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MCAT Chemistry
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Subjects
:
mcat
,
science
Instructions:
Answer 50 questions in 15 minutes.
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Match each statement with the correct term.
Don't refresh. All questions and answers are randomly picked and ordered every time you load a test.
This is a study tool. The 3 wrong answers for each question are randomly chosen from answers to other questions. So, you might find at times the answers obvious, but you will see it re-enforces your understanding as you take the test each time.
1. An emperimentally determined mathmatical expression showing the rate of a reaction as a function of the concentration of its reactants
Rate law
atomic emission spectrum
periodic trends
Percent yield
2. The area of chemistry that is concerned with reaction rates and reaction mechanisms
transition elements
percent composition
Chemical Kinetics
bond length
3. Nh/2p The angular momentum changes only in discete amounts with respect to the quantum number. Also E=- R_h/n^2
The bohr model
electromagnetic energy of photons emmited from electrons at ground state
Raoult's Law
angular momentum in the bohr model
4. Valence Shell Electron Pair Repulsion theory - stating that the three - dimensional molecular geometry about some central atom is determined by the elctronic repulsion between its bonding and nonbonding electron pairs.
VSEPR
Spin quantum number
pI
pH
5. 1913 - Niels Bohr - said that electrons formed specific layers instead or random ones - said atoms atoms absorb and give off energy when the electrons move from one shell to another
ionic cmpound
Rate law
The bohr model
electromagnetic energy of photons emmited from electrons at ground state
6. A bond formed when two atomic orbitals combine to form a molecular orbital that is symmetrical around the axis connecting the two atomic nuclei
Free radical
sigma bond
Reaction mechanism
law of constant composition
7. (chemistry) a substance that changes color to indicate the presence of some ion or substance
indicator
Lewis acid base reaction
electron configuration
Ionization energy
8. A fundamental constant - h - that relates the energy of light quanta to their frequency: h = 6.6 X 10^-34 joule
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9. Structure that occurs when it is possible to draw two or more valid electron dot structures that have the same number of electron pairs for a molecule or ion
Free radical
Molality
Resonance structure
London forces
10. Region in a molecule where atomic orbitals overlap - resulting in either a stable low - energy bonding orbital or an unstable high - energy antibonding orbital.
Molecular orbital
Nonpolar covalent bond
Solvent
Chemical Kinetics
11. 4 valence electrons +4 - -4 ions. - Carbon Group can form covalent bonds with nonmetals. Only carbon forms strong pi bonds
Electrolyte
quantum
Solution equilibrium
Group 4A
12. One - half the distance between the nuclei of two atoms of the same element when the atoms are joined
Common ion effect
Titration
atomic radius
Pauli exclusion principle
13. Attractions between molecules caused by the electron motion on one molecule affecting the electron motion on the other through electrical forces; these are the weakest interactions between molecules
Balmer series
Net ionic equation
angular momentum in the bohr model
Dispersion Forces
14. A set of frequencies of electromagnetic waves given off by atoms of an element; consists of a series of fine lines of individual colors
redox reaction
Equivalence point
atomic emission spectrum
Network covalent
15. States that if a stress is applied to a system at equilibrium - the system shifts in the direction that relieves the stress.
Le chateliers Principle
Reaction order
Nonpolar covalent bond
London forces
16. A naturally occurring or synthetic compound consisting of large molecules made up of a linked series of repeated simple monomers
pI
polymer
Rate law
Planck's Constant
17. The tendency for an atom to attract electrons to itself when it is chemically combined with another element
Solute
Electrolyte
percent composition
Electronegativity
18. The ways in which electrons are arranged in various orbitals around the nuclei of atoms
electron configuration
theoretical yield
Redox Half Reaction
Formal Charge
19. The number of atoms in exactly 12 g of pure 12c and equal to 6.022 x 10^23 is called
Phase diagram
Chemical Kinetics
Avagadros number
Electronegativity
20. Theory stating that the rate of a reaction is directly proportional to the number of collisions that take place between reactants per second.
Collision theory of chemical Kinetics
Triple point
Equlibrium constant
Effusion
21. A horizontal row of elements in the periodic table
STP
Common ion effect
quanta
Period
22. A graph of pressure versus temperature that shows the conditions under which the phases of a substance exist
Acid dissociation constant
decomposition reaction
Phase diagram
Graham's Law
23. The sum of the exponents in a rate law - where each exponent provides the reaction order with respect to its reactants
Reaction order
Nucleus
sigma bond
Magnetic quantum number
24. The hypothetical equation showing only the species that is oxidized or reduced in a redox reaction and the correct number of electrons transferred between the species in the complete - balanced equation.
Planck's Constant
Ground state
Dipole Dipole interaction
Redox Half Reaction
25. A concentration unit of a solution expressed as moles of solute dissolved per liter of solution
Molarity
Atomic weight
physical reaction
Combination Reaction
26. Property of the elements that can be predicted from the arrangement of the periodic table
Henderson Hasselbalch Equation
Buffer
percent composition
periodic trends
27. A measured amount of a solution of unknown concentration is added to a known volume of a second solution until the reaction between them is just complete
Titration
compound
Amphoteric
Strong acid
28. Sum of the protons and neutrons in an element often denoted by the letter A
Ionic Bond
representative elements
Mass number
Ion
29. Redox reaction - in which the same species is both oxidized and reduced.
Arrhenius Definition
Spin quantum number
Disproportionation
Water dissociation Constant
30. The process by which one or more substances change to produce one or more different substances
molecular weight
Ionic Bond
chemical reaction
effective nuclear charge
31. Charge assigned to an atom in a molecule or polyatmic ion - calculated by (# valence electrons) - (# 1/2 bonding electrons) - (# nonbonding electrons). Molecules containing atoms with lower formal charges tend to be more stable than those with higher
Normality
Formal Charge
ionic cmpound
subshell
32. Sol - a chemical process in which solvent molecules and molecules or ions of the solute combine to form a compound
solvation
pH
Spin quantum number
Combination Reaction
33. Process by which molecules tend to move from an area where they are more concentrated to an area where they are less concentrated
Magnetic quantum number
Dipole
Halogens
Diffusion
34. A physical property of a solution that depends on the number - but not the identity - of the disswolved solute particles; example properties include vapor pressure lowering - boiling point elevation - osmotic pressure - and frezzing point depression
Colligative properties
Magnetic quantum number
Ground state
Lewis acid base reaction
35. The solubility of a gas in a liquid is directly proportional to the partial pressure of that gas on the surface of the liquid
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36. A reaction in which atoms of one element take the place of atoms of another element in a compound
Molality
Neutralization reaction
Lyman series
single displacement reaction
37. Slightly less reactive than alkali metals - comprise group II
molecular weight
lewis base
Group 3A
Alkaline earths
38. The average distance between the nuclei of two bonded atoms
lewis base
bond length
Hydrogen bonding
redox reaction
39. Alkali metals: highly reactive - therefore always compounds. - 1 valence electron +1 ion - Hydrogen H? - Lithium Li? - Sodium Na? - Potassium K? - Rubidium Rb? - Cesium Cs?
Ionization energy
Nucleus
und's rule
Group 1A
40. Resulting positive nuclear charge an outer electron senses after accounting for the shielding effect of inner core electrons. Abbreviated as Z(eff). Increases from left to right - and bottom to top on the Periodic Table.
Pauli exclusion principle
Effective nuclear charge
Halogens
Electrolyte
41. In a solution - the substance that dissolves in the solvent
quantum
Solvent
pH
Solute
42. The point on a phase diagram that represents the only set of conditions at which all three phases exist in equilibrium with one another
crystalline solid
Decomposition reaction
Triple point
law of constant composition
43. Product of the molar concentrations of dissociated ions in solution at any point in the reaction other than equilibrium or saturation - where each ion is raised to the power of its stoichiometric coefficient. Denoted IP.
Phase diagram
Ion product
azimuthal quantum number
Activation energy
44. An element in an 'A' group in the periodic table; as a group these elements display a wide range of physical and chemical properties. In their atoms - the s and p sublevels in the highest occupied energy level are partially filled
Group 7A
Half equivalence point
representative elements
Henderson Hasselbalch Equation
45. A structural formula in which electrons are represented by dots; dot pairs or dashes between two atomic symbols represent pairs in covalent bonds.
Lewis structure
Mass number
Intermolecular forces
The bohr model
46. Tells you how much solute is present compared to the amount of solvent
Rate determining step
Concentration
Ion
Lewis structure
47. Sum of all the masses - in AMU - present in one molecule of a molecular compound.
Effective nuclear charge
Formula weight
angular momentum in the bohr model
The bohr model
48. Large molecular structures - strong covalent bonding - share qualities of IONIC And COVALENT
energy state
Intermolecular forces
single displacement reaction
Network covalent
49. Gram equivalent weight of solute per liter of solution - often denoted by N.
Covalent Bond
atomic theory
Normality
Dipole Dipole interaction
50. Keq describes the ratio of product concentration to reactant concentration - with each raised to the power corresponding ot its coefficient ion in the balanced equation
Spin quantum number
Equlibrium constant
pI
Water dissociation Constant
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