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Test your basic knowledge |
MCAT Organic Chemistry 2
Start Test
Study First
Subjects
:
mcat
,
science
Instructions:
Answer 50 questions in 15 minutes.
If you are not ready to take this test, you can
study here
.
Match each statement with the correct term.
Don't refresh. All questions and answers are randomly picked and ordered every time you load a test.
This is a study tool. The 3 wrong answers for each question are randomly chosen from answers to other questions. So, you might find at times the answers obvious, but you will see it re-enforces your understanding as you take the test each time.
1. Acidic amino acids
glutamic acid and aspartic acid
packing and energy content
serine - threonine - asparagine - glutamine - cysteine - tyrosine
C3H6O3 - with one chiral center
2. Glycosidic linkage of lactose
galactose - beta -1 -4- glucose
D- amino acid
Cause of Amino acid separation in gel electrophoresis
anomeric carbon
3. Basic amino acids
basic amino acid has pKa at 6.5 - so it can either be protonated or deprotonated at physiological pH
amphipathic
histidine - arginine - lysine
have acidic carboxylic acid on side chains - w/ pKa around 4
4. 1. it exists in solution in equilibrium with linear form 2. mutarotation occurs readily 3. it is a reducing sugar - and reacts positively w/ Benedict's reagent
3 things about the cyclic form of a sugar as a hemiacetal
modulates fluidity and seeks to maintain optimal fluidity
isoelectric point
D- amino acid
5. Storage form of fatty acid that is composed of 3 esterified fatty acid to a glycerol molecule
peptide bonds and disulfide bonds
long chain of unsubstituted alkanes that end in a carboxylic acid - making them amphipathic
C3H6O3 - with one chiral center
triacylglycerol
6. Fxn of cholesterol in the membrane?
anomeric carbon
optical activity
tertiary structure
modulates fluidity and seeks to maintain optimal fluidity
7. Name for 5 membered ring
lipases
furanose
secondary structure
CH3COOH
8. Enzyme that hydrolyzes lactose into galactose and glucose into
have amino group in their side chains
3 things about the cyclic form of a sugar as a hemiacetal
anomers
lactase
9. Adjacent polypeptide strands running in opposite directions in Beta pleated sheet structure
antiparallel beta sheet
van der Waal forces of hydrophobic tails
D- glyceraldehyde
anomeric carbon
10. Molecule can act as a base and as an acid
L- configuration
amphoteric
triacylglycerol
primary structure
11. Interconversion btw two anomers
mutarotation
all acidic - basic - and polar amino acids
quaternary structure
primary structure
12. Glycosidic linkage of cellulose
glucose - beta -1 -4- glucose
C3H6O3 - with one chiral center
lactase
alpha helix
13. Enzymes that hydrolyze fats
anomeric carbon
parallel beta sheet
lipases
1. form phospholipids of cellular membranes 2. store energy in adipose tissue 3. produce steroid hormones
14. Formula for urea
NH2CONH2
saturated fatty acid
maltase
glutamic acid and aspartic acid
15. What configuration do all naturally occuring amino acids have?
amphipathic
only amino acid that his a secondary amine
L- configuration
have acidic carboxylic acid on side chains - w/ pKa around 4
16. Fatty acid structure
glucose - alpha -1 -2- fructose
lipases
modulates fluidity and seeks to maintain optimal fluidity
long chain of unsubstituted alkanes that end in a carboxylic acid - making them amphipathic
17. Energy storage molecule of carbohydrates for plants
starch
anomers
maltase
amphoteric
18. Right handed helix w/ carboxyl of one amino acid bound to the amine of another amino acid three residues away - proline never resides in this structure b/c it would place a kink in the helix
aldose
alpha helix
glycine - alanine - valine - methionine - leucine - isoleucine - proline - phenylalanine - tryptophan
the basic precursor of the molecule (L or D glyceraldehyde)
19. Generated btw either thiols on different proteins or thiols on the same protein
L- configuration
peptide bond
only amino acid that his a secondary amine
disulfide bond
20. Fatty acid w/ one or more double bonds in cis form predominately
primary structure
have alkyl or aromatic side chains and tend to associate w/ each other - rather than water
unsaturated fatty acid
amphipathic
21. Unique feature of glycine
1. presence of strong acids 2. proteolytic enzymes
quaternary structure
only achiral amino acid
saturated fatty acid
22. Name for 6 membered ring
mutarotation
pyranose
Characteristics of the peptide bond
starch
23. What stabilizes lipid bilayer?
van der Waal forces of hydrophobic tails
only achiral amino acid
epimers
CH3COOH
24. Energy storage molecule of carbohydrates for animals
glycogen
furanose
optical activity
has thiol group that allows it the form disulfide bond
25. Amino group placed on the right of a fischer projection is a?
epimers
1. form phospholipids of cellular membranes 2. store energy in adipose tissue 3. produce steroid hormones
D- amino acid
phospholipids
26. Interaction btw polypeptide subunits arranged in polypeptide. can be covalent bonds or intermolecular forces - disulfide bond that does not form btw residues on the same protein affect (blank)
quaternary structure
peptide bond
anomers
furanose
27. PH at which the amino acid has a net neutral charge
isoelectric point
only amino acid that his a secondary amine
L- amino acid
saturated fatty acid
28. 3 carbon triol that forms backbone of triacylglycerol
1. form phospholipids of cellular membranes 2. store energy in adipose tissue 3. produce steroid hormones
maltase
glycerol
amphoteric
29. PH at which positive and negative charges balance to form a zwitterion
Characteristics of the peptide bond
triacylglycerol
pI
saturated fatty acid
30. Hydrolysis
optical activity
pyranose
D- amino acid
addition of water across of a bond
31. What describes the affinity of functional groups for a proton?
Ka
only achiral amino acid
antiparallel beta sheet
mutarotation
32. Naturally occurring carbohydrates are formed from what?
histidine - arginine - lysine
maltase
all acidic - basic - and polar amino acids
D- glyceraldehyde
33. The amino acid sequence of a protein that is determined by peptide bond
aldose
disulfide bond
absolute configuration
primary structure
34. Characteristics of polar amino acids
glycine - alanine - valine - methionine - leucine - isoleucine - proline - phenylalanine - tryptophan
have an R group that is polar enough to H bond - but does no acts an acid or a base
glycogen
galactose - beta -1 -4- glucose
35. Epimers of sugars that vary in the configuration of their anomeric carbons
anomers
lactase
cysteine and methionine
1. presence of strong acids 2. proteolytic enzymes
36. Polar amino acids
anomers
tertiary structure
serine - threonine - asparagine - glutamine - cysteine - tyrosine
Ka
37. Hydrophilic amino acids
packing and energy content
peptide bond
all acidic - basic - and polar amino acids
Characteristics of the peptide bond
38. D and L describe what?
only amino acid that his a secondary amine
cysteine and methionine
amphoteric
the basic precursor of the molecule (L or D glyceraldehyde)
39. Separation is due to charge - with negative charge moving toward positive electrode and positive charge moving toward negative electrode
unsaturated fatty acid
have amino group in their side chains
Cause of Amino acid separation in gel electrophoresis
glutamic acid and aspartic acid
40. Glycosidic linkage of maltose
glucose - alpha -1 -4- glucose
1. presence of strong acids 2. proteolytic enzymes
starch
primary structure
41. 1.has partial double bond character due to resonance 2. it cannot rotate 3. amide H is someWhat acidic and can H bond
Characteristics of the peptide bond
glucose - alpha -1 -2- fructose
histidine - arginine - lysine
maltase
42. 2 covalent bonds formed in proteins
isoelectric point
peptide bonds and disulfide bonds
serine - threonine - asparagine - glutamine - cysteine - tyrosine
ketose
43. Molecules with the same atoms and same bonds - but different bond geometries; can either be enantiomers or diastereomers
starch
stereoisomers
lactase
alpha helix
44. 2 things that accelerate the rate of hydrolysis for peptide cleavage?
CH3COOH
1. presence of strong acids 2. proteolytic enzymes
Characteristics of the peptide bond
glucose - alpha -1 -4- glucose
45. Initial folding of proteins into shapes stabilized by H bonds btw amino and carboxyl groups of backbone
Proteins
peptide bonds and disulfide bonds
secondary structure
quaternary structure
46. (+) and (-) describe what?
quaternary structure
optical activity
pyranose
tertiary structure
47. Acetic acid formula?
CH3COOH
long chain of unsubstituted alkanes that end in a carboxylic acid - making them amphipathic
anomeric carbon
van der Waal forces of hydrophobic tails
48. Histidine
pI
glycogen
basic amino acid has pKa at 6.5 - so it can either be protonated or deprotonated at physiological pH
histidine - arginine - lysine
49. Rule for all amino acids that are nonbasic and nonacidic pertaining to pI value?
D- amino acid
isoelectric point
will have pI of 6
triacylglycerol
50. Diastereomers that vary in the configuration of 1 chiral center
Beta pleated sheet
amphoteric
epimers
glycogen