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MCAT Chemistry
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Subjects
:
mcat
,
science
Instructions:
Answer 50 questions in 15 minutes.
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Match each statement with the correct term.
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This is a study tool. The 3 wrong answers for each question are randomly chosen from answers to other questions. So, you might find at times the answers obvious, but you will see it re-enforces your understanding as you take the test each time.
1. The weak attractive forces between molecules resulting from the small - instantaneous dipoles that occur because of the varying positions of the electrons during their motion about nuclei
Rate law
Ion product
quanta
London forces
2. A reaction in which atoms of one element take the place of atoms of another element in a compound
single displacement reaction
Equlibrium constant
mole
Free radical
3. When a solute is dissolved in a solvent - it will dissociate until reaching an equilibrium point at which the rate of dissociation equals the rate of precipitation of the solute - regardless of any additional solute introduced into the mixture
Hydrogen bonding
Reaction mechanism
Colligative properties
Solution equilibrium
4. Simplest whole # ration of atoms in a compound
Disproportionation
Emperical Formula
Redox Half Reaction
Octet Rule
5. A reaction in which atoms of one element take the place of atoms of another element in a compound
Avagadros number
single displacement reaction
Collision theory of chemical Kinetics
Percent composition
6. Any sample of a given compound will contain the same elements in the identical mass ratio.
law of constant composition
heisenberg uncertainty principle
Group 4A
Group 6A
7. Have the shape of a sphere - with the center of the sphere at the nucleus; completely symmetrical along all axes; 1s orbital is spherically symmetric and has no nodes; 2s orbital is also spherical but contains a node and is higher in energy
chemical reaction
Henry's Law
Magnetic quantum number
s orbital
8. The nuclear charge experienced by the outermost electrons of an atom (actual charge minus the shielding caused by inner shells: Z- eff)
Halogens
effective nuclear charge
Nucleus
angular momentum in the bohr model
9. A naturally occurring or synthetic compound consisting of large molecules made up of a linked series of repeated simple monomers
gram equivalent weight
electromagnetic energy of photons emmited from electrons at ground state
polymer
Formula weight
10. The weight in grams of one mole of a given elementand is expressedin tems of grams per mole.
Buffer
Dispersion Forces
Atomic weight
Rydberg constant
11. An atom - ion - or molecule that donates an electron pair to form a covalent bond.
Mass number
molecular weight
lewis base
azimuthal quantum number
12. Have three valance electrons. In certain instances - some elements will loose three electrons - but they will also share electrons with another element to attain stability.
Rydberg constant
Intermolecular forces
Resonance structure
Group 3A
13. Halogens; ns2np5 - - 2nd most reactive group - The Halogens; very active because of need to fill; form -1 ions; 7 electrons in valence shell; tend to form salts with elements from groups 1A and 2A
angular momentum in the bohr model
Group 7A
VSEPR
Formal Charge
14. When polar molecules orient themselves such that the positive region of one molecule is close to the negative region of another molecule.
Nucleus
Dipole Dipole interaction
atomic radius
Planck's Constant
15. Contains nonmetals - 7 valence electrons in it's outermost energy level. Very reactive
Pauli exclusion principle
crystalline solid
Covalent Bond
Halogens
16. A measured amount of a solution of unknown concentration is added to a known volume of a second solution until the reaction between them is just complete
bond length
Titration
Molecular orbital
Avagadros number
17. Systematic pairing of a deprotonated species (base) with its protonated form (conjugate acid). Conjugates appear on opposite sides of a chemical equation.
quantum numbers
Conjugate acids and Bases
molecular weight
Rate determining step
18. A chemical reaction involving the transfer of one or more electrons from one reactant to another; also called oxidation - reduction reaction.
Nucleus
The bohr model
redox reaction
heisenberg uncertainty principle
19. A chemical reaction involving the transfer of one or more electrons from one reactant to another; also called oxidation - reduction reaction.
redox reaction
Half equivalence point
Bronsted - Lowry definition
molecular weight
20. A concentration unit of a solution expressed as moles of solute dissolved per liter of solution
Molarity
actinide series
Activation energy
Resonance structure
21. The average distance between the nuclei of two bonded atoms
indicator
single displacement reaction
Diffusion
bond length
22. The energy required to break a chemical bond and form neutral isolated atoms
Effusion
Solubility Product Constant
transition elements
bond energy
23. Gram equivalent weight of solute per liter of solution - often denoted by N.
Group 1A
Activation energy
Alkaline earths
Normality
24. A bond formed when two atomic orbitals combine to form a molecular orbital that is symmetrical around the axis connecting the two atomic nuclei
polymer
percent composition
sigma bond
Theoretical yield
25. When dipoles are dissolved in a solution where ions are present ions wil arrange themselves with the opposite charged end of the dipole.
Ion dipole interactions
redox reaction
Neutron
Atomic weight
26. PH=pka+log[base/acid] Used in titration based problems that relates the pH or pOH of a solution to the pK and the ratio of the dissociated species.
Henderson Hasselbalch Equation
Covalent Bond
atomic emission spectrum
Ionization energy
27. The ways in which electrons are arranged in various orbitals around the nuclei of atoms
Ionization energy
sigma bond
Group 2A
electron configuration
28. Alkaline Earth Metals - 2 valence electrons +2 ions - Magnesium Mg
Spin quantum number
crystalline solid
Dispersion Forces
Group 2A
29. One - half of the distance between the center of identical atoms that are not bonded together. Since effective nuclear charge increases when moving from left to right each additional electron is pulled more strogly toward the nucleus.
atomic radius
lathanide series
Triple point
Theoretical yield
30. A definite stable energy that a physical system can have
electron affinity
energy state
crystalline solid
Equivalence point
31. A representation of a displacement reaction showing only the reactive species and omitting the spectator ions.
Net ionic equation
Effusion
Atomic weight
Combination Reaction
32. Defined acids as subtsances that produced H ions in water - while bases produced OH ions. When they reacted together - H and OH neutralise to make water
Rate determining step
theoretical yield
Strong acid
Arrhenius Definition
33. The molar amount of a solute that can dissolve in 1L of solvent until equilibrium - saturation - is reached
Solution equilibrium
single displacement reaction
Ion
Molar solubility
34. States that it is impossible to determine simultaneously both the position and momentum of an electron or any other particle
und's rule
transition elements
Period
heisenberg uncertainty principle
35. A covalent bond in which the bonding electrons are shared equally by the bonded atoms - resulting in a balanced distribution of electrical charge
Nonpolar covalent bond
Group 6A
Noble gases
chemical reaction
36. Where half of the acid is neutralized by the base on a titration curveAn acid dissociation constant - Ka - (also known as acidity constant - or acid - ionization constant) is a quantitative measure of the strength of an acid in solution. It is the eq
Concentration
Ionic Bond
Activation energy
Half equivalence point
37. The process by which one or more substances change to produce one or more different substances
Solubility Product Constant
Amphoteric
chemical reaction
Group 4A
38. The weight in grams of compound that can be substituted by 1 atom of Hydrogen. GEW = MW / # of acidic Hyrdogens
Hydrogen bonding
gram equivalent weight
Molecular orbital
Water dissociation Constant
39. Named after their cation and anion
Raoult's Law
Henry's Law
Henderson Hasselbalch Equation
ionic cmpound
40. Sum of all the masses - in AMU - present in one molecule of a molecular compound.
Decomposition reaction
actinide series
Graham's Law
Formula weight
41. An ionic compound that resists changes in its pH
Half equivalence point
Water dissociation Constant
Dispersion Forces
Buffer
42. Product of the molar concentrations of dissociated ions in solution at saturation - where each ion is raised to the power of its stoichiometric coefficient. Denoted Ksp.
Planck's Constant
Bronsted - Lowry definition
Solubility Product Constant
quantum numbers
43. Expression of auto - ionization of water into H+ and OH- at a certain temperature - given by the product of the ions' molar concentrations. Denoted by Kw and equal to 10-
angular momentum in the bohr model
Water dissociation Constant
heisenberg uncertainty principle
theoretical yield
44. PH of a molecule at which it contains no net electric charge - isoelectric point.
Vapor pressure
Redox Half Reaction
d orbital
pI
45. Specifies the specific orbital in which the electron is most likely to be found. - Third quantum number - designated as ml. Describes a particular orbital within a subshell where an electron is very likely to be found. Possible values are integers in
Alkaline earths
Magnetic quantum number
Water dissociation Constant
pH
46. Mixture of 2 or more substances that distills at a constant temperature and with constant composition - even though seperately the components have different boiling points
Henry's Law
Azeotrope
Activation energy
crystalline solid
47. The process of decomposing a chemical compound by the passage of an electric current.
electrolysis
Electrolyte
single displacement reaction
energy state
48. Chalcogens - - Oxide O
Formal Charge
Group 6A
Dispersion Forces
Ionization energy
49. (chemistry) a substance that changes color to indicate the presence of some ion or substance
single displacement reaction
Effective nuclear charge
Common ion effect
indicator
50. The formation of one or more covalent bonds between an electron pair donor and an electron pair acceptor
Water dissociation Constant
Principle quantum number
Lewis acid base reaction
Half equivalence point
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