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Test your basic knowledge |
MCAT Organic Chemistry 2
Start Test
Study First
Subjects
:
mcat
,
science
Instructions:
Answer 50 questions in 15 minutes.
If you are not ready to take this test, you can
study here
.
Match each statement with the correct term.
Don't refresh. All questions and answers are randomly picked and ordered every time you load a test.
This is a study tool. The 3 wrong answers for each question are randomly chosen from answers to other questions. So, you might find at times the answers obvious, but you will see it re-enforces your understanding as you take the test each time.
1. Property of fatty acids where one end is hydrophobic and the other is hydrophilic
saturated fatty acid
anomers
tertiary structure
amphipathic
2. Fatty acid w/ one or more double bonds in cis form predominately
unsaturated fatty acid
optical activity
L- configuration
stereoisomers
3. Enzyme that hydrolyzes lactose into galactose and glucose into
lactase
peptide bonds and disulfide bonds
optical activity
has thiol group that allows it the form disulfide bond
4. Hydrophobic and hydrophilic interactions btw amino acids more distant from each other on the polypeptide chain
pyranose
tertiary structure
quaternary structure
pI
5. PH at which the amino acid has a net neutral charge
have alkyl or aromatic side chains and tend to associate w/ each other - rather than water
absolute configuration
disulfide bond
isoelectric point
6. Diastereomers that vary in the configuration of 1 chiral center
phospholipids
epimers
disulfide bond
amphipathic
7. What kind of lipids compromise the lipid bilayer?
glucose - alpha -1 -4- glucose
3 things about the cyclic form of a sugar as a hemiacetal
optical activity
phospholipids
8. (+) and (-) describe what?
starch
unsaturated fatty acid
optical activity
stereoisomers
9. Structure where H bonds occur btw residues distant from each other - or on a separate chain. backbone is extended rather than coiled
Beta pleated sheet
glycerol
glycine - alanine - valine - methionine - leucine - isoleucine - proline - phenylalanine - tryptophan
amphipathic
10. Glycosidic linkage of cellulose
unsaturated fatty acid
packing and energy content
glucose - beta -1 -4- glucose
lactase
11. Energy storage molecule of carbohydrates for animals
mutarotation
triacylglycerol
glycogen
lipases
12. Glycosidic linkage of sucrose
glucose - alpha -1 -2- fructose
modulates fluidity and seeks to maintain optimal fluidity
C3H6O3 - with one chiral center
all acidic - basic - and polar amino acids
13. 2 reasons why fats have more efficient energy stores than carbs
have amino group in their side chains
packing and energy content
3 things about the cyclic form of a sugar as a hemiacetal
parallel beta sheet
14. Sugar with a carbonyl group at the 2 carbon position
amphoteric
the basic precursor of the molecule (L or D glyceraldehyde)
ketose
have an R group that is polar enough to H bond - but does no acts an acid or a base
15. Polar amino acids
secondary structure
tertiary structure
serine - threonine - asparagine - glutamine - cysteine - tyrosine
aldose
16. Adjacent polypeptide strands running in opposite directions in Beta pleated sheet structure
have amino group in their side chains
antiparallel beta sheet
NH2CONH2
alpha helix
17. Molecules with the same atoms and same bonds - but different bond geometries; can either be enantiomers or diastereomers
isoelectric point
disulfide bond
have an R group that is polar enough to H bond - but does no acts an acid or a base
stereoisomers
18. D and L describe what?
the basic precursor of the molecule (L or D glyceraldehyde)
L- amino acid
only achiral amino acid
glucose - alpha -1 -2- fructose
19. Characteristics of polar amino acids
primary structure
C3H6O3 - with one chiral center
antiparallel beta sheet
have an R group that is polar enough to H bond - but does no acts an acid or a base
20. Hydrolysis
galactose - beta -1 -4- glucose
antiparallel beta sheet
have an R group that is polar enough to H bond - but does no acts an acid or a base
addition of water across of a bond
21. Carbon that in linear form has a carbonyl - or in cyclic form has a hemiacetal or an acetal
anomeric carbon
basic amino acid has pKa at 6.5 - so it can either be protonated or deprotonated at physiological pH
L- amino acid
Ka
22. 2 covalent bonds formed in proteins
1. form phospholipids of cellular membranes 2. store energy in adipose tissue 3. produce steroid hormones
mutarotation
peptide bonds and disulfide bonds
amphipathic
23. Generated btw either thiols on different proteins or thiols on the same protein
glucose - alpha -1 -4- glucose
disulfide bond
triacylglycerol
quaternary structure
24. Interconversion btw two anomers
Beta pleated sheet
have amino group in their side chains
mutarotation
aldose
25. Nonpolar - hydrophobic amino acids
peptide bond
glycine - alanine - valine - methionine - leucine - isoleucine - proline - phenylalanine - tryptophan
glucose - beta -1 -4- glucose
2 things about the cyclic form of a sugar as an acetal
26. Unique feature of glycine
pI
absolute configuration
only achiral amino acid
glucose - alpha -1 -2- fructose
27. Glyceraldehyde
C3H6O3 - with one chiral center
histidine - arginine - lysine
peptide bonds and disulfide bonds
have alkyl or aromatic side chains and tend to associate w/ each other - rather than water
28. Energy storage molecule of carbohydrates for plants
van der Waal forces of hydrophobic tails
1. form phospholipids of cellular membranes 2. store energy in adipose tissue 3. produce steroid hormones
starch
Proteins
29. Sugar with an aldehyde at the first carbon position
aldose
quaternary structure
Characteristics of the peptide bond
long chain of unsubstituted alkanes that end in a carboxylic acid - making them amphipathic
30. Enzyme that hydrolyzes maltose into 2 glucose molecules?
parallel beta sheet
lactase
absolute configuration
maltase
31. Fxn of cholesterol in the membrane?
unsaturated fatty acid
modulates fluidity and seeks to maintain optimal fluidity
the basic precursor of the molecule (L or D glyceraldehyde)
long chain of unsubstituted alkanes that end in a carboxylic acid - making them amphipathic
32. Naturally occurring carbohydrates are formed from what?
1. presence of strong acids 2. proteolytic enzymes
3 things about the cyclic form of a sugar as a hemiacetal
D- glyceraldehyde
glycogen
33. Fatty acid structure
have amino group in their side chains
long chain of unsubstituted alkanes that end in a carboxylic acid - making them amphipathic
antiparallel beta sheet
peptide bonds and disulfide bonds
34. Basic amino acids
van der Waal forces of hydrophobic tails
histidine - arginine - lysine
epimers
3 things about the cyclic form of a sugar as a hemiacetal
35. Amino group placed on the left of a fischer projection is a?
3 things about the cyclic form of a sugar as a hemiacetal
1. form phospholipids of cellular membranes 2. store energy in adipose tissue 3. produce steroid hormones
L- amino acid
cysteine and methionine
36. Glycosidic linkage of maltose
3 things about the cyclic form of a sugar as a hemiacetal
D- glyceraldehyde
glucose - alpha -1 -4- glucose
furanose
37. Interaction btw polypeptide subunits arranged in polypeptide. can be covalent bonds or intermolecular forces - disulfide bond that does not form btw residues on the same protein affect (blank)
quaternary structure
unsaturated fatty acid
long chain of unsubstituted alkanes that end in a carboxylic acid - making them amphipathic
glycine - alanine - valine - methionine - leucine - isoleucine - proline - phenylalanine - tryptophan
38. (R) and (S) describe what?
absolute configuration
optical activity
parallel beta sheet
basic amino acid has pKa at 6.5 - so it can either be protonated or deprotonated at physiological pH
39. PH at which positive and negative charges balance to form a zwitterion
Proteins
ketose
tertiary structure
pI
40. Enzymes that hydrolyze fats
amphoteric
will have pI of 6
isoelectric point
lipases
41. Acetic acid formula?
CH3COOH
pyranose
isoelectric point
primary structure
42. Formula for urea
NH2CONH2
pI
antiparallel beta sheet
unsaturated fatty acid
43. Physiological pH
glucose - beta -1 -4- glucose
1. form phospholipids of cellular membranes 2. store energy in adipose tissue 3. produce steroid hormones
7.4
Beta pleated sheet
44. Name for 5 membered ring
mutarotation
glucose - beta -1 -4- glucose
CH3COOH
furanose
45. Initial folding of proteins into shapes stabilized by H bonds btw amino and carboxyl groups of backbone
histidine - arginine - lysine
secondary structure
peptide bonds and disulfide bonds
alpha helix
46. Characteristics of hydrophobic amino acids
peptide bond
triacylglycerol
have alkyl or aromatic side chains and tend to associate w/ each other - rather than water
tertiary structure
47. 1.has partial double bond character due to resonance 2. it cannot rotate 3. amide H is someWhat acidic and can H bond
galactose - beta -1 -4- glucose
Characteristics of the peptide bond
alpha helix
histidine - arginine - lysine
48. Epimers of sugars that vary in the configuration of their anomeric carbons
glucose - alpha -1 -4- glucose
anomers
cysteine and methionine
1. form phospholipids of cellular membranes 2. store energy in adipose tissue 3. produce steroid hormones
49. Histidine
isomers
amphipathic
only achiral amino acid
basic amino acid has pKa at 6.5 - so it can either be protonated or deprotonated at physiological pH
50. Characteristic of basic amino acids
has thiol group that allows it the form disulfide bond
isoelectric point
have amino group in their side chains
maltase