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MCAT Chemistry
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Subjects
:
mcat
,
science
Instructions:
Answer 50 questions in 15 minutes.
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Match each statement with the correct term.
Don't refresh. All questions and answers are randomly picked and ordered every time you load a test.
This is a study tool. The 3 wrong answers for each question are randomly chosen from answers to other questions. So, you might find at times the answers obvious, but you will see it re-enforces your understanding as you take the test each time.
1. A set of frequencies of electromagnetic waves given off by atoms of an element; consists of a series of fine lines of individual colors
Group 3A
Covalent Bond
Ion
atomic emission spectrum
2. Have the shape of a sphere - with the center of the sphere at the nucleus; completely symmetrical along all axes; 1s orbital is spherically symmetric and has no nodes; 2s orbital is also spherical but contains a node and is higher in energy
Lewis structure
Bronsted - Lowry definition
s orbital
STP
3. The ways in which electrons are arranged in various orbitals around the nuclei of atoms
Emperical Formula
redox reaction
lathanide series
electron configuration
4. A chemical reaction involving the transfer of one or more electrons from one reactant to another; also called oxidation - reduction reaction.
redox reaction
Ion
Rydberg constant
hydrogen bonding
5. The weak attractive forces between molecules resulting from the small - instantaneous dipoles that occur because of the varying positions of the electrons during their motion about nuclei
London forces
hydrogen bonding
Amphoteric
single displacement reaction
6. Second quantum number - designated by the letter 'l.' This 'angular momentum' refers to the subshells within each principle quantum energy level. It can take on the value of an integer in the 0 to (n -1) range. The four subshellscorresponding to l=0
azimuthal quantum number
Nonpolar covalent bond
Percent yield
Formal Charge
7. Slightly less reactive than alkali metals - comprise group II
Noble gases
Electrolyte
Solution equilibrium
Alkaline earths
8. Set of spectral lines appearing in the UV region when a hydrogen atom undergoes a transition from energy levels n>1 to n=1.
Halogens
Solution equilibrium
electrolysis
Lyman series
9. A concentration unit of a solution expressed as moles of solute dissolved per liter of solution
s orbital
electron configuration
Molarity
Pauli exclusion principle
10. A physical property of a solution that depends on the number - but not the identity - of the disswolved solute particles; example properties include vapor pressure lowering - boiling point elevation - osmotic pressure - and frezzing point depression
Common ion effect
Dispersion Forces
Colligative properties
empirical formula
11. Product of the molar concentrations of dissociated ions in solution at saturation - where each ion is raised to the power of its stoichiometric coefficient. Denoted Ksp.
Balmer series
Solubility Product Constant
Theoretical yield
d orbital
12. No two electrons or protons or neutrons in a given system can be in states characterized by the same set of quantum numbers
Pauli exclusion principle
Neutron
Net ionic equation
amorphous solid
13. The Percent by mass of each element in a compound.
redox reaction
Molarity
Titration
Percent composition
14. The slowest elementary step which is the limit for the rate of the other steps
Spin quantum number
atomic theory
Rate determining step
theoretical yield
15. Nh/2p The angular momentum changes only in discete amounts with respect to the quantum number. Also E=- R_h/n^2
Conjugate acids and Bases
Bronsted Lowry
Neutron
angular momentum in the bohr model
16. An equilibrium expression used to measure weak - acid strength - given by the ratio of the product of the products' molar concentrations to the product of the reactants' molar concentrations - with each term raised to the power of its stoichiometric
single displacement reaction
Halogens
Acid dissociation constant
decomposition reaction
17. Simplest whole # ration of atoms in a compound
law of constant composition
d orbital
Strong acid
Emperical Formula
18. An atom - ion - or molecule that donates an electron pair to form a covalent bond.
crystalline solid
lewis base
Common ion effect
Rate determining step
19. A structural formula in which electrons are represented by dots; dot pairs or dashes between two atomic symbols represent pairs in covalent bonds.
Neutron
Lewis structure
Arrhenius Definition
Graham's Law
20. (chemistry) separation of a substance into two or more substances that may differ from each other and from the original substance C>>>>A+B
molecular weight
periodic trends
Decomposition reaction
Hydrogen bonding
21. Having characteristics of both an acid and a base and capable of reacting as either
Magnetic quantum number
Molarity
Amphoteric
Ion product
22. Expression of auto - ionization of water into H+ and OH- at a certain temperature - given by the product of the ions' molar concentrations. Denoted by Kw and equal to 10-
Hydrogen bonding
Ionization energy
Water dissociation Constant
The bohr model
23. Acids defined as electron - pair acceptors and bases as electron - pair donors.
Lewis definition
Normality
crystalline solid
Nucleus
24. The process of decomposing a chemical compound by the passage of an electric current.
Atomic weight
Combination Reaction
electrolysis
chemical reaction
25. The reaction of the ions that characterize acids and the ions that characterize bases to form water molecules and a salt
Ionization energy
Henderson Hasselbalch Equation
single displacement reaction
Neutralization reaction
26. The energy required to remove an electron from a gaseous atom; generally increases in moving from left - to - right across a period and decreases in moving down a group
Solute
energy state
Ionization energy
effective nuclear charge
27. Small discrete increments of energy.
Proton
solvation
Decomposition reaction
quanta
28. Substance in which a solute is dissolved to form a solution
gram equivalent weight
Solvent
Equivalence point
VSEPR
29. Contains nonmetals - 7 valence electrons in it's outermost energy level. Very reactive
bond energy
polymer
Halogens
Diprotic Base
30. The center of the atom which contains the protons and neutrons; in cells - structure that contains the cell's genetic material (DNA) and controls the cell's activities
Collision theory of chemical Kinetics
Resonance structure
Diprotic Base
Nucleus
31. Mixture of 2 or more substances that distills at a constant temperature and with constant composition - even though seperately the components have different boiling points
Azeotrope
Group 2A
electrolysis
Rydberg constant
32. The hypothetical equation showing only the species that is oxidized or reduced in a redox reaction and the correct number of electrons transferred between the species in the complete - balanced equation.
quantum
VSEPR
Redox Half Reaction
Henderson Hasselbalch Equation
33. Region in a molecule where atomic orbitals overlap - resulting in either a stable low - energy bonding orbital or an unstable high - energy antibonding orbital.
Chemical Kinetics
Halogens
Hydrogen bonding
Molecular orbital
34. An element in an 'A' group in the periodic table; as a group these elements display a wide range of physical and chemical properties. In their atoms - the s and p sublevels in the highest occupied energy level are partially filled
representative elements
physical reaction
subshell
single displacement reaction
35. Common definition of acids as proton (H+) donors and bases as proton acceptors
Bronsted - Lowry definition
Raoult's Law
bond length
Intermolecular forces
36. A reaction in which atoms of one element take the place of atoms of another element in a compound
single displacement reaction
periodic trends
quantum
percent composition
37. Side - to side parallel orbitals overlap to share electrons - the 2nd/3rd covalent bond between two atoms - cannot rotate and maintain the bond.
Pauli exclusion principle
mole
pi bonds
Nonpolar covalent bond
38. Attractive and repulsive forces between molecules that are weaker than forces within molecules.
Group 5A
Halogens
Intermolecular forces
Group 3A
39. A covalent bond in which the bonding electrons are shared equally by the bonded atoms - resulting in a balanced distribution of electrical charge
Le chateliers Principle
Theoretical yield
Equilibrium
Nonpolar covalent bond
40. Contains nonmetals that are non - reactive. Full outermost energy level except helium which has 2.
Lewis structure
Collision theory of chemical Kinetics
Noble gases
Amphoteric
41. The average distance between the nuclei of two bonded atoms
Effective nuclear charge
bond length
Ionic Bond
Dipole Dipole interaction
42. The ratio of the number of moles of solute dissolved in one kilogram of solvent. molality (M = moles solute/kg of solution)
Molality
Buffer
Hydrogen bonding
Equivalence point
43. Keq describes the ratio of product concentration to reactant concentration - with each raised to the power corresponding ot its coefficient ion in the balanced equation
Group 1A
The bohr model
Dispersion Forces
Equlibrium constant
44. When a solute is dissolved in a solvent - it will dissociate until reaching an equilibrium point at which the rate of dissociation equals the rate of precipitation of the solute - regardless of any additional solute introduced into the mixture
compound
Solution equilibrium
Equilibrium
Concentration
45. A substance that - when dissolved in water - results in a solution that can conduct electricity
crystalline solid
Free radical
atomic theory
Electrolyte
46. A subatomic particle that has a positive charge and that is found in the nucleus of an atom Charge of +1 and mass of 1.0073 amu
hydrogen bonding
Nucleus
Proton
Avagadros number
47. Standard Temperature and Pressure. 273 Kelvin (0 Celsius) - 1 atmosphere (760 torr - 760 kPA).
STP
Proton
electrolysis
empirical formula
48. The weight in grams of compound that can be substituted by 1 atom of Hydrogen. GEW = MW / # of acidic Hyrdogens
electron configuration
gram equivalent weight
Collision theory of chemical Kinetics
heisenberg uncertainty principle
49. The nuclear charge experienced by the outermost electrons of an atom (actual charge minus the shielding caused by inner shells: Z- eff)
Dipole
Buffer
effective nuclear charge
Alkaline earths
50. Play- by- play showing the individual steps of a reaction - including the formation and destruction of any reaction intermediates that may occur.
Balmer series
Reaction mechanism
Lewis acid base reaction
Ion
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