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Test your basic knowledge |
MCAT Organic Chemistry 2
Start Test
Study First
Subjects
:
mcat
,
science
Instructions:
Answer 50 questions in 15 minutes.
If you are not ready to take this test, you can
study here
.
Match each statement with the correct term.
Don't refresh. All questions and answers are randomly picked and ordered every time you load a test.
This is a study tool. The 3 wrong answers for each question are randomly chosen from answers to other questions. So, you might find at times the answers obvious, but you will see it re-enforces your understanding as you take the test each time.
1. PH at which positive and negative charges balance to form a zwitterion
pI
have an R group that is polar enough to H bond - but does no acts an acid or a base
1. presence of strong acids 2. proteolytic enzymes
triacylglycerol
2. Sulfur containing amino acids
histidine - arginine - lysine
cysteine and methionine
amphipathic
have alkyl or aromatic side chains and tend to associate w/ each other - rather than water
3. (+) and (-) describe what?
lactase
L- amino acid
optical activity
triacylglycerol
4. Carbon that in linear form has a carbonyl - or in cyclic form has a hemiacetal or an acetal
packing and energy content
optical activity
anomeric carbon
isomers
5. Energy storage molecule of carbohydrates for plants
will have pI of 6
only amino acid that his a secondary amine
amphipathic
starch
6. Enzymes that hydrolyze fats
maltase
lipases
basic amino acid has pKa at 6.5 - so it can either be protonated or deprotonated at physiological pH
glycogen
7. Structure where H bonds occur btw residues distant from each other - or on a separate chain. backbone is extended rather than coiled
peptide bond
pI
glutamic acid and aspartic acid
Beta pleated sheet
8. Naturally occurring carbohydrates are formed from what?
pyranose
stereoisomers
phospholipids
D- glyceraldehyde
9. What describes the affinity of functional groups for a proton?
Ka
alpha helix
quaternary structure
van der Waal forces of hydrophobic tails
10. Property of fatty acids where one end is hydrophobic and the other is hydrophilic
glycerol
L- amino acid
amphipathic
mutarotation
11. Separation is due to charge - with negative charge moving toward positive electrode and positive charge moving toward negative electrode
galactose - beta -1 -4- glucose
1. form phospholipids of cellular membranes 2. store energy in adipose tissue 3. produce steroid hormones
glucose - alpha -1 -4- glucose
Cause of Amino acid separation in gel electrophoresis
12. Adjacent polypeptide strands running in the same direction in Beta pleated sheet structure
packing and energy content
parallel beta sheet
histidine - arginine - lysine
glycogen
13. Enzyme that hydrolyzes maltose into 2 glucose molecules?
C3H6O3 - with one chiral center
glucose - beta -1 -4- glucose
maltase
glycerol
14. 2 covalent bonds formed in proteins
saturated fatty acid
have amino group in their side chains
peptide bonds and disulfide bonds
only amino acid that his a secondary amine
15. Polar amino acids
serine - threonine - asparagine - glutamine - cysteine - tyrosine
will have pI of 6
triacylglycerol
Cause of Amino acid separation in gel electrophoresis
16. Unique feature of glycine
glucose - alpha -1 -2- fructose
Beta pleated sheet
parallel beta sheet
only achiral amino acid
17. Unique feature of cysteine
galactose - beta -1 -4- glucose
saturated fatty acid
has thiol group that allows it the form disulfide bond
will have pI of 6
18. Name for 6 membered ring
pyranose
epimers
ketose
peptide bonds and disulfide bonds
19. Fxn of cholesterol in the membrane?
anomeric carbon
modulates fluidity and seeks to maintain optimal fluidity
Ka
1. presence of strong acids 2. proteolytic enzymes
20. Glyceraldehyde
disulfide bond
alpha helix
C3H6O3 - with one chiral center
secondary structure
21. Glycosidic linkage of maltose
unsaturated fatty acid
primary structure
amphoteric
glucose - alpha -1 -4- glucose
22. Nonpolar - hydrophobic amino acids
glycine - alanine - valine - methionine - leucine - isoleucine - proline - phenylalanine - tryptophan
primary structure
aldose
2 things about the cyclic form of a sugar as an acetal
23. Characteristics of polar amino acids
basic amino acid has pKa at 6.5 - so it can either be protonated or deprotonated at physiological pH
have an R group that is polar enough to H bond - but does no acts an acid or a base
histidine - arginine - lysine
only achiral amino acid
24. 2 things that accelerate the rate of hydrolysis for peptide cleavage?
pI
Ka
1. presence of strong acids 2. proteolytic enzymes
have alkyl or aromatic side chains and tend to associate w/ each other - rather than water
25. Generated btw either thiols on different proteins or thiols on the same protein
only achiral amino acid
disulfide bond
L- amino acid
all acidic - basic - and polar amino acids
26. Rule for all amino acids that are nonbasic and nonacidic pertaining to pI value?
peptide bond
basic amino acid has pKa at 6.5 - so it can either be protonated or deprotonated at physiological pH
D- amino acid
will have pI of 6
27. Amino group placed on the left of a fischer projection is a?
histidine - arginine - lysine
only amino acid that his a secondary amine
amphoteric
L- amino acid
28. Basic amino acids
glucose - beta -1 -4- glucose
Beta pleated sheet
pI
histidine - arginine - lysine
29. (R) and (S) describe what?
NH2CONH2
pI
aldose
absolute configuration
30. Physiological pH
glutamic acid and aspartic acid
7.4
modulates fluidity and seeks to maintain optimal fluidity
1. presence of urea 2. extreme pH 3. extreme temperature 4. changes in salinity
31. Glycosidic linkage of sucrose
glucose - alpha -1 -2- fructose
2 things about the cyclic form of a sugar as an acetal
anomers
optical activity
32. Adjacent polypeptide strands running in opposite directions in Beta pleated sheet structure
stereoisomers
antiparallel beta sheet
have alkyl or aromatic side chains and tend to associate w/ each other - rather than water
furanose
33. 1. it exists in solution in equilibrium with linear form 2. mutarotation occurs readily 3. it is a reducing sugar - and reacts positively w/ Benedict's reagent
parallel beta sheet
3 things about the cyclic form of a sugar as a hemiacetal
NH2CONH2
modulates fluidity and seeks to maintain optimal fluidity
34. Covalent bond formed btw carboxyl group of one atom and the amino group of another amino acid in an addition - elimination mechanism - enzymes are required to carry out rxn
packing and energy content
glucose - beta -1 -4- glucose
NH2CONH2
peptide bond
35. PH at which the amino acid has a net neutral charge
saturated fatty acid
isoelectric point
cysteine and methionine
parallel beta sheet
36. 3 carbon triol that forms backbone of triacylglycerol
glycerol
quaternary structure
have acidic carboxylic acid on side chains - w/ pKa around 4
glucose - alpha -1 -4- glucose
37. 3 physiological roles of lipids
amphoteric
anomers
1. form phospholipids of cellular membranes 2. store energy in adipose tissue 3. produce steroid hormones
1. presence of urea 2. extreme pH 3. extreme temperature 4. changes in salinity
38. Characteristics of hydrophobic amino acids
all acidic - basic - and polar amino acids
have alkyl or aromatic side chains and tend to associate w/ each other - rather than water
lipases
Ka
39. 2 reasons why fats have more efficient energy stores than carbs
isomers
packing and energy content
unsaturated fatty acid
glutamic acid and aspartic acid
40. Acidic amino acids
glutamic acid and aspartic acid
secondary structure
ketose
peptide bond
41. Glycosidic linkage of lactose
NH2CONH2
packing and energy content
galactose - beta -1 -4- glucose
mutarotation
42. Characteristic of basic amino acids
furanose
isoelectric point
have amino group in their side chains
tertiary structure
43. Histidine
cysteine and methionine
amphipathic
aldose
basic amino acid has pKa at 6.5 - so it can either be protonated or deprotonated at physiological pH
44. 1. it requires an enzyme to linearize and mutarotate 2. it is not a reducing sugar and give negative Benedict's test
amphoteric
phospholipids
glutamic acid and aspartic acid
2 things about the cyclic form of a sugar as an acetal
45. Fatty acid w/ one or more double bonds in cis form predominately
have alkyl or aromatic side chains and tend to associate w/ each other - rather than water
packing and energy content
NH2CONH2
unsaturated fatty acid
46. Hydrophilic amino acids
1. form phospholipids of cellular membranes 2. store energy in adipose tissue 3. produce steroid hormones
D- amino acid
anomeric carbon
all acidic - basic - and polar amino acids
47. Enzyme that hydrolyzes lactose into galactose and glucose into
quaternary structure
unsaturated fatty acid
lactase
amphoteric
48. Molecule can act as a base and as an acid
glycerol
D- glyceraldehyde
mutarotation
amphoteric
49. What stabilizes lipid bilayer?
phospholipids
primary structure
van der Waal forces of hydrophobic tails
Cause of Amino acid separation in gel electrophoresis
50. Initial folding of proteins into shapes stabilized by H bonds btw amino and carboxyl groups of backbone
secondary structure
glucose - alpha -1 -2- fructose
anomers
peptide bond