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Test your basic knowledge |
MCAT Organic Chemistry 2
Start Test
Study First
Subjects
:
mcat
,
science
Instructions:
Answer 50 questions in 15 minutes.
If you are not ready to take this test, you can
study here
.
Match each statement with the correct term.
Don't refresh. All questions and answers are randomly picked and ordered every time you load a test.
This is a study tool. The 3 wrong answers for each question are randomly chosen from answers to other questions. So, you might find at times the answers obvious, but you will see it re-enforces your understanding as you take the test each time.
1. Property of fatty acids where one end is hydrophobic and the other is hydrophilic
maltase
2 things about the cyclic form of a sugar as an acetal
isomers
amphipathic
2. Unique feature of proline
only amino acid that his a secondary amine
cysteine and methionine
triacylglycerol
L- configuration
3. Interconversion btw two anomers
glucose - beta -1 -4- glucose
the basic precursor of the molecule (L or D glyceraldehyde)
mutarotation
D- glyceraldehyde
4. Molecule can act as a base and as an acid
absolute configuration
lipases
amphoteric
all acidic - basic - and polar amino acids
5. Enzyme that hydrolyzes lactose into galactose and glucose into
lactase
phospholipids
epimers
NH2CONH2
6. Sugar with a carbonyl group at the 2 carbon position
1. presence of strong acids 2. proteolytic enzymes
modulates fluidity and seeks to maintain optimal fluidity
ketose
3 things about the cyclic form of a sugar as a hemiacetal
7. Initial folding of proteins into shapes stabilized by H bonds btw amino and carboxyl groups of backbone
secondary structure
parallel beta sheet
only amino acid that his a secondary amine
serine - threonine - asparagine - glutamine - cysteine - tyrosine
8. 1. it exists in solution in equilibrium with linear form 2. mutarotation occurs readily 3. it is a reducing sugar - and reacts positively w/ Benedict's reagent
Cause of Amino acid separation in gel electrophoresis
Beta pleated sheet
3 things about the cyclic form of a sugar as a hemiacetal
absolute configuration
9. The amino acid sequence of a protein that is determined by peptide bond
glycogen
unsaturated fatty acid
NH2CONH2
primary structure
10. Interaction btw polypeptide subunits arranged in polypeptide. can be covalent bonds or intermolecular forces - disulfide bond that does not form btw residues on the same protein affect (blank)
only achiral amino acid
have acidic carboxylic acid on side chains - w/ pKa around 4
quaternary structure
galactose - beta -1 -4- glucose
11. Glycosidic linkage of sucrose
amphipathic
Proteins
triacylglycerol
glucose - alpha -1 -2- fructose
12. PH at which positive and negative charges balance to form a zwitterion
pI
glycogen
1. presence of urea 2. extreme pH 3. extreme temperature 4. changes in salinity
anomers
13. Enzyme that hydrolyzes maltose into 2 glucose molecules?
stereoisomers
D- glyceraldehyde
maltase
NH2CONH2
14. Glycosidic linkage of lactose
glucose - alpha -1 -2- fructose
CH3COOH
galactose - beta -1 -4- glucose
L- configuration
15. Adjacent polypeptide strands running in opposite directions in Beta pleated sheet structure
antiparallel beta sheet
D- amino acid
Characteristics of the peptide bond
amphoteric
16. Right handed helix w/ carboxyl of one amino acid bound to the amine of another amino acid three residues away - proline never resides in this structure b/c it would place a kink in the helix
Characteristics of the peptide bond
alpha helix
glutamic acid and aspartic acid
furanose
17. Energy storage molecule of carbohydrates for animals
triacylglycerol
isoelectric point
has thiol group that allows it the form disulfide bond
glycogen
18. Unique feature of cysteine
has thiol group that allows it the form disulfide bond
lipases
all acidic - basic - and polar amino acids
aldose
19. (R) and (S) describe what?
histidine - arginine - lysine
optical activity
absolute configuration
glycerol
20. What describes the affinity of functional groups for a proton?
Ka
have acidic carboxylic acid on side chains - w/ pKa around 4
van der Waal forces of hydrophobic tails
2 things about the cyclic form of a sugar as an acetal
21. What kind of lipids compromise the lipid bilayer?
parallel beta sheet
quaternary structure
long chain of unsubstituted alkanes that end in a carboxylic acid - making them amphipathic
phospholipids
22. Fatty acid structure
van der Waal forces of hydrophobic tails
only amino acid that his a secondary amine
long chain of unsubstituted alkanes that end in a carboxylic acid - making them amphipathic
glucose - alpha -1 -2- fructose
23. (+) and (-) describe what?
glucose - alpha -1 -2- fructose
phospholipids
optical activity
unsaturated fatty acid
24. Macromolecule that performs a variety of bodily functions and is composed of up to 20 different amino acids
serine - threonine - asparagine - glutamine - cysteine - tyrosine
quaternary structure
Proteins
glycine - alanine - valine - methionine - leucine - isoleucine - proline - phenylalanine - tryptophan
25. Storage form of fatty acid that is composed of 3 esterified fatty acid to a glycerol molecule
triacylglycerol
peptide bonds and disulfide bonds
CH3COOH
have an R group that is polar enough to H bond - but does no acts an acid or a base
26. Generated btw either thiols on different proteins or thiols on the same protein
disulfide bond
L- configuration
epimers
have acidic carboxylic acid on side chains - w/ pKa around 4
27. 3 carbon triol that forms backbone of triacylglycerol
glycerol
CH3COOH
stereoisomers
glycogen
28. Sulfur containing amino acids
the basic precursor of the molecule (L or D glyceraldehyde)
glucose - alpha -1 -4- glucose
mutarotation
cysteine and methionine
29. D and L describe what?
isoelectric point
1. presence of strong acids 2. proteolytic enzymes
glycerol
the basic precursor of the molecule (L or D glyceraldehyde)
30. Basic amino acids
only amino acid that his a secondary amine
histidine - arginine - lysine
2 things about the cyclic form of a sugar as an acetal
pyranose
31. Histidine
basic amino acid has pKa at 6.5 - so it can either be protonated or deprotonated at physiological pH
phospholipids
packing and energy content
maltase
32. 4 causes of denaturation of proteins
1. presence of urea 2. extreme pH 3. extreme temperature 4. changes in salinity
triacylglycerol
glycerol
amphipathic
33. Amino group placed on the left of a fischer projection is a?
L- amino acid
will have pI of 6
modulates fluidity and seeks to maintain optimal fluidity
1. form phospholipids of cellular membranes 2. store energy in adipose tissue 3. produce steroid hormones
34. Acidic amino acids
long chain of unsubstituted alkanes that end in a carboxylic acid - making them amphipathic
glutamic acid and aspartic acid
have amino group in their side chains
quaternary structure
35. Glycosidic linkage of maltose
addition of water across of a bond
glucose - alpha -1 -4- glucose
packing and energy content
van der Waal forces of hydrophobic tails
36. Characteristics of hydrophobic amino acids
glucose - alpha -1 -4- glucose
7.4
stereoisomers
have alkyl or aromatic side chains and tend to associate w/ each other - rather than water
37. 2 things that accelerate the rate of hydrolysis for peptide cleavage?
unsaturated fatty acid
packing and energy content
Cause of Amino acid separation in gel electrophoresis
1. presence of strong acids 2. proteolytic enzymes
38. Adjacent polypeptide strands running in the same direction in Beta pleated sheet structure
parallel beta sheet
3 things about the cyclic form of a sugar as a hemiacetal
ketose
Characteristics of the peptide bond
39. Fxn of cholesterol in the membrane?
ketose
modulates fluidity and seeks to maintain optimal fluidity
L- configuration
stereoisomers
40. Nonpolar - hydrophobic amino acids
anomeric carbon
Proteins
glycine - alanine - valine - methionine - leucine - isoleucine - proline - phenylalanine - tryptophan
have amino group in their side chains
41. What stabilizes lipid bilayer?
1. form phospholipids of cellular membranes 2. store energy in adipose tissue 3. produce steroid hormones
furanose
van der Waal forces of hydrophobic tails
Ka
42. Naturally occurring carbohydrates are formed from what?
all acidic - basic - and polar amino acids
anomers
pI
D- glyceraldehyde
43. 1.has partial double bond character due to resonance 2. it cannot rotate 3. amide H is someWhat acidic and can H bond
Characteristics of the peptide bond
have amino group in their side chains
unsaturated fatty acid
1. presence of strong acids 2. proteolytic enzymes
44. Separation is due to charge - with negative charge moving toward positive electrode and positive charge moving toward negative electrode
1. presence of urea 2. extreme pH 3. extreme temperature 4. changes in salinity
mutarotation
all acidic - basic - and polar amino acids
Cause of Amino acid separation in gel electrophoresis
45. Diastereomers that vary in the configuration of 1 chiral center
histidine - arginine - lysine
lactase
epimers
have alkyl or aromatic side chains and tend to associate w/ each other - rather than water
46. Glycosidic linkage of cellulose
isomers
2 things about the cyclic form of a sugar as an acetal
NH2CONH2
glucose - beta -1 -4- glucose
47. Characteristics of polar amino acids
optical activity
furanose
Proteins
have an R group that is polar enough to H bond - but does no acts an acid or a base
48. 1. it requires an enzyme to linearize and mutarotate 2. it is not a reducing sugar and give negative Benedict's test
2 things about the cyclic form of a sugar as an acetal
anomeric carbon
secondary structure
antiparallel beta sheet
49. Unique feature of glycine
ketose
aldose
peptide bond
only achiral amino acid
50. Fatty acid w/ no double bonds and maximum number of hydrogens
isoelectric point
primary structure
D- glyceraldehyde
saturated fatty acid