SUBJECTS
|
BROWSE
|
CAREER CENTER
|
POPULAR
|
JOIN
|
LOGIN
Business Skills
|
Soft Skills
|
Basic Literacy
|
Certifications
About
|
Help
|
Privacy
|
Terms
|
Email
Search
Test your basic knowledge |
MCAT Organic Chemistry 2
Start Test
Study First
Subjects
:
mcat
,
science
Instructions:
Answer 50 questions in 15 minutes.
If you are not ready to take this test, you can
study here
.
Match each statement with the correct term.
Don't refresh. All questions and answers are randomly picked and ordered every time you load a test.
This is a study tool. The 3 wrong answers for each question are randomly chosen from answers to other questions. So, you might find at times the answers obvious, but you will see it re-enforces your understanding as you take the test each time.
1. Glycosidic linkage of maltose
glucose - alpha -1 -4- glucose
glutamic acid and aspartic acid
all acidic - basic - and polar amino acids
have alkyl or aromatic side chains and tend to associate w/ each other - rather than water
2. Covalent bond formed btw carboxyl group of one atom and the amino group of another amino acid in an addition - elimination mechanism - enzymes are required to carry out rxn
peptide bond
maltase
isoelectric point
mutarotation
3. Molecules with the same atoms and same bonds - but different bond geometries; can either be enantiomers or diastereomers
7.4
serine - threonine - asparagine - glutamine - cysteine - tyrosine
glucose - alpha -1 -4- glucose
stereoisomers
4. Molecules with the same atoms - but different bonds
isomers
mutarotation
amphoteric
glucose - alpha -1 -2- fructose
5. Naturally occurring carbohydrates are formed from what?
7.4
D- glyceraldehyde
lipases
phospholipids
6. Unique feature of proline
cysteine and methionine
only amino acid that his a secondary amine
have alkyl or aromatic side chains and tend to associate w/ each other - rather than water
phospholipids
7. Diastereomers that vary in the configuration of 1 chiral center
D- amino acid
lactase
have an R group that is polar enough to H bond - but does no acts an acid or a base
epimers
8. Formula for urea
stereoisomers
NH2CONH2
Ka
histidine - arginine - lysine
9. Unique feature of glycine
has thiol group that allows it the form disulfide bond
only achiral amino acid
packing and energy content
D- amino acid
10. D and L describe what?
glycine - alanine - valine - methionine - leucine - isoleucine - proline - phenylalanine - tryptophan
cysteine and methionine
glucose - alpha -1 -2- fructose
the basic precursor of the molecule (L or D glyceraldehyde)
11. Generated btw either thiols on different proteins or thiols on the same protein
pI
quaternary structure
maltase
disulfide bond
12. Rule for all amino acids that are nonbasic and nonacidic pertaining to pI value?
only achiral amino acid
starch
have an R group that is polar enough to H bond - but does no acts an acid or a base
will have pI of 6
13. 3 carbon triol that forms backbone of triacylglycerol
glycerol
7.4
packing and energy content
absolute configuration
14. 1. it requires an enzyme to linearize and mutarotate 2. it is not a reducing sugar and give negative Benedict's test
stereoisomers
2 things about the cyclic form of a sugar as an acetal
glutamic acid and aspartic acid
only achiral amino acid
15. Amino group placed on the left of a fischer projection is a?
L- amino acid
primary structure
optical activity
7.4
16. Basic amino acids
long chain of unsubstituted alkanes that end in a carboxylic acid - making them amphipathic
glucose - alpha -1 -2- fructose
secondary structure
histidine - arginine - lysine
17. Sulfur containing amino acids
disulfide bond
alpha helix
L- amino acid
cysteine and methionine
18. Epimers of sugars that vary in the configuration of their anomeric carbons
anomers
C3H6O3 - with one chiral center
peptide bond
serine - threonine - asparagine - glutamine - cysteine - tyrosine
19. (+) and (-) describe what?
glycerol
optical activity
D- glyceraldehyde
ketose
20. Adjacent polypeptide strands running in opposite directions in Beta pleated sheet structure
glucose - alpha -1 -2- fructose
antiparallel beta sheet
lipases
disulfide bond
21. Separation is due to charge - with negative charge moving toward positive electrode and positive charge moving toward negative electrode
glucose - alpha -1 -4- glucose
Cause of Amino acid separation in gel electrophoresis
saturated fatty acid
have an R group that is polar enough to H bond - but does no acts an acid or a base
22. Molecule can act as a base and as an acid
isoelectric point
histidine - arginine - lysine
amphoteric
addition of water across of a bond
23. Characteristic of basic amino acids
glycogen
phospholipids
amphipathic
have amino group in their side chains
24. Characteristics of hydrophobic amino acids
have alkyl or aromatic side chains and tend to associate w/ each other - rather than water
pyranose
D- glyceraldehyde
antiparallel beta sheet
25. 2 things that accelerate the rate of hydrolysis for peptide cleavage?
glucose - alpha -1 -2- fructose
triacylglycerol
1. presence of strong acids 2. proteolytic enzymes
alpha helix
26. 1.has partial double bond character due to resonance 2. it cannot rotate 3. amide H is someWhat acidic and can H bond
anomeric carbon
addition of water across of a bond
secondary structure
Characteristics of the peptide bond
27. Storage form of fatty acid that is composed of 3 esterified fatty acid to a glycerol molecule
have an R group that is polar enough to H bond - but does no acts an acid or a base
isomers
triacylglycerol
alpha helix
28. What configuration do all naturally occuring amino acids have?
maltase
disulfide bond
primary structure
L- configuration
29. Glycosidic linkage of lactose
histidine - arginine - lysine
anomers
galactose - beta -1 -4- glucose
2 things about the cyclic form of a sugar as an acetal
30. The amino acid sequence of a protein that is determined by peptide bond
Cause of Amino acid separation in gel electrophoresis
van der Waal forces of hydrophobic tails
primary structure
have an R group that is polar enough to H bond - but does no acts an acid or a base
31. Amino group placed on the right of a fischer projection is a?
addition of water across of a bond
D- amino acid
have acidic carboxylic acid on side chains - w/ pKa around 4
phospholipids
32. Hydrophilic amino acids
all acidic - basic - and polar amino acids
stereoisomers
7.4
glucose - beta -1 -4- glucose
33. Hydrolysis
addition of water across of a bond
Ka
antiparallel beta sheet
lipases
34. Acidic amino acids
only amino acid that his a secondary amine
glutamic acid and aspartic acid
glycerol
have an R group that is polar enough to H bond - but does no acts an acid or a base
35. Property of fatty acids where one end is hydrophobic and the other is hydrophilic
2 things about the cyclic form of a sugar as an acetal
galactose - beta -1 -4- glucose
amphipathic
have amino group in their side chains
36. PH at which positive and negative charges balance to form a zwitterion
triacylglycerol
pI
Characteristics of the peptide bond
have an R group that is polar enough to H bond - but does no acts an acid or a base
37. Macromolecule that performs a variety of bodily functions and is composed of up to 20 different amino acids
Proteins
saturated fatty acid
galactose - beta -1 -4- glucose
glutamic acid and aspartic acid
38. Enzyme that hydrolyzes maltose into 2 glucose molecules?
glycerol
cysteine and methionine
maltase
L- amino acid
39. Structure where H bonds occur btw residues distant from each other - or on a separate chain. backbone is extended rather than coiled
Beta pleated sheet
D- glyceraldehyde
glycogen
all acidic - basic - and polar amino acids
40. Initial folding of proteins into shapes stabilized by H bonds btw amino and carboxyl groups of backbone
ketose
secondary structure
isoelectric point
Beta pleated sheet
41. Interconversion btw two anomers
mutarotation
D- amino acid
optical activity
have acidic carboxylic acid on side chains - w/ pKa around 4
42. 3 physiological roles of lipids
long chain of unsubstituted alkanes that end in a carboxylic acid - making them amphipathic
secondary structure
glycogen
1. form phospholipids of cellular membranes 2. store energy in adipose tissue 3. produce steroid hormones
43. Polar amino acids
serine - threonine - asparagine - glutamine - cysteine - tyrosine
Beta pleated sheet
maltase
will have pI of 6
44. Physiological pH
CH3COOH
7.4
isoelectric point
optical activity
45. Glycosidic linkage of sucrose
quaternary structure
Ka
only achiral amino acid
glucose - alpha -1 -2- fructose
46. Enzyme that hydrolyzes lactose into galactose and glucose into
lipases
glycogen
stereoisomers
lactase
47. Right handed helix w/ carboxyl of one amino acid bound to the amine of another amino acid three residues away - proline never resides in this structure b/c it would place a kink in the helix
amphipathic
alpha helix
lactase
D- glyceraldehyde
48. Fatty acid w/ no double bonds and maximum number of hydrogens
glucose - alpha -1 -2- fructose
anomeric carbon
phospholipids
saturated fatty acid
49. Energy storage molecule of carbohydrates for plants
starch
D- glyceraldehyde
amphipathic
peptide bond
50. Histidine
basic amino acid has pKa at 6.5 - so it can either be protonated or deprotonated at physiological pH
Beta pleated sheet
saturated fatty acid
van der Waal forces of hydrophobic tails