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Test your basic knowledge |
MCAT Organic Chemistry
Start Test
Study First
Subjects
:
mcat
,
science
Instructions:
Answer 50 questions in 15 minutes.
If you are not ready to take this test, you can
study here
.
Match each statement with the correct term.
Don't refresh. All questions and answers are randomly picked and ordered every time you load a test.
This is a study tool. The 3 wrong answers for each question are randomly chosen from answers to other questions. So, you might find at times the answers obvious, but you will see it re-enforces your understanding as you take the test each time.
1. Chain of carbons connected by single bonds with hydrogen atoms attached.
Alkane
absolute configuration
isomer
y- root - en -x-yne
2. F - CL - Br - I
halogen
triple bond
sigma bond
pi bond
3. Describes the exact spatial arrangement of groups of atoms independent of other molecules.
gauche conformation
absolute configuration
nonbonded strain
enantiomer
4. Name for mathanal
carbonyl
electrophilic addition of HX
enantiomer
formaldehyde
5. Monosubstituted ethylene
Vinyl
pyrolysis
optical activity
saturated hydrocarbon
6. Object that is not superimposable upon mirror image
ethers
diastereomers
chiral
oxidizing
7. Nucleus lover. electron rich species that are attracked to charged atoms
electrophilic addition of HX
chiral center
configuration
nucleophile
8. Propylenes attached to a backbone at the C-3 position. Meaning the double bond at end of the chain and single bonded carbon at rest
carboxylic acid
racemic mixture
allyl
aldehyde
9. Configuration in relation to another chiral molecule. use it to determine if a molecule is an enantiomer - diastereomer - etc
relative configuration
hot - acidic potassium permanganate
reducing
alkyne
10. Carbon double bonded to an oxygen
stereoisomers
allyl
sigma bond
carbonyl
11. Same molecular formula but different structure
conformational isomer
eclipsed conformation
Ignored
isomer
12. Name for ethanal
peroxycarboxylic acid
Alkyne
acetaldehyde
isomer
13. Most favorable of staggared conformations
2^n
not ignored
formaldehyde
anti conformation
14. If reagent has a bunch of oxygen
oxidation
mcpba
isomer
methylene
15. Two hydroxyl groups
y- root - en -x-yne
diol
allyl
halogen
16. Spatial arrangement of the atoms or groups of a sterioisomer
structural isomers
configuration
mcpba
ozonolysis
17. Solvents with protons in solution - e.g. water or alcohol. large atoms tend to be better nucleophiles in here because they can shed the solvating protons around them and are more polarizable
protic solvent
sp3
optical activity
achiral
18. When two p orbitals line up in parallel and electron clouds overlap. it exsits over a single bond.
carboxylic acid
pi bond
Combustion
disproportionation
19. Methyl are 60 degrees apart. kinda stable
alcohol
electrophile
gauche conformation
covalent bond
20. Transfer of electrions from one atome to another
stereoisomers
ionic bond
sp
amines
21. A = observed rotation / concentration * length
sigma bond
Alkane nomenclature
specific rotation
Ignored
22. What are the best leaving groups?
Haloalkane
amines
weak bases
potassium permanganate
23. Is bonded to only one other carbon atom
primary carbon
diastereomers
gauche conformation
pyrolysis
24. Differ in position of substitutents attached to a double bond or cycloalkane. Cis or trans or e or z
protic solvent
ozonolysis
oxidation
geometric isomers
25. No double bonds. it has the maximum number of hydrogens.
conformational isomer
carboxylic acid
saturated hydrocarbon
chiral
26. If a compound is able to rotate plane polarized light.
ozonolysis
optical activity
enantiomer
diastereomers
27. Rotations cancel each other out therefore no optical activity
meso compound
racemic mixture
nonbonded strain
sp3
28. Arise from angle strain - torsional strian and nonbonded strain
triple bond
y- root - en -x-yne
enantiomer
ring strain
29. Reducing an alkene by adding molecular hydrogen to double bond with aid of metal catalyst. e.g. pt - pd - ni. takes place on surface of metal so it does syn addition
C3H8 + 5O2 = 3CO2 + 4H2O + heat
pi bond
catalytic hydrogenation
geminal
30. When a molecular orbital is formed head to head or tail to tail. all single bonds are tehese.
sigma bond
electrophilic addition of X2
configuration
enantiomer
31. Steps of free radical substitution
protic solvent
electrophilic addition of H2O
Combustion
initiation propagation termination
32. Goal is to produce most stable carbocation
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33. Charged - need electrons
electrophile
enantiomer
reducing
geminal
34. Use the Greek root for the number of carbons followed by the ending - - ane
sigma bond
propionaldehyde
lindlar's catalyst
Alkane nomenclature
35. Formed by mixing different types of orbitals
relative configuration
torsional strain
ozonolysis
hybridization
36. In which one or morehydrogen atoms are replaced with a halogen atom. via free radical substitution
nonbonded strain
halogenation
Acetylene
structural isomers
37. Hydrocarbon with one or more carbon carbon triple bond
cold potassium permanganate
anti conformation
alkyne
gauche conformation
38. A radical transfers a hydrogen atom to another radical and makes an alkane and alkene
covalent bond
pyrolysis
disproportionation
hydroboration
39. Refers to the =CH2 group
vicinal
relative configuration
enantiomer
methylene
40. Reaction of alkane with oxygen to form carbon dioxide - water and heat.
Combustion
carbonyl
meso compound
optical activity
41. Carbonyl located in middle or somewhere in chane. Named with One
hybridization
ketone
acetaldehyde
meso compound
42. A molecule with an internal plane of symmetry
specific rotation
propionaldehyde
meso compound
carbonyl
43. O3
geometric isomers
ozonolysis
chiral
stereoisomers
44. Alkenes oxidzed with kmno4 - if made with cold - dilue - make OH on each side of double bond - diols or glycol in syn orientation
optical activity
cold potassium permanganate
y- root - en -x-yne
sp
45. When two atomic orbitals combine. obtained mathematically by adding or subtracting wave functions. if sings are the same - make bonding - if different - less stable antibonding.
molecular orbital
peroxycarboxylic acid
ozonolysis
oxidation
46. Occur when a molecule is broken down by heat. used to reduce the avverage molecular weight of heavy oils. c - c - bonds are cleave dand make small chain alkyl radicals that recombine to form different alkanes
pyrolysis
Alkyne
eclipsed conformation
hydroboration
47. Iso - neo - cyclo
molecular orbital
initiation propagation termination
not ignored
electrophilic addition
48. Nonsuperimposable mirror image of chiral objects - a specific steroisomer.
ionic bond
meso compound
electrophilic addition of X2
enantiomer
49. Most similar. same molecule only at different points in their rotation. show them with newmans projections
quantum numbers
electrophilic addition of free radicals
vicinal
conformational isomer
50. Carbon with four different substituents and lack a plane of symmetry
ozonolysis
hybridization
markovnikov's rule
chiral center