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Test your basic knowledge |
MCAT Organic Chemistry 2
Start Test
Study First
Subjects
:
mcat
,
science
Instructions:
Answer 50 questions in 15 minutes.
If you are not ready to take this test, you can
study here
.
Match each statement with the correct term.
Don't refresh. All questions and answers are randomly picked and ordered every time you load a test.
This is a study tool. The 3 wrong answers for each question are randomly chosen from answers to other questions. So, you might find at times the answers obvious, but you will see it re-enforces your understanding as you take the test each time.
1. Amino group placed on the right of a fischer projection is a?
ketose
D- amino acid
have an R group that is polar enough to H bond - but does no acts an acid or a base
unsaturated fatty acid
2. Epimers of sugars that vary in the configuration of their anomeric carbons
secondary structure
anomers
addition of water across of a bond
disulfide bond
3. Fatty acid w/ one or more double bonds in cis form predominately
amphoteric
basic amino acid has pKa at 6.5 - so it can either be protonated or deprotonated at physiological pH
glucose - alpha -1 -4- glucose
unsaturated fatty acid
4. Name for 6 membered ring
pyranose
basic amino acid has pKa at 6.5 - so it can either be protonated or deprotonated at physiological pH
peptide bond
anomeric carbon
5. PH at which positive and negative charges balance to form a zwitterion
cysteine and methionine
glycogen
pI
1. presence of urea 2. extreme pH 3. extreme temperature 4. changes in salinity
6. Characteristic of basic amino acids
galactose - beta -1 -4- glucose
have amino group in their side chains
long chain of unsubstituted alkanes that end in a carboxylic acid - making them amphipathic
pI
7. Storage form of fatty acid that is composed of 3 esterified fatty acid to a glycerol molecule
furanose
D- amino acid
have acidic carboxylic acid on side chains - w/ pKa around 4
triacylglycerol
8. Right handed helix w/ carboxyl of one amino acid bound to the amine of another amino acid three residues away - proline never resides in this structure b/c it would place a kink in the helix
1. form phospholipids of cellular membranes 2. store energy in adipose tissue 3. produce steroid hormones
C3H6O3 - with one chiral center
alpha helix
starch
9. Adjacent polypeptide strands running in opposite directions in Beta pleated sheet structure
phospholipids
has thiol group that allows it the form disulfide bond
antiparallel beta sheet
glycine - alanine - valine - methionine - leucine - isoleucine - proline - phenylalanine - tryptophan
10. (+) and (-) describe what?
lipases
alpha helix
only achiral amino acid
optical activity
11. What configuration do all naturally occuring amino acids have?
ketose
epimers
isomers
L- configuration
12. Name for 5 membered ring
furanose
van der Waal forces of hydrophobic tails
have amino group in their side chains
modulates fluidity and seeks to maintain optimal fluidity
13. 1.has partial double bond character due to resonance 2. it cannot rotate 3. amide H is someWhat acidic and can H bond
epimers
anomers
only achiral amino acid
Characteristics of the peptide bond
14. (R) and (S) describe what?
mutarotation
primary structure
maltase
absolute configuration
15. Enzyme that hydrolyzes lactose into galactose and glucose into
ketose
lactase
anomers
have alkyl or aromatic side chains and tend to associate w/ each other - rather than water
16. 3 physiological roles of lipids
aldose
D- amino acid
1. form phospholipids of cellular membranes 2. store energy in adipose tissue 3. produce steroid hormones
packing and energy content
17. Characteristics of hydrophobic amino acids
have alkyl or aromatic side chains and tend to associate w/ each other - rather than water
pyranose
long chain of unsubstituted alkanes that end in a carboxylic acid - making them amphipathic
the basic precursor of the molecule (L or D glyceraldehyde)
18. 1. it requires an enzyme to linearize and mutarotate 2. it is not a reducing sugar and give negative Benedict's test
phospholipids
glycine - alanine - valine - methionine - leucine - isoleucine - proline - phenylalanine - tryptophan
2 things about the cyclic form of a sugar as an acetal
cysteine and methionine
19. Energy storage molecule of carbohydrates for plants
glucose - beta -1 -4- glucose
saturated fatty acid
starch
have acidic carboxylic acid on side chains - w/ pKa around 4
20. Energy storage molecule of carbohydrates for animals
glycogen
only amino acid that his a secondary amine
have an R group that is polar enough to H bond - but does no acts an acid or a base
D- glyceraldehyde
21. What describes the affinity of functional groups for a proton?
Ka
L- amino acid
NH2CONH2
maltase
22. Macromolecule that performs a variety of bodily functions and is composed of up to 20 different amino acids
van der Waal forces of hydrophobic tails
CH3COOH
Proteins
NH2CONH2
23. Formula for urea
stereoisomers
7.4
NH2CONH2
maltase
24. Sugar with an aldehyde at the first carbon position
D- amino acid
aldose
only amino acid that his a secondary amine
3 things about the cyclic form of a sugar as a hemiacetal
25. What stabilizes lipid bilayer?
phospholipids
D- glyceraldehyde
glucose - alpha -1 -4- glucose
van der Waal forces of hydrophobic tails
26. 3 carbon triol that forms backbone of triacylglycerol
glycerol
pI
glucose - beta -1 -4- glucose
amphipathic
27. Characteristics of acidic amino acids
isomers
have acidic carboxylic acid on side chains - w/ pKa around 4
modulates fluidity and seeks to maintain optimal fluidity
Ka
28. Structure where H bonds occur btw residues distant from each other - or on a separate chain. backbone is extended rather than coiled
Cause of Amino acid separation in gel electrophoresis
Beta pleated sheet
will have pI of 6
triacylglycerol
29. Covalent bond formed btw carboxyl group of one atom and the amino group of another amino acid in an addition - elimination mechanism - enzymes are required to carry out rxn
glycerol
peptide bond
cysteine and methionine
have an R group that is polar enough to H bond - but does no acts an acid or a base
30. Glycosidic linkage of lactose
NH2CONH2
furanose
galactose - beta -1 -4- glucose
glycine - alanine - valine - methionine - leucine - isoleucine - proline - phenylalanine - tryptophan
31. Glyceraldehyde
C3H6O3 - with one chiral center
saturated fatty acid
all acidic - basic - and polar amino acids
NH2CONH2
32. Interaction btw polypeptide subunits arranged in polypeptide. can be covalent bonds or intermolecular forces - disulfide bond that does not form btw residues on the same protein affect (blank)
tertiary structure
glucose - alpha -1 -2- fructose
D- amino acid
quaternary structure
33. Rule for all amino acids that are nonbasic and nonacidic pertaining to pI value?
unsaturated fatty acid
Cause of Amino acid separation in gel electrophoresis
will have pI of 6
stereoisomers
34. Carbon that in linear form has a carbonyl - or in cyclic form has a hemiacetal or an acetal
glucose - alpha -1 -2- fructose
anomeric carbon
glucose - beta -1 -4- glucose
basic amino acid has pKa at 6.5 - so it can either be protonated or deprotonated at physiological pH
35. Polar amino acids
will have pI of 6
histidine - arginine - lysine
peptide bond
serine - threonine - asparagine - glutamine - cysteine - tyrosine
36. Nonpolar - hydrophobic amino acids
stereoisomers
C3H6O3 - with one chiral center
glycine - alanine - valine - methionine - leucine - isoleucine - proline - phenylalanine - tryptophan
amphoteric
37. The amino acid sequence of a protein that is determined by peptide bond
glycogen
serine - threonine - asparagine - glutamine - cysteine - tyrosine
primary structure
only amino acid that his a secondary amine
38. Amino group placed on the left of a fischer projection is a?
Beta pleated sheet
saturated fatty acid
D- amino acid
L- amino acid
39. Fxn of cholesterol in the membrane?
modulates fluidity and seeks to maintain optimal fluidity
Ka
have amino group in their side chains
ketose
40. Unique feature of cysteine
histidine - arginine - lysine
glycerol
has thiol group that allows it the form disulfide bond
CH3COOH
41. Property of fatty acids where one end is hydrophobic and the other is hydrophilic
lipases
primary structure
2 things about the cyclic form of a sugar as an acetal
amphipathic
42. Enzyme that hydrolyzes maltose into 2 glucose molecules?
maltase
addition of water across of a bond
L- configuration
optical activity
43. Naturally occurring carbohydrates are formed from what?
D- glyceraldehyde
stereoisomers
Ka
Beta pleated sheet
44. Hydrolysis
NH2CONH2
addition of water across of a bond
optical activity
have amino group in their side chains
45. D and L describe what?
stereoisomers
Ka
the basic precursor of the molecule (L or D glyceraldehyde)
lactase
46. Diastereomers that vary in the configuration of 1 chiral center
parallel beta sheet
isoelectric point
the basic precursor of the molecule (L or D glyceraldehyde)
epimers
47. Molecule can act as a base and as an acid
Beta pleated sheet
histidine - arginine - lysine
amphoteric
has thiol group that allows it the form disulfide bond
48. Characteristics of polar amino acids
Ka
have alkyl or aromatic side chains and tend to associate w/ each other - rather than water
2 things about the cyclic form of a sugar as an acetal
have an R group that is polar enough to H bond - but does no acts an acid or a base
49. Acidic amino acids
2 things about the cyclic form of a sugar as an acetal
have acidic carboxylic acid on side chains - w/ pKa around 4
Beta pleated sheet
glutamic acid and aspartic acid
50. Unique feature of glycine
pI
has thiol group that allows it the form disulfide bond
only achiral amino acid
glucose - alpha -1 -2- fructose