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MCAT Chemistry
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Subjects
:
mcat
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science
Instructions:
Answer 50 questions in 15 minutes.
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Match each statement with the correct term.
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1. One - half the distance between the nuclei of two atoms of the same element when the atoms are joined
electromagnetic energy of photons emmited from electrons at ground state
quanta
Lewis acid base reaction
atomic radius
2. A set of frequencies of electromagnetic waves given off by atoms of an element; consists of a series of fine lines of individual colors
Solution equilibrium
Molar solubility
Disproportionation
atomic emission spectrum
3. A chemical bond in which one atom loses an electron to form a positive ion and the other atom gains to electron to form a negative ion
Redox Half Reaction
Ionic Bond
The bohr model
Concentration
4. Alkali metals: highly reactive - therefore always compounds. - 1 valence electron +1 ion - Hydrogen H? - Lithium Li? - Sodium Na? - Potassium K? - Rubidium Rb? - Cesium Cs?
Normality
Ionization energy
Group 1A
Ion
5. The quantum number that has only two possible values - +1/2 and -1/2 - which indicate the two fundamental spin states of an electron in an orbital
Resonance structure
Spin quantum number
Dispersion Forces
Aqueous Solution
6. The area of chemistry that is concerned with reaction rates and reaction mechanisms
Lewis definition
Chemical Kinetics
Henderson Hasselbalch Equation
mole
7. The tendency for an atom to attract electrons to itself when it is chemically combined with another element
Formula weight
Electronegativity
Azeotrope
subshell
8. A chemical formula showing the ratio of elements in a compound rather than the total number of atoms
Hydrogen bonding
empirical formula
azimuthal quantum number
Equilibrium
9. Atoms react by gaining or losing electrons so as to acquire the stable electron structure of a noble gas - usually eight valence electrons
Nonpolar covalent bond
Aqueous Solution
Octet Rule
Normality
10. PH=pka+log[base/acid] Used in titration based problems that relates the pH or pOH of a solution to the pK and the ratio of the dissociated species.
Halogens
Henderson Hasselbalch Equation
Equlibrium constant
Intermolecular forces
11. 4 valence electrons +4 - -4 ions. - Carbon Group can form covalent bonds with nonmetals. Only carbon forms strong pi bonds
Vapor pressure
theoretical yield
Amphoteric
Group 4A
12. (chemistry) a substance formed by chemical union of two or more elements or ingredients in definite proportion by weight
Reaction mechanism
energy state
compound
Rate law
13. Sol - a chemical process in which solvent molecules and molecules or ions of the solute combine to form a compound
Ion product
Disproportionation
Triple point
solvation
14. Solids in which the particles are arranged in a repeating - 3- D pattern - has a specific melting point - classified as ionic network covalent - metallic or molecular.
Solute
atomic radius
crystalline solid
pI
15. Orbitals of equal energy are each occupied by one electron before any orbital is occupied by a second electron - and all electrons in singly occupied orbitals must have the same spin
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16. The amount of energy that reactants must absorb before a chemical reaction will start; also called free energy of activation.
theoretical yield
Activation energy
compound
Henry's Law
17. An element in an 'A' group in the periodic table; as a group these elements display a wide range of physical and chemical properties. In their atoms - the s and p sublevels in the highest occupied energy level are partially filled
chemical reaction
gram equivalent weight
Proton
representative elements
18. The reaction of the ions that characterize acids and the ions that characterize bases to form water molecules and a salt
Neutralization reaction
Solution equilibrium
Titration
heisenberg uncertainty principle
19. An atom or group of atoms that has a positive or negative charge
Arrhenius Definition
Disproportionation
Aqueous Solution
Ion
20. A set of spectral lines that appear in the visible light region when a hydrogen atom undergoes a transition from energy levels n>2 to n=2.
Ion dipole interactions
quantum
Balmer series
physical reaction
21. The point during a titration when the number of H+ ions and OH- ions are equal. This is at the middle of the steepest part of the titration curve.
Mass number
Nonpolar covalent bond
amorphous solid
Equivalence point
22. A chemical reaction involving the transfer of one or more electrons from one reactant to another; also called oxidation - reduction reaction.
crystalline solid
redox reaction
Amphoteric
Alkaline earths
23. Process by which molecules tend to move from an area where they are more concentrated to an area where they are less concentrated
Electronegativity
quanta
Diffusion
Octet Rule
24. (physics) the smallest discrete quantity of some physical property that a system can possess (according to quantum theory) E=hf
quantum
Proton
Effective nuclear charge
polymer
25. The center of the atom which contains the protons and neutrons; in cells - structure that contains the cell's genetic material (DNA) and controls the cell's activities
Group 5A
physical reaction
Nucleus
Bronsted - Lowry definition
26. An equilibrium expression used to measure weak - acid strength - given by the ratio of the product of the products' molar concentrations to the product of the reactants' molar concentrations - with each term raised to the power of its stoichiometric
Diprotic Base
Nonpolar covalent bond
Acid dissociation constant
single displacement reaction
27. 2.18 x 10^-18 J/electron
Rydberg constant
Equivalence point
quantum
Group 1A
28. The solubility of a gas in a liquid is directly proportional to the partial pressure of that gas on the surface of the liquid
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29. The maximum amount of product that can be produced from a given amount of reactant
Network covalent
theoretical yield
Solvent
hydrogen bonding
30. Property of the elements that can be predicted from the arrangement of the periodic table
Diprotic Base
Molar solubility
Half equivalence point
periodic trends
31. Have three valance electrons. In certain instances - some elements will loose three electrons - but they will also share electrons with another element to attain stability.
STP
Diffusion
atomic emission spectrum
Group 3A
32. Rare earth element group (elements 58-71)
Combination Reaction
Redox Half Reaction
Planck's Constant
lathanide series
33. Defined acids as subtsances that produced H ions in water - while bases produced OH ions. When they reacted together - H and OH neutralise to make water
Network covalent
actinide series
Arrhenius Definition
sigma bond
34. A reaction in which two or more substances combine to form a single substance A+B>>>>>>>C
Combination Reaction
Concentration
Bronsted Lowry
Lewis definition
35. Gram equivalent weight of solute per liter of solution - often denoted by N.
indicator
Molecular orbital
Normality
quantum
36. The process by which one or more substances change to produce one or more different substances
Rate determining step
Normality
Solvent
chemical reaction
37. Contains nonmetals that are non - reactive. Full outermost energy level except helium which has 2.
electron affinity
molecular weight
Noble gases
ionic cmpound
38. A solid made up of particles that are not arranged in a regular pattern.
Pauli exclusion principle
Ionization energy
amorphous solid
Phase diagram
39. The energy required to remove an electron from a gaseous atom; generally increases in moving from left - to - right across a period and decreases in moving down a group
Acid dissociation constant
single displacement reaction
Ionization energy
sigma bond
40. A chemical reaction involving the transfer of one or more electrons from one reactant to another; also called oxidation - reduction reaction.
Net ionic equation
Combination Reaction
redox reaction
Intermolecular forces
41. (chemistry) any theory in which all matter is composed of tiny discrete finite indivisible indestructible particles
Triple point
Group 7A
Formula weight
atomic theory
42. Sum of all the masses - in AMU - present in one molecule of a molecular compound.
Strong acid
Decomposition reaction
Atomic weight
Formula weight
43. A bond formed when two atomic orbitals combine to form a molecular orbital that is symmetrical around the axis connecting the two atomic nuclei
Neutron
Group 3A
sigma bond
atomic radius
44. The molar amount of a solute that can dissolve in 1L of solvent until equilibrium - saturation - is reached
Molar solubility
Lyman series
Rydberg constant
redox reaction
45. The point on a phase diagram that represents the only set of conditions at which all three phases exist in equilibrium with one another
Lyman series
Free radical
Amphoteric
Triple point
46. When a solute is dissolved in a solvent - it will dissociate until reaching an equilibrium point at which the rate of dissociation equals the rate of precipitation of the solute - regardless of any additional solute introduced into the mixture
Combination Reaction
Solution equilibrium
Redox Half Reaction
gram equivalent weight
47. The quantum number that indicates the main energy level occupied by the electron. Can theoretically take on any positive interger. Denoted by the letter n.
Principle quantum number
Mass number
percent composition
STP
48. Second quantum number - designated by the letter 'l.' This 'angular momentum' refers to the subshells within each principle quantum energy level. It can take on the value of an integer in the 0 to (n -1) range. The four subshellscorresponding to l=0
Dipole Dipole interaction
molecule
single displacement reaction
azimuthal quantum number
49. An emperimentally determined mathmatical expression showing the rate of a reaction as a function of the concentration of its reactants
Lewis structure
Lewis acid base reaction
Rate law
Water dissociation Constant
50. Spectrum of certain absorbed wavelengths of light corresponding to an atom's spectrum of emitted frequencies of light. Unique to each element. AAS can be used to indentify an element.
Atomic absorption Spectra
Rate determining step
Water dissociation Constant
representative elements
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