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Test your basic knowledge |
MCAT Organic Chemistry
Start Test
Study First
Subjects
:
mcat
,
science
Instructions:
Answer 50 questions in 15 minutes.
If you are not ready to take this test, you can
study here
.
Match each statement with the correct term.
Don't refresh. All questions and answers are randomly picked and ordered every time you load a test.
This is a study tool. The 3 wrong answers for each question are randomly chosen from answers to other questions. So, you might find at times the answers obvious, but you will see it re-enforces your understanding as you take the test each time.
1. Name for mathanal
Combustion
polymerization
2^n
formaldehyde
2. Diols with hydroxyl group on adjacent carbon
carboxylic acid
relative configuration
vicinal
initiation propagation termination
3. A = observed rotation / concentration * length
specific rotation
halogenation
sp2
angle strain
4. Goal is to produce most stable carbocation
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5. Differ in position of substitutents attached to a double bond or cycloalkane. Cis or trans or e or z
relative configuration
electrophile
geometric isomers
polymerization
6. Creation of long - high molecular weight polymer composed of repeating subunit called monomers. occur through a radical mechanism.
ring strain
polymerization
Alkene
absolute configuration
7. Combustion reaction occurs through a radical process
C3H8 + 5O2 = 3CO2 + 4H2O + heat
molecular orbital
combustion - disproportionation - free - radical substitution - pyrolysis
aldehyde
8. Carbonyl located in middle or somewhere in chane. Named with One
triple bond
Haloalkane
ketone
racemic mixture
9. Iso - neo - cyclo
electrophilic addition of free radicals
electrophilic addition of H2O
not ignored
diastereomers
10. What are the best leaving groups?
weak bases
achiral
ethers
Vinyl
11. When bond angles deviate from ideal values
angle strain
potassium permanganate
enantiomer
quantum numbers
12. Chain of carbons connected by single bonds with hydrogen atoms attached.
catalytic hydrogenation
Alkane
hybridization
chiral center
13. Contain carbon carbon double bonds. Use same root of alkane but end with 'ene'
diol
aprotic solvent
Alkene
relative configuration
14. A sigma bond and two pi bonds
halogenation
carboxylic acid
triple bond
achiral
15. Name for propanal
Alkane nomenclature
propionaldehyde
hybridization
Alkyne
16. Same chemical formula. same atomic connectivity . different in how atoms are arranged in space
hydroboration
sp
ozonolysis
stereoisomers
17. Charged - need electrons
electrophile
cold potassium permanganate
saturated hydrocarbon
quantum numbers
18. Reaction of alkane with oxygen to form carbon dioxide - water and heat.
markovnikov's rule
Combustion
chiral center
torsional strain
19. Alkenes oxidzed with kmno4 - if made with cold - dilue - make OH on each side of double bond - diols or glycol in syn orientation
diol
anti conformation
cold potassium permanganate
enantiomer
20. How many stereoisomers can a molecule have with n chiral centers
C3H8 + 5O2 = 3CO2 + 4H2O + heat
ring flip
2^n
saturated hydrocarbon
21. N - l - ml - ms
protic solvent
vicinal
mcpba
quantum numbers
22. Nitrogen containing compound - longest chain attached to nitrogen used in backbone. use e and replace with AMINE. if more complex molecule present - use prefix amino. IF additional group added - use N-
sigma bond
amines
electrophilic addition of X2
ionic bond
23. Occur when a molecule is broken down by heat. used to reduce the avverage molecular weight of heavy oils. c - c - bonds are cleave dand make small chain alkyl radicals that recombine to form different alkanes
polymerization
pyrolysis
oxidation
catalytic hydrogenation
24. Sharing of electron between atoms
meso compound
covalent bond
achiral
anti conformation
25. A radical transfers a hydrogen atom to another radical and makes an alkane and alkene
stereoisomers
amines
peroxycarboxylic acid
disproportionation
26. A molecule with an internal plane of symmetry
meso compound
halogenation
alkyne
structural isomers
27. Name for ethanal
not ignored
acetaldehyde
ethers
geometric isomers
28. Two hydroxyl groups
geometric isomers
chiral center
Vinyl
diol
29. When two atomic orbitals combine. obtained mathematically by adding or subtracting wave functions. if sings are the same - make bonding - if different - less stable antibonding.
nonbonded strain
reducing
formaldehyde
molecular orbital
30. Carbon carbon triple bonds. Suffix-yne.
hydroboration
diol
anti conformation
Alkyne
31. Same molecular formula but different structure
covalent bond
stereoisomers
isomer
nonbonded strain
32. Nonsuperimposable mirror image of chiral objects - a specific steroisomer.
polymerization
enantiomer
alkyne
combustion - disproportionation - free - radical substitution - pyrolysis
33. Is bonded to only one other carbon atom
primary carbon
sp2
halogenation
stereoisomers
34. Refers to the =CH2 group
electrophilic addition of free radicals
methylene
C3H8 + 5O2 = 3CO2 + 4H2O + heat
stereoisomers
35. Transfer of electrions from one atome to another
Alkane nomenclature
ionic bond
nonbonded strain
enantiomer
36. O3
ozonolysis
cold potassium permanganate
propionaldehyde
Alkane
37. Fast process. double bond is nucleophile and attack x2. make cyclic halonium ion with either br or cl. and make dihalo trans
gauche conformation
halogenation
catalytic hydrogenation
electrophilic addition of X2
38. Zn/h or CH3/s with ozonolysis
Vinyl
angle strain
reducing
combustion - disproportionation - free - radical substitution - pyrolysis
39. Solvents with protons in solution - e.g. water or alcohol. large atoms tend to be better nucleophiles in here because they can shed the solvating protons around them and are more polarizable
racemic mixture
achiral
basicity
protic solvent
40. Arise from angle strain - torsional strian and nonbonded strain
allyl
alkyne
vicinal
ring strain
41. Use the Greek root for the number of carbons followed by the ending - - ane
ethers
vicinal
halogen
Alkane nomenclature
42. Nonterminal alkenes are cleaved to form two molar equivalent of carvoxylic acid ..make keton
lindlar's catalyst
covalent bond
carbonyl
hot - acidic potassium permanganate
43. Share molecular formula but have different chemical and physical properties
C3H8 + 5O2 = 3CO2 + 4H2O + heat
structural isomers
catalytic hydrogenation
alcohol
44. Hydrocarbon with one or more carbon carbon triple bond
structural isomers
aprotic solvent
alkyne
oxidation
45. Diol with hydroxyl group on same carbon
Haloalkane
geminal
oxidizing
Alkane
46. Spatial arrangement of the atoms or groups of a sterioisomer
configuration
Haloalkane
oxidation
triple bond
47. Y = position of double bond - x is position of triple bond - root is the prefix representing the length of the principal carbon chain
halogenation
y- root - en -x-yne
ozonolysis
propionaldehyde
48. Monosubstituted ethylene
hydroboration
mcpba
allyl
Vinyl
49. Di - tri - t - sec - n -
potassium permanganate
diol
ozonolysis
Ignored
50. Two p orbital form pi and third p orbital combine with s to make two sp hybrid. 180 degree apart
diastereomers
molecular orbital
polymerization
sp