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MCAT Chemistry
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Subjects
:
mcat
,
science
Instructions:
Answer 50 questions in 15 minutes.
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Match each statement with the correct term.
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1. E=hc/?
Bronsted - Lowry definition
Period
electromagnetic energy of photons emmited from electrons at ground state
Colligative properties
2. Keq describes the ratio of product concentration to reactant concentration - with each raised to the power corresponding ot its coefficient ion in the balanced equation
Molality
Equlibrium constant
ionic cmpound
Colligative properties
3. Contains nonmetals that are non - reactive. Full outermost energy level except helium which has 2.
Colligative properties
crystalline solid
Noble gases
redox reaction
4. Small discrete increments of energy.
Bronsted - Lowry definition
quanta
electromagnetic energy of photons emmited from electrons at ground state
Ionic Bond
5. Systematic pairing of a deprotonated species (base) with its protonated form (conjugate acid). Conjugates appear on opposite sides of a chemical equation.
Electrolyte
Conjugate acids and Bases
azimuthal quantum number
Group 2A
6. Attractive and repulsive forces between molecules that are weaker than forces within molecules.
Buffer
Intermolecular forces
Solvent
Group 1A
7. An atom - ion - or molecule that donates an electron pair to form a covalent bond.
molecule
lewis base
Charles and Gay Lussac's Law
percent composition
8. Charge assigned to an atom in a molecule or polyatmic ion - calculated by (# valence electrons) - (# 1/2 bonding electrons) - (# nonbonding electrons). Molecules containing atoms with lower formal charges tend to be more stable than those with higher
Diffusion
Formal Charge
Solution equilibrium
Magnetic quantum number
9. A structural formula in which electrons are represented by dots; dot pairs or dashes between two atomic symbols represent pairs in covalent bonds.
Lewis structure
Water dissociation Constant
Electrolyte
azimuthal quantum number
10. A subdivision of an energy level in an atom. They are divided into orbitals.
Rate determining step
subshell
theoretical yield
Activation energy
11. The reaction of the ions that characterize acids and the ions that characterize bases to form water molecules and a salt
redox reaction
Water dissociation Constant
Neutralization reaction
Ground state
12. A chemical formula showing the ratio of elements in a compound rather than the total number of atoms
lewis base
mole
Lyman series
empirical formula
13. Simplest whole # ration of atoms in a compound
Planck's Constant
Bronsted - Lowry definition
Emperical Formula
Strong acid
14. Halogens; ns2np5 - - 2nd most reactive group - The Halogens; very active because of need to fill; form -1 ions; 7 electrons in valence shell; tend to form salts with elements from groups 1A and 2A
Collision theory of chemical Kinetics
solvation
Group 7A
mole
15. A chemical bond that involves sharing a pair of electrons between atoms in a molecule
empirical formula
Covalent Bond
Molecular orbital
Nucleus
16. Resulting positive nuclear charge an outer electron senses after accounting for the shielding effect of inner core electrons. Abbreviated as Z(eff). Increases from left to right - and bottom to top on the Periodic Table.
Rate law
gram equivalent weight
quantum numbers
Effective nuclear charge
17. Elements in the middle of the periodic table - in groups 3-12.
Group 5A
Dipole
Pauli exclusion principle
transition elements
18. 1913 - Niels Bohr - said that electrons formed specific layers instead or random ones - said atoms atoms absorb and give off energy when the electrons move from one shell to another
The bohr model
Net ionic equation
Electrolyte
Molality
19. Substance in which a solute is dissolved to form a solution
Solvent
Proton
und's rule
Molarity
20. The process by which a gas escapes from one container to another at lower pressure through a tiny hole in the container.
Effusion
quanta
Free radical
Ground state
21. 5 different orbitals shaped like clover leaves and max electrons is 10
Molarity
Solubility Product Constant
molecule
d orbital
22. A reaction in which atoms of one element take the place of atoms of another element in a compound
Azeotrope
Spin quantum number
Group 4A
single displacement reaction
23. The quantum number that indicates the main energy level occupied by the electron. Can theoretically take on any positive interger. Denoted by the letter n.
decomposition reaction
Principle quantum number
Group 5A
Reaction order
24. Having characteristics of both an acid and a base and capable of reacting as either
sigma bond
crystalline solid
Covalent Bond
Amphoteric
25. Nh/2p The angular momentum changes only in discete amounts with respect to the quantum number. Also E=- R_h/n^2
Arrhenius Definition
angular momentum in the bohr model
Ion
Dipole Dipole interaction
26. Rare earth element group (elements 58-71)
Group 4A
lathanide series
electron configuration
Ground state
27. (chemistry) the sum of the relative atomic masses of the constituent atoms of a molecule
effective nuclear charge
molecular weight
sigma bond
Conjugate acids and Bases
28. The intermolecular force in which a hydrogen atom that is bonded to a highly electronegative atom is attracted to an unshared pair of electrons of an electronegative atom in a nearby molecule
Molar solubility
Balmer series
ionic cmpound
hydrogen bonding
29. Second quantum number - designated by the letter 'l.' This 'angular momentum' refers to the subshells within each principle quantum energy level. It can take on the value of an integer in the 0 to (n -1) range. The four subshellscorresponding to l=0
Acid dissociation constant
Molar solubility
bond length
azimuthal quantum number
30. A naturally occurring or synthetic compound consisting of large molecules made up of a linked series of repeated simple monomers
polymer
Neutron
Mass number
Combination Reaction
31. The molar amount of a solute that can dissolve in 1L of solvent until equilibrium - saturation - is reached
Molar solubility
percent composition
Planck's Constant
subshell
32. At a constant pressure - the volume of an ideal gas is directly proportinal to its temperature: V (a) T
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33. Named after their cation and anion
ionic cmpound
atomic theory
Aqueous Solution
quantum
34. The lowest allowable energy state of an atom
Ground state
Redox Half Reaction
Balmer series
angular momentum in the bohr model
35. Mixture of 2 or more substances that distills at a constant temperature and with constant composition - even though seperately the components have different boiling points
Emperical Formula
periodic trends
Lyman series
Azeotrope
36. Two or more atoms held together by covalent bonds
Conjugate acids and Bases
molecule
pI
Emperical Formula
37. The maximum amount of product that can be produced from a given amount of reactant
indicator
theoretical yield
energy state
pI
38. A chemical reaction involving the transfer of one or more electrons from one reactant to another; also called oxidation - reduction reaction.
Vapor pressure
theoretical yield
redox reaction
Equivalence point
39. One - half of the distance between the center of identical atoms that are not bonded together. Since effective nuclear charge increases when moving from left to right each additional electron is pulled more strogly toward the nucleus.
quantum numbers
decomposition reaction
atomic radius
gram equivalent weight
40. 4 valence electrons +4 - -4 ions. - Carbon Group can form covalent bonds with nonmetals. Only carbon forms strong pi bonds
Group 4A
Solution equilibrium
effective nuclear charge
Electronegativity
41. A reaction in which atoms of one element take the place of atoms of another element in a compound
bond energy
single displacement reaction
law of constant composition
Decomposition reaction
42. PH of a molecule at which it contains no net electric charge - isoelectric point.
single displacement reaction
pI
lathanide series
Chemical Kinetics
43. The intermolecular force in which a hydrogen atom that is bonded to a highly electronegative atom is attracted to an unshared pair of electrons of an electronegative atom in a nearby molecule
Free radical
Hydrogen bonding
Lewis acid base reaction
crystalline solid
44. Common definition of acids as proton (H+) donors and bases as proton acceptors
Noble gases
polymer
Intermolecular forces
Bronsted - Lowry definition
45. Where half of the acid is neutralized by the base on a titration curveAn acid dissociation constant - Ka - (also known as acidity constant - or acid - ionization constant) is a quantitative measure of the strength of an acid in solution. It is the eq
Arrhenius Definition
Noble gases
Group 5A
Half equivalence point
46. The percent by mass of each element in a compound
Resonance structure
percent composition
Nonpolar covalent bond
Equlibrium constant
47. An equilibrium expression used to measure weak - acid strength - given by the ratio of the product of the products' molar concentrations to the product of the reactants' molar concentrations - with each term raised to the power of its stoichiometric
Acid dissociation constant
Nucleus
Concentration
physical reaction
48. The hypothetical equation showing only the species that is oxidized or reduced in a redox reaction and the correct number of electrons transferred between the species in the complete - balanced equation.
Redox Half Reaction
Group 4A
Effusion
chemical reaction
49. (chemistry) a substance formed by chemical union of two or more elements or ingredients in definite proportion by weight
Covalent Bond
Redox Half Reaction
Effective nuclear charge
compound
50. A model of acids and bases which an acid is hydrogen ion donor and base is a hydrogen ion acceptor.
periodic trends
Bronsted Lowry
Rate law
quantum
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