination Reaction
15. An acid that will completely dissociate in aqueous solution - like HCl - HI - HClO4 HBr.
Lyman series
Dipole Dipole interaction
Combination Reaction
Strong acid
16. A chemical bond that involves sharing a pair of electrons between atoms in a molecule
Normality
physical reaction
Intermolecular forces
Covalent Bond
17. A bond formed when two atomic orbitals combine to form a molecular orbital that is symmetrical around the axis connecting the two atomic nuclei
Solvent
Henry's Law
sigma bond
quanta
18. The ways in which electrons are arranged in various orbitals around the nuclei of atoms
electron configuration
Solute
Principle quantum number
Combination Reaction
19. When a solute is dissolved in a solvent - it will dissociate until reaching an equilibrium point at which the rate of dissociation equals the rate of precipitation of the solute - regardless of any additional solute introduced into the mixture
Atomic weight
Ion
Solution equilibrium
Covalent Bond
20. Second quantum number - designated by the letter 'l.' This 'angular momentum' refers to the subshells within each principle quantum energy level. It can take on the value of an integer in the 0 to (n -1) range. The four subshellscorresponding to l=0
azimuthal quantum number
Group 4A
Effective nuclear charge
s orbital
21. A definite stable energy that a physical system can have
quantum numbers
energy state
Neutron
Henderson Hasselbalch Equation
22. The intermolecular force in which a hydrogen atom that is bonded to a highly electronegative atom is attracted to an unshared pair of electrons of an electronegative atom in a nearby molecule
molecular weight
Hydrogen bonding
Free radical
Octet Rule
23. An emperimentally determined mathmatical expression showing the rate of a reaction as a function of the concentration of its reactants
Bronsted Lowry
Rate law
law of constant composition
Equivalence point
24. Property of the elements that can be predicted from the arrangement of the periodic table
pi bonds
STP
Halogens
periodic trends
25. A graph of pressure versus temperature that shows the conditions under which the phases of a substance exist
Phase diagram
Hydrogen bonding
Avagadros number
Alkaline earths
26. The maximum amount of product that can be produced from a given amount of reactant
Buffer
Chemical Kinetics
Diprotic Base
theoretical yield
27. An atom or group of atoms that has a positive or negative charge
Ion
Formal Charge
polymer
Octet Rule
28. PH=pka+log[base/acid] Used in titration based problems that relates the pH or pOH of a solution to the pK and the ratio of the dissociated species.
transition elements
electromagnetic energy of photons emmited from electrons at ground state
bond energy
Henderson Hasselbalch Equation
29. The weight in grams of compound that can be substituted by 1 atom of Hydrogen. GEW = MW / # of acidic Hyrdogens
Molality
Ground state
electromagnetic energy of photons emmited from electrons at ground state
gram equivalent weight
30. (chemistry) separation of a substance into two or more substances that may differ from each other and from the original substance
single displacement reaction
decomposition reaction
Covalent Bond
lewis base
31. 2.18 x 10^-18 J/electron
decomposition reaction
Henderson Hasselbalch Equation
Balmer series
Rydberg constant
32. Any sample of a given compound will contain the same elements in the identical mass ratio.
Amphoteric
law of constant composition
Octet Rule
Network covalent
33. Two or more atoms held together by covalent bonds
Percent yield
molecule
Diprotic Base
empirical formula
34. A set of frequencies of electromagnetic waves given off by atoms of an element; consists of a series of fine lines of individual colors
atomic emission spectrum
Principle quantum number
Percent yield
Solvent
35. Sol - a chemical process in which solvent molecules and molecules or ions of the solute combine to form a compound
solvation
electrolysis
Group 6A
Le chateliers Principle
36. A set of spectral lines that appear in the visible light region when a hydrogen atom undergoes a transition from energy levels n>2 to n=2.
Balmer series
Henderson Hasselbalch Equation
Emperical Formula
Group 6A
37. Sum of all the masses - in AMU - present in one molecule of a molecular compound.
Formula weight
Triple point
Ion dipole interactions
Ion
38. The amount of a substance that contains as many particles as there are atoms in exactly 12g of carbon -12
sigma bond
mole
periodic trends
Ionization energy
39. Large molecular structures - strong covalent bonding - share qualities of IONIC And COVALENT
Network covalent
redox reaction
bond length
gram equivalent weight
40. 5 valence electrons -3 ions - Nitride N
Spin quantum number
Equilibrium
single displacement reaction
Group 5A
41. A structural formula in which electrons are represented by dots; dot pairs or dashes between two atomic symbols represent pairs in covalent bonds.
Lewis structure
Buffer
Water dissociation Constant
quantum
42. A representation of a displacement reaction showing only the reactive species and omitting the spectator ions.
Net ionic equation
amorphous solid
Charles and Gay Lussac's Law
effective nuclear charge
43. Theory stating that the rate of a reaction is directly proportional to the number of collisions that take place between reactants per second.
Collision theory of chemical Kinetics
Group 7A
Molarity
Network covalent
44. The quantum number that has only two possible values - +1/2 and -1/2 - which indicate the two fundamental spin states of an electron in an orbital
Combination Reaction
Magnetic quantum number
Molar solubility
Spin quantum number
45. The process by which one or more substances change to produce one or more different substances
chemical reaction
Lyman series
law of constant composition
Magnetic quantum number
46. The area of chemistry that is concerned with reaction rates and reaction mechanisms
Phase diagram
Intermolecular forces
Chemical Kinetics
Dipole Dipole interaction
47. States that if a stress is applied to a system at equilibrium - the system shifts in the direction that relieves the stress.
atomic radius
Le chateliers Principle
Charles and Gay Lussac's Law
pI
48. A subatomic particle that has a positive charge and that is found in the nucleus of an atom Charge of +1 and mass of 1.0073 amu
gram equivalent weight
Bronsted Lowry
Proton
Strong acid
49. The weak attractive forces between molecules resulting from the small - instantaneous dipoles that occur because of the varying positions of the electrons during their motion about nuclei
single displacement reaction
London forces
Redox Half Reaction
Chemical Kinetics
50. Have the shape of a sphere - with the center of the sphere at the nucleus; completely symmetrical along all axes; 1s orbital is spherically symmetric and has no nodes; 2s orbital is also spherical but contains a node and is higher in energy
Molecular orbital
Noble gases
Diffusion
s orbital
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