SUBJECTS
|
BROWSE
|
CAREER CENTER
|
POPULAR
|
JOIN
|
LOGIN
Business Skills
|
Soft Skills
|
Basic Literacy
|
Certifications
About
|
Help
|
Privacy
|
Terms
|
Email
Search
Test your basic knowledge |
MCAT Organic Chemistry
Start Test
Study First
Subjects
:
mcat
,
science
Instructions:
Answer 50 questions in 15 minutes.
If you are not ready to take this test, you can
study here
.
Match each statement with the correct term.
Don't refresh. All questions and answers are randomly picked and ordered every time you load a test.
This is a study tool. The 3 wrong answers for each question are randomly chosen from answers to other questions. So, you might find at times the answers obvious, but you will see it re-enforces your understanding as you take the test each time.
1. Carbon double bonded to an oxygen
formaldehyde
carbonyl
relative configuration
sigma bond
2. Carbon carbon triple bonds. Suffix-yne.
molecular orbital
ring strain
Alkyne
combustion - disproportionation - free - radical substitution - pyrolysis
3. Is bonded to only one other carbon atom
primary carbon
conformational isomer
specific rotation
sigma bond
4. Formed by mixing different types of orbitals
saturated hydrocarbon
sp3
hybridization
sigma bond
5. N - l - ml - ms
ketone
quantum numbers
initiation propagation termination
hybridization
6. Carbon with four different substituents and lack a plane of symmetry
chiral center
enantiomer
propionaldehyde
Alkyne
7. Common name for ethyne
structural isomers
Acetylene
optical activity
diastereomers
8. Diborane add to double bond. boron acts as lewis acid and attaches to less hindered carbon. hydride transferred to adjacent carbon. antimarkonikov - alcohol produced
not ignored
hydroboration
2^n
molecular orbital
9. Compounds with halogen
2^n
acetaldehyde
Haloalkane
relative configuration
10. A molecule with an internal plane of symmetry
geminal
not ignored
meso compound
ketone
11. Creation of long - high molecular weight polymer composed of repeating subunit called monomers. occur through a radical mechanism.
sp3
polymerization
geometric isomers
reducing
12. Sharing of electron between atoms
ionic bond
weak bases
reducing
covalent bond
13. What are the best leaving groups?
not ignored
gauche conformation
sp
weak bases
14. Differ in position of substitutents attached to a double bond or cycloalkane. Cis or trans or e or z
oxidation
Acetylene
geometric isomers
mcpba
15. Di - tri - t - sec - n -
conformational isomer
Ignored
electrophilic addition of HX
sp2
16. Configuration in relation to another chiral molecule. use it to determine if a molecule is an enantiomer - diastereomer - etc
fischer projection
ring strain
enantiomer
relative configuration
17. Transfer of electrions from one atome to another
ionic bond
sp2
electrophilic addition of free radicals
configuration
18. Cleaves double bond in half - it only oxidizes the carbon to an aldehyde under reducing conditions. if ozidizing make same product as KMNO4
saturated hydrocarbon
ketone
racemic mixture
ozonolysis
19. Two hydroxyl groups
eclipsed conformation
propionaldehyde
carboxylic acid
diol
20. Nucleus lover. electron rich species that are attracked to charged atoms
specific rotation
electrophilic addition
nucleophile
allyl
21. O3
ozonolysis
lindlar's catalyst
diastereomers
oxidation
22. When a molecular orbital is formed head to head or tail to tail. all single bonds are tehese.
diastereomers
conformational isomer
electrophile
sigma bond
23. Carbonyl located in middle or somewhere in chane. Named with One
ketone
ethers
mcpba
meso compound
24. How many stereoisomers can a molecule have with n chiral centers
protic solvent
eclipsed conformation
2^n
ketone
25. Y = position of double bond - x is position of triple bond - root is the prefix representing the length of the principal carbon chain
not ignored
y- root - en -x-yne
electrophilic addition of H2O
alcohol
26. One s and two p 120 degree apart
alcohol
Haloalkane
structural isomers
sp2
27. Always receive number one. contain carbonyl and OH group - very oxidized. highest priority functional group.
polymerization
carboxylic acid
diastereomers
anti conformation
28. Name for propanal
formaldehyde
Alkane nomenclature
geometric isomers
propionaldehyde
29. Object that is not superimposable upon mirror image
Combustion
chiral
aprotic solvent
lindlar's catalyst
30. Same molecular formula but different structure
sp
triple bond
isomer
achiral
31. Diol with hydroxyl group on same carbon
geminal
Alkene
meso compound
diol
32. Alkenes oxidzed with kmno4 - if made with cold - dilue - make OH on each side of double bond - diols or glycol in syn orientation
cold potassium permanganate
halogenation
Alkyne
lindlar's catalyst
33. Highest energy no separation. or 120 separation.
optical activity
eclipsed conformation
ionic bond
specific rotation
34. Contain carbon carbon double bonds. Use same root of alkane but end with 'ene'
Alkene
triple bond
polymerization
enantiomer
35. Water can be added to alkenes under acidic conditions. make carbocation. ends with alcohol
sp
electrophilic addition of H2O
isomer
C3H8 + 5O2 = 3CO2 + 4H2O + heat
36. If a compound is able to rotate plane polarized light.
relative configuration
weak bases
ionic bond
optical activity
37. Zn/h or CH3/s with ozonolysis
fischer projection
saturated hydrocarbon
Acetylene
reducing
38. M - chloroperoxybenzoic acid
2^n
mcpba
disproportionation
optical activity
39. Refers to the =CH2 group
torsional strain
Alkyne
methylene
triple bond
40. In which one or morehydrogen atoms are replaced with a halogen atom. via free radical substitution
electrophilic addition of HX
meso compound
anti conformation
halogenation
41. Spatial arrangement of the atoms or groups of a sterioisomer
configuration
potassium permanganate
absolute configuration
hydroboration
42. Ozonolysis under hot acidic kmO4 - e.g. H2O2 condition
ozonolysis
oxidizing
Ignored
Alkane nomenclature
43. Moleculse that have the opposite configuration at their one chiral center. or if multiple chiral centers - must have the opposite configuration at every one of their chiral centers to be enantiomers. identical physical properties and much of the same
isomer
hot - acidic potassium permanganate
y- root - en -x-yne
enantiomer
44. Carbonyl located at the end of the chain named by replacing al with e. e.g. butanal
aldehyde
electrophilic addition of free radicals
cold potassium permanganate
catalytic hydrogenation
45. Name for ethanal
ozonolysis
enantiomer
acetaldehyde
formaldehyde
46. Alphabetical order of alkane rxn
meso compound
carboxylic acid
Alkane
combustion - disproportionation - free - radical substitution - pyrolysis
47. Hydrocarbon with one or more carbon carbon triple bond
halogen
mcpba
specific rotation
alkyne
48. Nonsuperimposable mirror image of chiral objects - a specific steroisomer.
geometric isomers
ozonolysis
enantiomer
molecular orbital
49. Rotations cancel each other out therefore no optical activity
angle strain
racemic mixture
ionic bond
specific rotation
50. E of double bond act as lewis base and react with hydrogen of hx. make carbocation intermediate. use markonikovs rule
geminal
isomer
electrophilic addition of HX
gauche conformation