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MCAT Organic Chemistry
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Subjects
:
mcat
,
science
Instructions:
Answer 50 questions in 15 minutes.
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Match each statement with the correct term.
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1. Charged - need electrons
electrophilic addition of X2
vicinal
electrophile
Alkane nomenclature
2. Hydrocarbon with one or more carbon carbon triple bond
alkyne
electrophilic addition of H2O
optical activity
gauche conformation
3. Configuration in relation to another chiral molecule. use it to determine if a molecule is an enantiomer - diastereomer - etc
ring flip
relative configuration
geminal
oxidizing
4. Use the Greek root for the number of carbons followed by the ending - - ane
Alkane nomenclature
achiral
disproportionation
ozonolysis
5. Palladium or barium sulfate (BaSO4) with quinoline. occur on metal surface - make cis.
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6. What are the best leaving groups?
peroxycarboxylic acid
amines
diol
weak bases
7. Carbon carbon triple bonds. Suffix-yne.
geometric isomers
sp2
carboxylic acid
Alkyne
8. Nucleus lover. electron rich species that are attracked to charged atoms
chiral
alkyne
nucleophile
acetaldehyde
9. Functionality is specified by alkoxy- prefix. ROR
disproportionation
structural isomers
carboxylic acid
ethers
10. Iso - neo - cyclo
not ignored
disproportionation
configuration
stereoisomers
11. Moleculse that have the opposite configuration at their one chiral center. or if multiple chiral centers - must have the opposite configuration at every one of their chiral centers to be enantiomers. identical physical properties and much of the same
carbonyl
alkyne
enantiomer
sp3
12. Most favorable of staggared conformations
racemic mixture
hybridization
ionic bond
anti conformation
13. Kmno4
2^n
potassium permanganate
diol
conformational isomer
14. Same molecular formula but different structure
2^n
nonbonded strain
alcohol
isomer
15. If a compound is able to rotate plane polarized light.
chiral
electrophile
ketone
optical activity
16. Compounds with halogen
Haloalkane
reducing
anti conformation
ring strain
17. Goal is to produce most stable carbocation
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18. When a molecular orbital is formed head to head or tail to tail. all single bonds are tehese.
torsional strain
configuration
sp3
sigma bond
19. When boat flips
potassium permanganate
sp2
ring flip
halogen
20. Occur when a molecule is broken down by heat. used to reduce the avverage molecular weight of heavy oils. c - c - bonds are cleave dand make small chain alkyl radicals that recombine to form different alkanes
markovnikov's rule
combustion - disproportionation - free - radical substitution - pyrolysis
ring flip
pyrolysis
21. N - l - ml - ms
fischer projection
enantiomer
acetaldehyde
quantum numbers
22. Name for ethanal
aprotic solvent
acetaldehyde
weak bases
catalytic hydrogenation
23. Steps of free radical substitution
alcohol
electrophile
diastereomers
initiation propagation termination
24. One s and three p orbitals
electrophile
electrophilic addition of HX
halogen
sp3
25. Reaction of alkane with oxygen to form carbon dioxide - water and heat.
Acetylene
primary carbon
Combustion
isomer
26. Di - tri - t - sec - n -
C3H8 + 5O2 = 3CO2 + 4H2O + heat
Ignored
Combustion
eclipsed conformation
27. O3
absolute configuration
electrophilic addition of HX
markovnikov's rule
ozonolysis
28. One s and two p 120 degree apart
potassium permanganate
sp2
structural isomers
Combustion
29. Diborane add to double bond. boron acts as lewis acid and attaches to less hindered carbon. hydride transferred to adjacent carbon. antimarkonikov - alcohol produced
Alkane nomenclature
hydroboration
ethers
quantum numbers
30. A sigma bond and two pi bonds
disproportionation
achiral
triple bond
combustion - disproportionation - free - radical substitution - pyrolysis
31. Two hydroxyl groups
electrophilic addition
methylene
diol
hot - acidic potassium permanganate
32. Creation of long - high molecular weight polymer composed of repeating subunit called monomers. occur through a radical mechanism.
polymerization
potassium permanganate
not ignored
ring strain
33. How many stereoisomers can a molecule have with n chiral centers
2^n
markovnikov's rule
molecular orbital
quantum numbers
34. Most similar. same molecule only at different points in their rotation. show them with newmans projections
basicity
halogen
structural isomers
conformational isomer
35. Spatial arrangement of the atoms or groups of a sterioisomer
initiation propagation termination
combustion - disproportionation - free - radical substitution - pyrolysis
configuration
cold potassium permanganate
36. If reagent has a bunch of oxygen
relative configuration
oxidation
initiation propagation termination
diastereomers
37. Arise from angle strain - torsional strian and nonbonded strain
acetaldehyde
triple bond
ring strain
formaldehyde
38. A = observed rotation / concentration * length
ozonolysis
protic solvent
allyl
specific rotation
39. Object that is not superimposable upon mirror image
chiral center
chiral
enantiomer
reducing
40. E of double bond act as lewis base and react with hydrogen of hx. make carbocation intermediate. use markonikovs rule
hydroboration
pi bond
gauche conformation
electrophilic addition of HX
41. Highest energy no separation. or 120 separation.
alcohol
structural isomers
eclipsed conformation
disproportionation
42. A radical transfers a hydrogen atom to another radical and makes an alkane and alkene
achiral
electrophile
disproportionation
Vinyl
43. Zn/h or CH3/s with ozonolysis
pi bond
potassium permanganate
reducing
enantiomer
44. Transfer of electrions from one atome to another
y- root - en -x-yne
ionic bond
absolute configuration
carbonyl
45. Alkenes oxidzed with kmno4 - if made with cold - dilue - make OH on each side of double bond - diols or glycol in syn orientation
protic solvent
cold potassium permanganate
quantum numbers
acetaldehyde
46. Differ in position of substitutents attached to a double bond or cycloalkane. Cis or trans or e or z
geometric isomers
catalytic hydrogenation
polymerization
markovnikov's rule
47. Alphabetical order of alkane rxn
combustion - disproportionation - free - radical substitution - pyrolysis
halogenation
vicinal
fischer projection
48. Carbonyl located at the end of the chain named by replacing al with e. e.g. butanal
enantiomer
aprotic solvent
aldehyde
isomer
49. No double bonds. it has the maximum number of hydrogens.
meso compound
triple bond
saturated hydrocarbon
carbonyl
50. Cleaves double bond in half - it only oxidizes the carbon to an aldehyde under reducing conditions. if ozidizing make same product as KMNO4
alkyne
ozonolysis
Acetylene
amines
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