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MCAT Organic Chemistry
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Subjects
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mcat
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science
Instructions:
Answer 50 questions in 15 minutes.
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Match each statement with the correct term.
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This is a study tool. The 3 wrong answers for each question are randomly chosen from answers to other questions. So, you might find at times the answers obvious, but you will see it re-enforces your understanding as you take the test each time.
1. Not solvated
optical activity
aprotic solvent
sp3
electrophilic addition of free radicals
2. Transfer of electrions from one atome to another
specific rotation
ionic bond
carboxylic acid
absolute configuration
3. Creation of long - high molecular weight polymer composed of repeating subunit called monomers. occur through a radical mechanism.
polymerization
vicinal
diastereomers
absolute configuration
4. N - l - ml - ms
Haloalkane
sigma bond
molecular orbital
quantum numbers
5. O3
aldehyde
acetaldehyde
allyl
ozonolysis
6. Nitrogen containing compound - longest chain attached to nitrogen used in backbone. use e and replace with AMINE. if more complex molecule present - use prefix amino. IF additional group added - use N-
optical activity
initiation propagation termination
carboxylic acid
amines
7. Formed by mixing different types of orbitals
hybridization
peroxycarboxylic acid
electrophilic addition of H2O
hydroboration
8. Propylenes attached to a backbone at the C-3 position. Meaning the double bond at end of the chain and single bonded carbon at rest
sigma bond
allyl
isomer
sp3
9. Common name for ethyne
Acetylene
oxidizing
amines
aprotic solvent
10. Nucleus lover. electron rich species that are attracked to charged atoms
nucleophile
achiral
anti conformation
aprotic solvent
11. Combustion reaction occurs through a radical process
electrophilic addition
C3H8 + 5O2 = 3CO2 + 4H2O + heat
ozonolysis
conformational isomer
12. Compounds with halogen
ring flip
triple bond
Haloalkane
methylene
13. Carbonyl located in middle or somewhere in chane. Named with One
ketone
carboxylic acid
y- root - en -x-yne
electrophile
14. A sigma bond and two pi bonds
initiation propagation termination
angle strain
triple bond
sp2
15. F - CL - Br - I
racemic mixture
catalytic hydrogenation
halogen
weak bases
16. Diol with hydroxyl group on same carbon
electrophilic addition of X2
propionaldehyde
reducing
geminal
17. Nonsuperimposable mirror image of chiral objects - a specific steroisomer.
ozonolysis
enantiomer
quantum numbers
ring flip
18. If reagent has a bunch of oxygen
molecular orbital
oxidation
Haloalkane
combustion - disproportionation - free - radical substitution - pyrolysis
19. Share molecular formula but have different chemical and physical properties
structural isomers
absolute configuration
lindlar's catalyst
racemic mixture
20. One s and two p 120 degree apart
sp2
electrophilic addition
nonbonded strain
geminal
21. Same chemical formula. same atomic connectivity . different in how atoms are arranged in space
electrophilic addition of free radicals
fischer projection
stereoisomers
quantum numbers
22. In which one or morehydrogen atoms are replaced with a halogen atom. via free radical substitution
halogenation
Acetylene
electrophilic addition of H2O
pyrolysis
23. Results when nonadjacent atoms or groups compete for space. dominant source of energy in flagpole interactions of the boat conformation. thus it goes in various conformations like chair boat and twist.
carboxylic acid
nonbonded strain
halogenation
triple bond
24. A molecule with an internal plane of symmetry
amines
meso compound
torsional strain
pyrolysis
25. If a compound is able to rotate plane polarized light.
sp3
optical activity
geometric isomers
methylene
26. No double bonds. it has the maximum number of hydrogens.
Ignored
saturated hydrocarbon
hybridization
diastereomers
27. Name for ethanal
absolute configuration
acetaldehyde
isomer
aldehyde
28. Alphabetical order of alkane rxn
Ignored
combustion - disproportionation - free - radical substitution - pyrolysis
Alkyne
Combustion
29. Refers to the =CH2 group
methylene
pi bond
sigma bond
ring flip
30. Methyl are 60 degrees apart. kinda stable
configuration
reducing
gauche conformation
Acetylene
31. Two hydroxyl groups
diol
2^n
mcpba
ring strain
32. Name for mathanal
mcpba
chiral
molecular orbital
formaldehyde
33. When a molecular orbital is formed head to head or tail to tail. all single bonds are tehese.
ozonolysis
sigma bond
aprotic solvent
structural isomers
34. Two p orbital form pi and third p orbital combine with s to make two sp hybrid. 180 degree apart
alkyne
sp
acetaldehyde
nucleophile
35. Hydrocarbon with one or more carbon carbon triple bond
halogen
C3H8 + 5O2 = 3CO2 + 4H2O + heat
alkyne
Acetylene
36. Charged - need electrons
angle strain
Haloalkane
mcpba
electrophile
37. Zn/h or CH3/s with ozonolysis
reducing
potassium permanganate
acetaldehyde
achiral
38. What is produced when o3 with lialh4 or nabh4
Alkane nomenclature
reducing
alcohol
racemic mixture
39. Functionality is specified by alkoxy- prefix. ROR
aldehyde
nonbonded strain
ethers
absolute configuration
40. Arise from angle strain - torsional strian and nonbonded strain
structural isomers
2^n
ring strain
electrophilic addition of HX
41. Goal is to produce most stable carbocation
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42. Solvents with protons in solution - e.g. water or alcohol. large atoms tend to be better nucleophiles in here because they can shed the solvating protons around them and are more polarizable
carboxylic acid
protic solvent
covalent bond
lindlar's catalyst
43. Diols with hydroxyl group on adjacent carbon
Alkane nomenclature
vicinal
structural isomers
chiral center
44. E of double bond act as lewis base and react with hydrogen of hx. make carbocation intermediate. use markonikovs rule
vicinal
allyl
electrophilic addition of HX
pi bond
45. Y = position of double bond - x is position of triple bond - root is the prefix representing the length of the principal carbon chain
C3H8 + 5O2 = 3CO2 + 4H2O + heat
chiral center
carboxylic acid
y- root - en -x-yne
46. Three different substitutents often have plane of symmetry. and rotation of 180 will allow molecule to be superimposed on mirror image
basicity
gauche conformation
aldehyde
achiral
47. Highest energy no separation. or 120 separation.
sp
sigma bond
Alkane nomenclature
eclipsed conformation
48. Most similar. same molecule only at different points in their rotation. show them with newmans projections
meso compound
diol
conformational isomer
structural isomers
49. Reducing an alkene by adding molecular hydrogen to double bond with aid of metal catalyst. e.g. pt - pd - ni. takes place on surface of metal so it does syn addition
basicity
ring strain
catalytic hydrogenation
sigma bond
50. Is bonded to only one other carbon atom
anti conformation
nucleophile
primary carbon
sp3
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