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MCAT Chemistry
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Subjects
:
mcat
,
science
Instructions:
Answer 50 questions in 15 minutes.
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Match each statement with the correct term.
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This is a study tool. The 3 wrong answers for each question are randomly chosen from answers to other questions. So, you might find at times the answers obvious, but you will see it re-enforces your understanding as you take the test each time.
1. Specifies the specific orbital in which the electron is most likely to be found. - Third quantum number - designated as ml. Describes a particular orbital within a subshell where an electron is very likely to be found. Possible values are integers in
subshell
Rate determining step
s orbital
Magnetic quantum number
2. The intermolecular force in which a hydrogen atom that is bonded to a highly electronegative atom is attracted to an unshared pair of electrons of an electronegative atom in a nearby molecule
transition elements
azimuthal quantum number
hydrogen bonding
effective nuclear charge
3. Mixture of 2 or more substances that distills at a constant temperature and with constant composition - even though seperately the components have different boiling points
Avagadros number
Lewis structure
Azeotrope
theoretical yield
4. The ways in which electrons are arranged in various orbitals around the nuclei of atoms
Planck's Constant
electron configuration
Effective nuclear charge
Solution equilibrium
5. Redox reaction - in which the same species is both oxidized and reduced.
und's rule
bond energy
Combination Reaction
Disproportionation
6. Charge assigned to an atom in a molecule or polyatmic ion - calculated by (# valence electrons) - (# 1/2 bonding electrons) - (# nonbonding electrons). Molecules containing atoms with lower formal charges tend to be more stable than those with higher
Nonpolar covalent bond
Formal Charge
Alkaline earths
Conjugate acids and Bases
7. The weight in grams of compound that can be substituted by 1 atom of Hydrogen. GEW = MW / # of acidic Hyrdogens
gram equivalent weight
Collision theory of chemical Kinetics
Solvent
Atomic absorption Spectra
8. The pressure exerted by a vapor in equilibrium with its liquid or solid phase
representative elements
Theoretical yield
electrolysis
Vapor pressure
9. Have three valance electrons. In certain instances - some elements will loose three electrons - but they will also share electrons with another element to attain stability.
Formal Charge
Normality
single displacement reaction
Group 3A
10. The amount of energy that reactants must absorb before a chemical reaction will start; also called free energy of activation.
Decomposition reaction
solvation
Activation energy
Solvent
11. 4 valence electrons +4 - -4 ions. - Carbon Group can form covalent bonds with nonmetals. Only carbon forms strong pi bonds
Bronsted Lowry
Diprotic Base
Theoretical yield
Group 4A
12. A definite stable energy that a physical system can have
energy state
Decomposition reaction
atomic radius
indicator
13. Alkaline Earth Metals - 2 valence electrons +2 ions - Magnesium Mg
Nonpolar covalent bond
Group 2A
Diprotic Base
London forces
14. Product of the molar concentrations of dissociated ions in solution at saturation - where each ion is raised to the power of its stoichiometric coefficient. Denoted Ksp.
Formal Charge
electron affinity
Neutron
Solubility Product Constant
15. Set of spectral lines appearing in the UV region when a hydrogen atom undergoes a transition from energy levels n>1 to n=1.
Theoretical yield
Le chateliers Principle
Lyman series
Mass number
16. States that if a stress is applied to a system at equilibrium - the system shifts in the direction that relieves the stress.
quanta
Common ion effect
Hydrogen bonding
Le chateliers Principle
17. Product of the molar concentrations of dissociated ions in solution at any point in the reaction other than equilibrium or saturation - where each ion is raised to the power of its stoichiometric coefficient. Denoted IP.
Solute
decomposition reaction
Ion product
Water dissociation Constant
18. Simplest whole # ration of atoms in a compound
quantum
Emperical Formula
Disproportionation
Ion
19. A reaction where a compound does Not change its molecular structure.
physical reaction
Lewis structure
sigma bond
indicator
20. A base that can accept two moles of H+ per mole of itself (ex: SO4
Phase diagram
Diprotic Base
Ion
Equilibrium
21. A representation of a displacement reaction showing only the reactive species and omitting the spectator ions.
Dipole
Theoretical yield
Net ionic equation
angular momentum in the bohr model
22. A physical property of a solution that depends on the number - but not the identity - of the disswolved solute particles; example properties include vapor pressure lowering - boiling point elevation - osmotic pressure - and frezzing point depression
Colligative properties
Reaction mechanism
Equilibrium
Amphoteric
23. A bond formed when two atomic orbitals combine to form a molecular orbital that is symmetrical around the axis connecting the two atomic nuclei
sigma bond
Water dissociation Constant
Solubility Product Constant
Acid dissociation constant
24. Chalcogens - - Oxide O
pi bonds
Water dissociation Constant
sigma bond
Group 6A
25. A concentration unit of a solution expressed as moles of solute dissolved per liter of solution
pH
Lewis acid base reaction
Molarity
Dispersion Forces
26. An ionic compound that resists changes in its pH
effective nuclear charge
Buffer
single displacement reaction
pi bonds
27. The center of the atom which contains the protons and neutrons; in cells - structure that contains the cell's genetic material (DNA) and controls the cell's activities
Formal Charge
Avagadros number
Electrolyte
Nucleus
28. The quantum number that indicates the main energy level occupied by the electron. Can theoretically take on any positive interger. Denoted by the letter n.
Electrolyte
chemical reaction
Principle quantum number
Collision theory of chemical Kinetics
29. Elements in the middle of the periodic table - in groups 3-12.
Magnetic quantum number
Rate determining step
percent composition
transition elements
30. Large molecular structures - strong covalent bonding - share qualities of IONIC And COVALENT
Redox Half Reaction
redox reaction
Activation energy
Network covalent
31. Property of the elements that can be predicted from the arrangement of the periodic table
Spin quantum number
Disproportionation
Molality
periodic trends
32. Valence Shell Electron Pair Repulsion theory - stating that the three - dimensional molecular geometry about some central atom is determined by the elctronic repulsion between its bonding and nonbonding electron pairs.
VSEPR
Disproportionation
The bohr model
Water dissociation Constant
33. Gram equivalent weight of solute per liter of solution - often denoted by N.
gram equivalent weight
polymer
Normality
Planck's Constant
34. Keq describes the ratio of product concentration to reactant concentration - with each raised to the power corresponding ot its coefficient ion in the balanced equation
Formal Charge
Equlibrium constant
quantum numbers
The bohr model
35. The Percent by mass of each element in a compound.
Percent composition
Molecular orbital
bond length
Diprotic Base
36. A reaction in which two or more substances combine to form a single substance A+B>>>>>>>C
STP
Half equivalence point
Combination Reaction
Net ionic equation
37. The weight in grams of one mole of a given elementand is expressedin tems of grams per mole.
amorphous solid
Halogens
Hydrogen bonding
Atomic weight
38. Structure that occurs when it is possible to draw two or more valid electron dot structures that have the same number of electron pairs for a molecule or ion
Collision theory of chemical Kinetics
Resonance structure
Intermolecular forces
VSEPR
39. Named after their cation and anion
polymer
und's rule
ionic cmpound
Equivalence point
40. Region in a molecule where atomic orbitals overlap - resulting in either a stable low - energy bonding orbital or an unstable high - energy antibonding orbital.
Principle quantum number
Group 4A
Molecular orbital
Disproportionation
41. Side - to side parallel orbitals overlap to share electrons - the 2nd/3rd covalent bond between two atoms - cannot rotate and maintain the bond.
Group 7A
Formula weight
d orbital
pi bonds
42. A chemical reaction involving the transfer of one or more electrons from one reactant to another; also called oxidation - reduction reaction.
electron configuration
redox reaction
Strong acid
Ion dipole interactions
43. Process by which molecules tend to move from an area where they are more concentrated to an area where they are less concentrated
lewis base
amorphous solid
Diffusion
compound
44. Have the shape of a sphere - with the center of the sphere at the nucleus; completely symmetrical along all axes; 1s orbital is spherically symmetric and has no nodes; 2s orbital is also spherical but contains a node and is higher in energy
Ionization energy
Group 3A
Solute
s orbital
45. Numbers that specify the properties of atomic orbitals and of their electrons
electrolysis
quantum numbers
electromagnetic energy of photons emmited from electrons at ground state
indicator
46. Attractions between molecules caused by the electron motion on one molecule affecting the electron motion on the other through electrical forces; these are the weakest interactions between molecules
Dispersion Forces
subshell
Aqueous Solution
Intermolecular forces
47. (chemistry) p(otential of) H(ydrogen)
s orbital
pH
law of constant composition
Molarity
48. The energy required to remove an electron from a gaseous atom; generally increases in moving from left - to - right across a period and decreases in moving down a group
Henry's Law
Ionization energy
Planck's Constant
redox reaction
49. The process of decomposing a chemical compound by the passage of an electric current.
electrolysis
Effective nuclear charge
hydrogen bonding
single displacement reaction
50. Standard Temperature and Pressure. 273 Kelvin (0 Celsius) - 1 atmosphere (760 torr - 760 kPA).
indicator
Le chateliers Principle
STP
Titration
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