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MCAT Chemistry
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Subjects
:
mcat
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science
Instructions:
Answer 50 questions in 15 minutes.
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Match each statement with the correct term.
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This is a study tool. The 3 wrong answers for each question are randomly chosen from answers to other questions. So, you might find at times the answers obvious, but you will see it re-enforces your understanding as you take the test each time.
1. (physics) the smallest discrete quantity of some physical property that a system can possess (according to quantum theory) E=hf
Henry's Law
quantum
Activation energy
STP
2. (chemistry) a substance that changes color to indicate the presence of some ion or substance
Azeotrope
indicator
Avagadros number
Group 5A
3. Product of the molar concentrations of dissociated ions in solution at saturation - where each ion is raised to the power of its stoichiometric coefficient. Denoted Ksp.
Molecular orbital
electrolysis
Titration
Solubility Product Constant
4. A representation of a displacement reaction showing only the reactive species and omitting the spectator ions.
Decomposition reaction
Avagadros number
Net ionic equation
Rate law
5. Tells you how much solute is present compared to the amount of solvent
Phase diagram
molecular weight
Concentration
Percent yield
6. Sum of the protons and neutrons in an element often denoted by the letter A
hydrogen bonding
Le chateliers Principle
Balmer series
Mass number
7. An emperimentally determined mathmatical expression showing the rate of a reaction as a function of the concentration of its reactants
Rate law
quantum
Neutron
electron affinity
8. Process by which molecules tend to move from an area where they are more concentrated to an area where they are less concentrated
Octet Rule
Decomposition reaction
Collision theory of chemical Kinetics
Diffusion
9. The molar solubility of one salt is reduced when another salt - having a common ion is brought into the same solution
Titration
Common ion effect
Combination Reaction
Avagadros number
10. Set of spectral lines appearing in the UV region when a hydrogen atom undergoes a transition from energy levels n>1 to n=1.
Titration
Ionic Bond
Spin quantum number
Lyman series
11. A naturally occurring or synthetic compound consisting of large molecules made up of a linked series of repeated simple monomers
Effective nuclear charge
Equlibrium constant
polymer
Period
12. The center of the atom which contains the protons and neutrons; in cells - structure that contains the cell's genetic material (DNA) and controls the cell's activities
Nucleus
Ion
Strong acid
Diprotic Base
13. Any sample of a given compound will contain the same elements in the identical mass ratio.
Lewis acid base reaction
Solute
Rate law
law of constant composition
14. The nuclear charge experienced by the outermost electrons of an atom (actual charge minus the shielding caused by inner shells: Z- eff)
effective nuclear charge
polymer
heisenberg uncertainty principle
Rate law
15. A fundamental constant - h - that relates the energy of light quanta to their frequency: h = 6.6 X 10^-34 joule
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16. Attractive and repulsive forces between molecules that are weaker than forces within molecules.
Intermolecular forces
heisenberg uncertainty principle
actinide series
Phase diagram
17. The amount of energy that reactants must absorb before a chemical reaction will start; also called free energy of activation.
subshell
hydrogen bonding
Activation energy
Balmer series
18. When polar molecules orient themselves such that the positive region of one molecule is close to the negative region of another molecule.
Dipole Dipole interaction
Raoult's Law
Formula weight
s orbital
19. Structure that occurs when it is possible to draw two or more valid electron dot structures that have the same number of electron pairs for a molecule or ion
Resonance structure
atomic radius
s orbital
Alkaline earths
20. The tendency for an atom to attract electrons to itself when it is chemically combined with another element
percent composition
Chemical Kinetics
Lewis structure
Electronegativity
21. An atom - radical - or molecule that has gained or lost one or more electrons and has a negative or positive charge
electron configuration
Ion
Rydberg constant
Redox Half Reaction
22. The vapor pressure of solution is the product of the mole fraction of the solvent and the vapor pressure of the pure solvent. P_a=X_aP_total
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23. The area of chemistry that is concerned with reaction rates and reaction mechanisms
Group 1A
Percent yield
Ion dipole interactions
Chemical Kinetics
24. Sol - a chemical process in which solvent molecules and molecules or ions of the solute combine to form a compound
solvation
lewis base
Combination Reaction
Triple point
25. A chemical reaction involving the transfer of one or more electrons from one reactant to another; also called oxidation - reduction reaction.
Rate law
indicator
redox reaction
Ion
26. The slowest elementary step which is the limit for the rate of the other steps
solvation
Molarity
Rate determining step
pH
27. Halogens; ns2np5 - - 2nd most reactive group - The Halogens; very active because of need to fill; form -1 ions; 7 electrons in valence shell; tend to form salts with elements from groups 1A and 2A
Nonpolar covalent bond
Equlibrium constant
Molality
Group 7A
28. A reaction in which two or more substances combine to form a single substance A+B>>>>>>>C
Bronsted Lowry
Ionization energy
electrolysis
Combination Reaction
29. The intermolecular force in which a hydrogen atom that is bonded to a highly electronegative atom is attracted to an unshared pair of electrons of an electronegative atom in a nearby molecule
Pauli exclusion principle
Group 4A
hydrogen bonding
Decomposition reaction
30. No two electrons or protons or neutrons in a given system can be in states characterized by the same set of quantum numbers
Pauli exclusion principle
Decomposition reaction
hydrogen bonding
Arrhenius Definition
31. One - half the distance between the nuclei of two atoms of the same element when the atoms are joined
atomic radius
Molecular orbital
Arrhenius Definition
Spin quantum number
32. Contains nonmetals that are non - reactive. Full outermost energy level except helium which has 2.
law of constant composition
physical reaction
Henry's Law
Noble gases
33. Numbers that specify the properties of atomic orbitals and of their electrons
Phase diagram
Half equivalence point
quantum numbers
Collision theory of chemical Kinetics
34. Keq describes the ratio of product concentration to reactant concentration - with each raised to the power corresponding ot its coefficient ion in the balanced equation
Equlibrium constant
Emperical Formula
The bohr model
electron affinity
35. An uncharged molecule with a single unpaitred electron in its outer ring - very unstable - exists for only about 10 seconds
Henry's Law
Free radical
Bronsted Lowry
Net ionic equation
36. The number of atoms in exactly 12 g of pure 12c and equal to 6.022 x 10^23 is called
Avagadros number
Buffer
Noble gases
Vapor pressure
37. Standard Temperature and Pressure. 273 Kelvin (0 Celsius) - 1 atmosphere (760 torr - 760 kPA).
STP
Ground state
Molar solubility
Electronegativity
38. The process by which one or more substances change to produce one or more different substances
London forces
polymer
chemical reaction
Equlibrium constant
39. A structural formula in which electrons are represented by dots; dot pairs or dashes between two atomic symbols represent pairs in covalent bonds.
quantum
Lewis structure
Hydrogen bonding
Noble gases
40. Sum of all the masses - in AMU - present in one molecule of a molecular compound.
Formula weight
Resonance structure
Lewis definition
Dipole
41. Specifies the specific orbital in which the electron is most likely to be found. - Third quantum number - designated as ml. Describes a particular orbital within a subshell where an electron is very likely to be found. Possible values are integers in
Ground state
Magnetic quantum number
polymer
Planck's Constant
42. A set of spectral lines that appear in the visible light region when a hydrogen atom undergoes a transition from energy levels n>2 to n=2.
Amphoteric
Balmer series
Effective nuclear charge
Ion product
43. Nh/2p The angular momentum changes only in discete amounts with respect to the quantum number. Also E=- R_h/n^2
Lewis definition
Rate law
angular momentum in the bohr model
sigma bond
44. E=hc/?
effective nuclear charge
percent composition
electromagnetic energy of photons emmited from electrons at ground state
Covalent Bond
45. A definite stable energy that a physical system can have
Nucleus
Reaction mechanism
ionic cmpound
energy state
46. At a constant pressure - the volume of an ideal gas is directly proportinal to its temperature: V (a) T
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47. Expression of auto - ionization of water into H+ and OH- at a certain temperature - given by the product of the ions' molar concentrations. Denoted by Kw and equal to 10-
Group 1A
Group 2A
Resonance structure
Water dissociation Constant
48. The ratio of the number of moles of solute dissolved in one kilogram of solvent. molality (M = moles solute/kg of solution)
Arrhenius Definition
Molality
heisenberg uncertainty principle
Redox Half Reaction
49. When dipoles are dissolved in a solution where ions are present ions wil arrange themselves with the opposite charged end of the dipole.
bond length
Electrolyte
Water dissociation Constant
Ion dipole interactions
50. The pressure exerted by a vapor in equilibrium with its liquid or solid phase
Vapor pressure
pH
Emperical Formula
chemical reaction
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