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Test your basic knowledge |
MCAT Organic Chemistry 2
Start Test
Study First
Subjects
:
mcat
,
science
Instructions:
Answer 50 questions in 30 minutes.
If you are not ready to take this test, you can
study here
.
Match each statement with the correct term.
Don't refresh. All questions and answers are randomly picked and ordered every time you load a test.
This is a study tool. The 3 wrong answers for each question are randomly chosen from answers to other questions. So, you might find at times the answers obvious, but you will see it re-enforces your understanding as you take the test each time.
1. Macromolecule that performs a variety of bodily functions and is composed of up to 20 different amino acids
addition of water across of a bond
ketose
Proteins
stereoisomers
2. Interconversion btw two anomers
D- glyceraldehyde
mutarotation
glutamic acid and aspartic acid
NH2CONH2
3. What kind of lipids compromise the lipid bilayer?
histidine - arginine - lysine
the basic precursor of the molecule (L or D glyceraldehyde)
only amino acid that his a secondary amine
phospholipids
4. Glyceraldehyde
the basic precursor of the molecule (L or D glyceraldehyde)
7.4
C3H6O3 - with one chiral center
disulfide bond
5. Glycosidic linkage of maltose
glucose - alpha -1 -4- glucose
long chain of unsubstituted alkanes that end in a carboxylic acid - making them amphipathic
absolute configuration
will have pI of 6
6. What describes the affinity of functional groups for a proton?
Ka
optical activity
all acidic - basic - and polar amino acids
parallel beta sheet
7. Sulfur containing amino acids
antiparallel beta sheet
furanose
glycerol
cysteine and methionine
8. PH at which the amino acid has a net neutral charge
isoelectric point
cysteine and methionine
galactose - beta -1 -4- glucose
have acidic carboxylic acid on side chains - w/ pKa around 4
9. 3 carbon triol that forms backbone of triacylglycerol
glycerol
pI
1. presence of urea 2. extreme pH 3. extreme temperature 4. changes in salinity
packing and energy content
10. Naturally occurring carbohydrates are formed from what?
2 things about the cyclic form of a sugar as an acetal
L- amino acid
basic amino acid has pKa at 6.5 - so it can either be protonated or deprotonated at physiological pH
D- glyceraldehyde
11. Enzyme that hydrolyzes maltose into 2 glucose molecules?
secondary structure
Proteins
maltase
glucose - alpha -1 -4- glucose
12. Fatty acid structure
triacylglycerol
addition of water across of a bond
long chain of unsubstituted alkanes that end in a carboxylic acid - making them amphipathic
serine - threonine - asparagine - glutamine - cysteine - tyrosine
13. 2 covalent bonds formed in proteins
peptide bonds and disulfide bonds
3 things about the cyclic form of a sugar as a hemiacetal
maltase
amphipathic
14. PH at which positive and negative charges balance to form a zwitterion
pI
aldose
only achiral amino acid
1. presence of urea 2. extreme pH 3. extreme temperature 4. changes in salinity
15. Enzymes that hydrolyze fats
lipases
saturated fatty acid
Beta pleated sheet
stereoisomers
16. Adjacent polypeptide strands running in opposite directions in Beta pleated sheet structure
will have pI of 6
antiparallel beta sheet
glycine - alanine - valine - methionine - leucine - isoleucine - proline - phenylalanine - tryptophan
glucose - beta -1 -4- glucose
17. Characteristics of polar amino acids
cysteine and methionine
glucose - beta -1 -4- glucose
amphoteric
have an R group that is polar enough to H bond - but does no acts an acid or a base
18. Epimers of sugars that vary in the configuration of their anomeric carbons
packing and energy content
anomers
glucose - alpha -1 -2- fructose
peptide bond
19. Acetic acid formula?
glutamic acid and aspartic acid
CH3COOH
have alkyl or aromatic side chains and tend to associate w/ each other - rather than water
furanose
20. Nonpolar - hydrophobic amino acids
peptide bond
ketose
aldose
glycine - alanine - valine - methionine - leucine - isoleucine - proline - phenylalanine - tryptophan
21. 2 reasons why fats have more efficient energy stores than carbs
have amino group in their side chains
packing and energy content
will have pI of 6
C3H6O3 - with one chiral center
22. Physiological pH
triacylglycerol
secondary structure
7.4
phospholipids
23. Fatty acid w/ one or more double bonds in cis form predominately
histidine - arginine - lysine
unsaturated fatty acid
2 things about the cyclic form of a sugar as an acetal
1. form phospholipids of cellular membranes 2. store energy in adipose tissue 3. produce steroid hormones
24. Initial folding of proteins into shapes stabilized by H bonds btw amino and carboxyl groups of backbone
ketose
secondary structure
cysteine and methionine
stereoisomers
25. Name for 6 membered ring
optical activity
absolute configuration
Beta pleated sheet
pyranose
26. Fatty acid w/ no double bonds and maximum number of hydrogens
glucose - alpha -1 -2- fructose
only amino acid that his a secondary amine
isomers
saturated fatty acid
27. 1. it exists in solution in equilibrium with linear form 2. mutarotation occurs readily 3. it is a reducing sugar - and reacts positively w/ Benedict's reagent
glucose - alpha -1 -2- fructose
mutarotation
packing and energy content
3 things about the cyclic form of a sugar as a hemiacetal
28. Molecules with the same atoms and same bonds - but different bond geometries; can either be enantiomers or diastereomers
stereoisomers
Beta pleated sheet
serine - threonine - asparagine - glutamine - cysteine - tyrosine
aldose
29. Amino group placed on the right of a fischer projection is a?
D- amino acid
mutarotation
absolute configuration
optical activity
30. Unique feature of proline
antiparallel beta sheet
all acidic - basic - and polar amino acids
only amino acid that his a secondary amine
galactose - beta -1 -4- glucose
31. (+) and (-) describe what?
will have pI of 6
CH3COOH
glutamic acid and aspartic acid
optical activity
32. Histidine
maltase
basic amino acid has pKa at 6.5 - so it can either be protonated or deprotonated at physiological pH
ketose
amphipathic
33. Structure where H bonds occur btw residues distant from each other - or on a separate chain. backbone is extended rather than coiled
galactose - beta -1 -4- glucose
Beta pleated sheet
serine - threonine - asparagine - glutamine - cysteine - tyrosine
have alkyl or aromatic side chains and tend to associate w/ each other - rather than water
34. Fxn of cholesterol in the membrane?
glucose - beta -1 -4- glucose
modulates fluidity and seeks to maintain optimal fluidity
starch
pI
35. Glycosidic linkage of lactose
cysteine and methionine
D- glyceraldehyde
have amino group in their side chains
galactose - beta -1 -4- glucose
36. Hydrolysis
phospholipids
lipases
glucose - alpha -1 -4- glucose
addition of water across of a bond
37. Characteristic of basic amino acids
have amino group in their side chains
glucose - alpha -1 -4- glucose
7.4
aldose
38. Amino group placed on the left of a fischer projection is a?
van der Waal forces of hydrophobic tails
L- amino acid
D- amino acid
amphoteric
39. What configuration do all naturally occuring amino acids have?
triacylglycerol
L- configuration
have acidic carboxylic acid on side chains - w/ pKa around 4
tertiary structure
40. 3 physiological roles of lipids
1. form phospholipids of cellular membranes 2. store energy in adipose tissue 3. produce steroid hormones
ketose
absolute configuration
disulfide bond
41. Adjacent polypeptide strands running in the same direction in Beta pleated sheet structure
L- amino acid
1. presence of strong acids 2. proteolytic enzymes
parallel beta sheet
saturated fatty acid
42. Sugar with a carbonyl group at the 2 carbon position
NH2CONH2
lipases
L- amino acid
ketose
43. Property of fatty acids where one end is hydrophobic and the other is hydrophilic
tertiary structure
amphipathic
2 things about the cyclic form of a sugar as an acetal
glutamic acid and aspartic acid
44. Energy storage molecule of carbohydrates for animals
L- configuration
glycogen
saturated fatty acid
1. presence of strong acids 2. proteolytic enzymes
45. Formula for urea
have acidic carboxylic acid on side chains - w/ pKa around 4
NH2CONH2
mutarotation
2 things about the cyclic form of a sugar as an acetal
46. 1.has partial double bond character due to resonance 2. it cannot rotate 3. amide H is someWhat acidic and can H bond
1. presence of urea 2. extreme pH 3. extreme temperature 4. changes in salinity
saturated fatty acid
CH3COOH
Characteristics of the peptide bond
47. The amino acid sequence of a protein that is determined by peptide bond
primary structure
pI
isoelectric point
will have pI of 6
48. Characteristics of acidic amino acids
have acidic carboxylic acid on side chains - w/ pKa around 4
lactase
3 things about the cyclic form of a sugar as a hemiacetal
have amino group in their side chains
49. Interaction btw polypeptide subunits arranged in polypeptide. can be covalent bonds or intermolecular forces - disulfide bond that does not form btw residues on the same protein affect (blank)
quaternary structure
tertiary structure
furanose
only achiral amino acid
50. 2 things that accelerate the rate of hydrolysis for peptide cleavage?
1. presence of strong acids 2. proteolytic enzymes
optical activity
aldose
7.4