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Test your basic knowledge |
MCAT Organic Chemistry 2
Start Test
Study First
Subjects
:
mcat
,
science
Instructions:
Answer 50 questions in 15 minutes.
If you are not ready to take this test, you can
study here
.
Match each statement with the correct term.
Don't refresh. All questions and answers are randomly picked and ordered every time you load a test.
This is a study tool. The 3 wrong answers for each question are randomly chosen from answers to other questions. So, you might find at times the answers obvious, but you will see it re-enforces your understanding as you take the test each time.
1. Acetic acid formula?
CH3COOH
NH2CONH2
ketose
Cause of Amino acid separation in gel electrophoresis
2. 1.has partial double bond character due to resonance 2. it cannot rotate 3. amide H is someWhat acidic and can H bond
cysteine and methionine
Characteristics of the peptide bond
unsaturated fatty acid
Cause of Amino acid separation in gel electrophoresis
3. Sugar with a carbonyl group at the 2 carbon position
lipases
2 things about the cyclic form of a sugar as an acetal
secondary structure
ketose
4. Glycosidic linkage of lactose
ketose
galactose - beta -1 -4- glucose
have acidic carboxylic acid on side chains - w/ pKa around 4
glycogen
5. Characteristics of acidic amino acids
anomers
have acidic carboxylic acid on side chains - w/ pKa around 4
maltase
antiparallel beta sheet
6. Separation is due to charge - with negative charge moving toward positive electrode and positive charge moving toward negative electrode
disulfide bond
unsaturated fatty acid
Cause of Amino acid separation in gel electrophoresis
serine - threonine - asparagine - glutamine - cysteine - tyrosine
7. Naturally occurring carbohydrates are formed from what?
van der Waal forces of hydrophobic tails
D- glyceraldehyde
parallel beta sheet
have acidic carboxylic acid on side chains - w/ pKa around 4
8. Energy storage molecule of carbohydrates for animals
2 things about the cyclic form of a sugar as an acetal
phospholipids
amphoteric
glycogen
9. Acidic amino acids
Characteristics of the peptide bond
pI
glutamic acid and aspartic acid
3 things about the cyclic form of a sugar as a hemiacetal
10. 3 carbon triol that forms backbone of triacylglycerol
isomers
CH3COOH
glycerol
packing and energy content
11. Hydrophilic amino acids
packing and energy content
2 things about the cyclic form of a sugar as an acetal
histidine - arginine - lysine
all acidic - basic - and polar amino acids
12. Glycosidic linkage of sucrose
Cause of Amino acid separation in gel electrophoresis
maltase
glucose - alpha -1 -2- fructose
Proteins
13. Interaction btw polypeptide subunits arranged in polypeptide. can be covalent bonds or intermolecular forces - disulfide bond that does not form btw residues on the same protein affect (blank)
starch
aldose
histidine - arginine - lysine
quaternary structure
14. 2 reasons why fats have more efficient energy stores than carbs
Characteristics of the peptide bond
phospholipids
glycerol
packing and energy content
15. Name for 5 membered ring
epimers
has thiol group that allows it the form disulfide bond
furanose
ketose
16. Structure where H bonds occur btw residues distant from each other - or on a separate chain. backbone is extended rather than coiled
furanose
CH3COOH
Beta pleated sheet
3 things about the cyclic form of a sugar as a hemiacetal
17. Physiological pH
starch
cysteine and methionine
long chain of unsubstituted alkanes that end in a carboxylic acid - making them amphipathic
7.4
18. Hydrophobic and hydrophilic interactions btw amino acids more distant from each other on the polypeptide chain
CH3COOH
tertiary structure
lipases
glucose - alpha -1 -2- fructose
19. Molecules with the same atoms and same bonds - but different bond geometries; can either be enantiomers or diastereomers
D- glyceraldehyde
stereoisomers
2 things about the cyclic form of a sugar as an acetal
addition of water across of a bond
20. Unique feature of glycine
van der Waal forces of hydrophobic tails
glucose - alpha -1 -4- glucose
addition of water across of a bond
only achiral amino acid
21. Sugar with an aldehyde at the first carbon position
2 things about the cyclic form of a sugar as an acetal
aldose
glycogen
serine - threonine - asparagine - glutamine - cysteine - tyrosine
22. Rule for all amino acids that are nonbasic and nonacidic pertaining to pI value?
secondary structure
glucose - alpha -1 -2- fructose
will have pI of 6
has thiol group that allows it the form disulfide bond
23. Fatty acid structure
long chain of unsubstituted alkanes that end in a carboxylic acid - making them amphipathic
peptide bonds and disulfide bonds
glucose - alpha -1 -4- glucose
all acidic - basic - and polar amino acids
24. Histidine
have acidic carboxylic acid on side chains - w/ pKa around 4
basic amino acid has pKa at 6.5 - so it can either be protonated or deprotonated at physiological pH
amphipathic
3 things about the cyclic form of a sugar as a hemiacetal
25. Fatty acid w/ one or more double bonds in cis form predominately
unsaturated fatty acid
maltase
1. presence of urea 2. extreme pH 3. extreme temperature 4. changes in salinity
CH3COOH
26. Property of fatty acids where one end is hydrophobic and the other is hydrophilic
1. presence of urea 2. extreme pH 3. extreme temperature 4. changes in salinity
amphipathic
isoelectric point
Characteristics of the peptide bond
27. Unique feature of cysteine
L- configuration
tertiary structure
has thiol group that allows it the form disulfide bond
alpha helix
28. 2 covalent bonds formed in proteins
have an R group that is polar enough to H bond - but does no acts an acid or a base
aldose
van der Waal forces of hydrophobic tails
peptide bonds and disulfide bonds
29. Name for 6 membered ring
glutamic acid and aspartic acid
aldose
1. presence of urea 2. extreme pH 3. extreme temperature 4. changes in salinity
pyranose
30. Characteristic of basic amino acids
glycogen
1. presence of strong acids 2. proteolytic enzymes
have amino group in their side chains
packing and energy content
31. (R) and (S) describe what?
packing and energy content
absolute configuration
glucose - beta -1 -4- glucose
the basic precursor of the molecule (L or D glyceraldehyde)
32. Molecule can act as a base and as an acid
only achiral amino acid
stereoisomers
amphoteric
van der Waal forces of hydrophobic tails
33. Fatty acid w/ no double bonds and maximum number of hydrogens
CH3COOH
saturated fatty acid
aldose
1. presence of strong acids 2. proteolytic enzymes
34. Unique feature of proline
pyranose
optical activity
saturated fatty acid
only amino acid that his a secondary amine
35. Fxn of cholesterol in the membrane?
addition of water across of a bond
ketose
modulates fluidity and seeks to maintain optimal fluidity
Cause of Amino acid separation in gel electrophoresis
36. Enzyme that hydrolyzes maltose into 2 glucose molecules?
all acidic - basic - and polar amino acids
maltase
have an R group that is polar enough to H bond - but does no acts an acid or a base
1. presence of urea 2. extreme pH 3. extreme temperature 4. changes in salinity
37. Adjacent polypeptide strands running in the same direction in Beta pleated sheet structure
long chain of unsubstituted alkanes that end in a carboxylic acid - making them amphipathic
only amino acid that his a secondary amine
optical activity
parallel beta sheet
38. Hydrolysis
peptide bond
absolute configuration
optical activity
addition of water across of a bond
39. Energy storage molecule of carbohydrates for plants
alpha helix
lactase
starch
L- configuration
40. Interconversion btw two anomers
maltase
1. presence of strong acids 2. proteolytic enzymes
mutarotation
furanose
41. Amino group placed on the left of a fischer projection is a?
cysteine and methionine
2 things about the cyclic form of a sugar as an acetal
L- amino acid
addition of water across of a bond
42. D and L describe what?
L- configuration
isomers
stereoisomers
the basic precursor of the molecule (L or D glyceraldehyde)
43. Characteristics of hydrophobic amino acids
stereoisomers
peptide bonds and disulfide bonds
parallel beta sheet
have alkyl or aromatic side chains and tend to associate w/ each other - rather than water
44. Initial folding of proteins into shapes stabilized by H bonds btw amino and carboxyl groups of backbone
galactose - beta -1 -4- glucose
packing and energy content
secondary structure
peptide bond
45. Polar amino acids
van der Waal forces of hydrophobic tails
unsaturated fatty acid
serine - threonine - asparagine - glutamine - cysteine - tyrosine
stereoisomers
46. Right handed helix w/ carboxyl of one amino acid bound to the amine of another amino acid three residues away - proline never resides in this structure b/c it would place a kink in the helix
glucose - alpha -1 -4- glucose
stereoisomers
alpha helix
long chain of unsubstituted alkanes that end in a carboxylic acid - making them amphipathic
47. Glycosidic linkage of maltose
alpha helix
glucose - alpha -1 -4- glucose
have amino group in their side chains
tertiary structure
48. PH at which the amino acid has a net neutral charge
NH2CONH2
isoelectric point
1. presence of strong acids 2. proteolytic enzymes
secondary structure
49. 1. it requires an enzyme to linearize and mutarotate 2. it is not a reducing sugar and give negative Benedict's test
unsaturated fatty acid
2 things about the cyclic form of a sugar as an acetal
amphipathic
Cause of Amino acid separation in gel electrophoresis
50. 1. it exists in solution in equilibrium with linear form 2. mutarotation occurs readily 3. it is a reducing sugar - and reacts positively w/ Benedict's reagent
3 things about the cyclic form of a sugar as a hemiacetal
basic amino acid has pKa at 6.5 - so it can either be protonated or deprotonated at physiological pH
long chain of unsubstituted alkanes that end in a carboxylic acid - making them amphipathic
addition of water across of a bond