SUBJECTS
|
BROWSE
|
CAREER CENTER
|
POPULAR
|
JOIN
|
LOGIN
Business Skills
|
Soft Skills
|
Basic Literacy
|
Certifications
About
|
Help
|
Privacy
|
Terms
|
Email
Search
Test your basic knowledge |
MCAT Organic Chemistry 2
Start Test
Study First
Subjects
:
mcat
,
science
Instructions:
Answer 50 questions in 15 minutes.
If you are not ready to take this test, you can
study here
.
Match each statement with the correct term.
Don't refresh. All questions and answers are randomly picked and ordered every time you load a test.
This is a study tool. The 3 wrong answers for each question are randomly chosen from answers to other questions. So, you might find at times the answers obvious, but you will see it re-enforces your understanding as you take the test each time.
1. Glycosidic linkage of cellulose
glucose - beta -1 -4- glucose
2 things about the cyclic form of a sugar as an acetal
will have pI of 6
modulates fluidity and seeks to maintain optimal fluidity
2. Right handed helix w/ carboxyl of one amino acid bound to the amine of another amino acid three residues away - proline never resides in this structure b/c it would place a kink in the helix
glycerol
alpha helix
absolute configuration
addition of water across of a bond
3. Amino group placed on the right of a fischer projection is a?
amphoteric
will have pI of 6
D- amino acid
only amino acid that his a secondary amine
4. (+) and (-) describe what?
L- amino acid
optical activity
parallel beta sheet
ketose
5. Molecule can act as a base and as an acid
amphoteric
tertiary structure
Beta pleated sheet
anomeric carbon
6. Nonpolar - hydrophobic amino acids
isomers
glycine - alanine - valine - methionine - leucine - isoleucine - proline - phenylalanine - tryptophan
alpha helix
tertiary structure
7. Storage form of fatty acid that is composed of 3 esterified fatty acid to a glycerol molecule
isomers
1. form phospholipids of cellular membranes 2. store energy in adipose tissue 3. produce steroid hormones
long chain of unsubstituted alkanes that end in a carboxylic acid - making them amphipathic
triacylglycerol
8. Energy storage molecule of carbohydrates for animals
glycogen
pI
antiparallel beta sheet
Characteristics of the peptide bond
9. 2 things that accelerate the rate of hydrolysis for peptide cleavage?
starch
antiparallel beta sheet
Characteristics of the peptide bond
1. presence of strong acids 2. proteolytic enzymes
10. Fatty acid structure
only amino acid that his a secondary amine
long chain of unsubstituted alkanes that end in a carboxylic acid - making them amphipathic
1. presence of strong acids 2. proteolytic enzymes
glycogen
11. Rule for all amino acids that are nonbasic and nonacidic pertaining to pI value?
will have pI of 6
have alkyl or aromatic side chains and tend to associate w/ each other - rather than water
D- amino acid
disulfide bond
12. Sugar with an aldehyde at the first carbon position
antiparallel beta sheet
aldose
NH2CONH2
glucose - beta -1 -4- glucose
13. Hydrophilic amino acids
aldose
pI
all acidic - basic - and polar amino acids
glycogen
14. Interaction btw polypeptide subunits arranged in polypeptide. can be covalent bonds or intermolecular forces - disulfide bond that does not form btw residues on the same protein affect (blank)
C3H6O3 - with one chiral center
quaternary structure
peptide bonds and disulfide bonds
maltase
15. Acidic amino acids
glutamic acid and aspartic acid
C3H6O3 - with one chiral center
histidine - arginine - lysine
cysteine and methionine
16. 1. it exists in solution in equilibrium with linear form 2. mutarotation occurs readily 3. it is a reducing sugar - and reacts positively w/ Benedict's reagent
peptide bond
triacylglycerol
3 things about the cyclic form of a sugar as a hemiacetal
glucose - alpha -1 -2- fructose
17. Amino group placed on the left of a fischer projection is a?
L- amino acid
maltase
lipases
secondary structure
18. PH at which the amino acid has a net neutral charge
isoelectric point
have an R group that is polar enough to H bond - but does no acts an acid or a base
galactose - beta -1 -4- glucose
Proteins
19. Fatty acid w/ one or more double bonds in cis form predominately
1. presence of strong acids 2. proteolytic enzymes
all acidic - basic - and polar amino acids
unsaturated fatty acid
Characteristics of the peptide bond
20. Name for 6 membered ring
7.4
pyranose
furanose
saturated fatty acid
21. 4 causes of denaturation of proteins
mutarotation
saturated fatty acid
anomeric carbon
1. presence of urea 2. extreme pH 3. extreme temperature 4. changes in salinity
22. PH at which positive and negative charges balance to form a zwitterion
lipases
glycine - alanine - valine - methionine - leucine - isoleucine - proline - phenylalanine - tryptophan
pI
amphipathic
23. Molecules with the same atoms - but different bonds
lactase
isomers
D- glyceraldehyde
glucose - alpha -1 -2- fructose
24. What describes the affinity of functional groups for a proton?
saturated fatty acid
all acidic - basic - and polar amino acids
Ka
absolute configuration
25. Formula for urea
L- amino acid
lactase
peptide bond
NH2CONH2
26. Adjacent polypeptide strands running in opposite directions in Beta pleated sheet structure
antiparallel beta sheet
furanose
Ka
stereoisomers
27. Energy storage molecule of carbohydrates for plants
starch
modulates fluidity and seeks to maintain optimal fluidity
cysteine and methionine
van der Waal forces of hydrophobic tails
28. Separation is due to charge - with negative charge moving toward positive electrode and positive charge moving toward negative electrode
1. presence of urea 2. extreme pH 3. extreme temperature 4. changes in salinity
have acidic carboxylic acid on side chains - w/ pKa around 4
saturated fatty acid
Cause of Amino acid separation in gel electrophoresis
29. Adjacent polypeptide strands running in the same direction in Beta pleated sheet structure
furanose
long chain of unsubstituted alkanes that end in a carboxylic acid - making them amphipathic
histidine - arginine - lysine
parallel beta sheet
30. 3 physiological roles of lipids
cysteine and methionine
1. form phospholipids of cellular membranes 2. store energy in adipose tissue 3. produce steroid hormones
triacylglycerol
C3H6O3 - with one chiral center
31. Glycosidic linkage of sucrose
glucose - alpha -1 -2- fructose
have alkyl or aromatic side chains and tend to associate w/ each other - rather than water
anomers
amphipathic
32. 1. it requires an enzyme to linearize and mutarotate 2. it is not a reducing sugar and give negative Benedict's test
alpha helix
3 things about the cyclic form of a sugar as a hemiacetal
2 things about the cyclic form of a sugar as an acetal
secondary structure
33. Unique feature of cysteine
has thiol group that allows it the form disulfide bond
have acidic carboxylic acid on side chains - w/ pKa around 4
the basic precursor of the molecule (L or D glyceraldehyde)
D- glyceraldehyde
34. Enzymes that hydrolyze fats
basic amino acid has pKa at 6.5 - so it can either be protonated or deprotonated at physiological pH
lipases
maltase
amphipathic
35. Characteristics of acidic amino acids
NH2CONH2
have acidic carboxylic acid on side chains - w/ pKa around 4
amphoteric
furanose
36. Histidine
basic amino acid has pKa at 6.5 - so it can either be protonated or deprotonated at physiological pH
L- amino acid
quaternary structure
2 things about the cyclic form of a sugar as an acetal
37. Acetic acid formula?
all acidic - basic - and polar amino acids
optical activity
CH3COOH
amphipathic
38. Sulfur containing amino acids
anomeric carbon
cysteine and methionine
tertiary structure
pI
39. Structure where H bonds occur btw residues distant from each other - or on a separate chain. backbone is extended rather than coiled
Beta pleated sheet
D- amino acid
the basic precursor of the molecule (L or D glyceraldehyde)
ketose
40. Interconversion btw two anomers
7.4
mutarotation
phospholipids
glutamic acid and aspartic acid
41. Glyceraldehyde
peptide bonds and disulfide bonds
alpha helix
all acidic - basic - and polar amino acids
C3H6O3 - with one chiral center
42. Enzyme that hydrolyzes maltose into 2 glucose molecules?
isoelectric point
maltase
have acidic carboxylic acid on side chains - w/ pKa around 4
amphipathic
43. Diastereomers that vary in the configuration of 1 chiral center
glucose - alpha -1 -4- glucose
epimers
antiparallel beta sheet
glycine - alanine - valine - methionine - leucine - isoleucine - proline - phenylalanine - tryptophan
44. Fatty acid w/ no double bonds and maximum number of hydrogens
have acidic carboxylic acid on side chains - w/ pKa around 4
stereoisomers
2 things about the cyclic form of a sugar as an acetal
saturated fatty acid
45. Unique feature of proline
will have pI of 6
only amino acid that his a secondary amine
packing and energy content
unsaturated fatty acid
46. Epimers of sugars that vary in the configuration of their anomeric carbons
cysteine and methionine
anomers
pI
amphipathic
47. What configuration do all naturally occuring amino acids have?
D- glyceraldehyde
L- configuration
addition of water across of a bond
Ka
48. Polar amino acids
secondary structure
glycine - alanine - valine - methionine - leucine - isoleucine - proline - phenylalanine - tryptophan
glucose - beta -1 -4- glucose
serine - threonine - asparagine - glutamine - cysteine - tyrosine
49. Enzyme that hydrolyzes lactose into galactose and glucose into
1. presence of strong acids 2. proteolytic enzymes
lactase
Beta pleated sheet
maltase
50. Unique feature of glycine
glutamic acid and aspartic acid
glycerol
pI
only achiral amino acid