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Test your basic knowledge |
MCAT Organic Chemistry 2
Start Test
Study First
Subjects
:
mcat
,
science
Instructions:
Answer 50 questions in 15 minutes.
If you are not ready to take this test, you can
study here
.
Match each statement with the correct term.
Don't refresh. All questions and answers are randomly picked and ordered every time you load a test.
This is a study tool. The 3 wrong answers for each question are randomly chosen from answers to other questions. So, you might find at times the answers obvious, but you will see it re-enforces your understanding as you take the test each time.
1. What describes the affinity of functional groups for a proton?
Ka
furanose
aldose
addition of water across of a bond
2. (R) and (S) describe what?
glycogen
maltase
alpha helix
absolute configuration
3. Molecules with the same atoms - but different bonds
the basic precursor of the molecule (L or D glyceraldehyde)
disulfide bond
isomers
stereoisomers
4. Diastereomers that vary in the configuration of 1 chiral center
epimers
have amino group in their side chains
glycine - alanine - valine - methionine - leucine - isoleucine - proline - phenylalanine - tryptophan
CH3COOH
5. 1. it exists in solution in equilibrium with linear form 2. mutarotation occurs readily 3. it is a reducing sugar - and reacts positively w/ Benedict's reagent
has thiol group that allows it the form disulfide bond
1. form phospholipids of cellular membranes 2. store energy in adipose tissue 3. produce steroid hormones
3 things about the cyclic form of a sugar as a hemiacetal
starch
6. Unique feature of proline
have an R group that is polar enough to H bond - but does no acts an acid or a base
only amino acid that his a secondary amine
7.4
glycogen
7. Initial folding of proteins into shapes stabilized by H bonds btw amino and carboxyl groups of backbone
1. presence of strong acids 2. proteolytic enzymes
Cause of Amino acid separation in gel electrophoresis
quaternary structure
secondary structure
8. Generated btw either thiols on different proteins or thiols on the same protein
anomeric carbon
mutarotation
phospholipids
disulfide bond
9. Polar amino acids
glycine - alanine - valine - methionine - leucine - isoleucine - proline - phenylalanine - tryptophan
saturated fatty acid
serine - threonine - asparagine - glutamine - cysteine - tyrosine
epimers
10. Amino group placed on the right of a fischer projection is a?
only amino acid that his a secondary amine
D- amino acid
anomeric carbon
cysteine and methionine
11. Adjacent polypeptide strands running in the same direction in Beta pleated sheet structure
phospholipids
antiparallel beta sheet
parallel beta sheet
D- glyceraldehyde
12. Glycosidic linkage of cellulose
Beta pleated sheet
peptide bonds and disulfide bonds
glucose - beta -1 -4- glucose
glutamic acid and aspartic acid
13. The amino acid sequence of a protein that is determined by peptide bond
1. presence of strong acids 2. proteolytic enzymes
primary structure
secondary structure
lipases
14. Unique feature of glycine
addition of water across of a bond
phospholipids
2 things about the cyclic form of a sugar as an acetal
only achiral amino acid
15. Hydrophobic and hydrophilic interactions btw amino acids more distant from each other on the polypeptide chain
D- glyceraldehyde
1. form phospholipids of cellular membranes 2. store energy in adipose tissue 3. produce steroid hormones
saturated fatty acid
tertiary structure
16. Glycosidic linkage of sucrose
glycerol
glucose - alpha -1 -2- fructose
CH3COOH
have acidic carboxylic acid on side chains - w/ pKa around 4
17. Hydrophilic amino acids
peptide bond
glucose - alpha -1 -2- fructose
all acidic - basic - and polar amino acids
galactose - beta -1 -4- glucose
18. Interconversion btw two anomers
have an R group that is polar enough to H bond - but does no acts an acid or a base
3 things about the cyclic form of a sugar as a hemiacetal
amphoteric
mutarotation
19. Rule for all amino acids that are nonbasic and nonacidic pertaining to pI value?
will have pI of 6
3 things about the cyclic form of a sugar as a hemiacetal
secondary structure
pyranose
20. Property of fatty acids where one end is hydrophobic and the other is hydrophilic
the basic precursor of the molecule (L or D glyceraldehyde)
7.4
secondary structure
amphipathic
21. Covalent bond formed btw carboxyl group of one atom and the amino group of another amino acid in an addition - elimination mechanism - enzymes are required to carry out rxn
peptide bond
modulates fluidity and seeks to maintain optimal fluidity
CH3COOH
serine - threonine - asparagine - glutamine - cysteine - tyrosine
22. Physiological pH
amphipathic
7.4
serine - threonine - asparagine - glutamine - cysteine - tyrosine
3 things about the cyclic form of a sugar as a hemiacetal
23. Name for 6 membered ring
7.4
pyranose
1. presence of urea 2. extreme pH 3. extreme temperature 4. changes in salinity
amphipathic
24. Acetic acid formula?
stereoisomers
disulfide bond
CH3COOH
van der Waal forces of hydrophobic tails
25. Structure where H bonds occur btw residues distant from each other - or on a separate chain. backbone is extended rather than coiled
optical activity
1. presence of strong acids 2. proteolytic enzymes
Beta pleated sheet
lactase
26. What stabilizes lipid bilayer?
serine - threonine - asparagine - glutamine - cysteine - tyrosine
glutamic acid and aspartic acid
van der Waal forces of hydrophobic tails
triacylglycerol
27. Unique feature of cysteine
serine - threonine - asparagine - glutamine - cysteine - tyrosine
7.4
has thiol group that allows it the form disulfide bond
1. presence of urea 2. extreme pH 3. extreme temperature 4. changes in salinity
28. Interaction btw polypeptide subunits arranged in polypeptide. can be covalent bonds or intermolecular forces - disulfide bond that does not form btw residues on the same protein affect (blank)
quaternary structure
only achiral amino acid
7.4
van der Waal forces of hydrophobic tails
29. Fatty acid w/ one or more double bonds in cis form predominately
disulfide bond
amphoteric
pI
unsaturated fatty acid
30. 2 covalent bonds formed in proteins
peptide bonds and disulfide bonds
2 things about the cyclic form of a sugar as an acetal
glycine - alanine - valine - methionine - leucine - isoleucine - proline - phenylalanine - tryptophan
glycerol
31. Hydrolysis
glucose - alpha -1 -4- glucose
7.4
addition of water across of a bond
pyranose
32. 4 causes of denaturation of proteins
addition of water across of a bond
1. presence of urea 2. extreme pH 3. extreme temperature 4. changes in salinity
secondary structure
van der Waal forces of hydrophobic tails
33. Characteristics of hydrophobic amino acids
furanose
glucose - alpha -1 -2- fructose
have alkyl or aromatic side chains and tend to associate w/ each other - rather than water
glutamic acid and aspartic acid
34. Naturally occurring carbohydrates are formed from what?
D- glyceraldehyde
maltase
only amino acid that his a secondary amine
glycerol
35. Sugar with an aldehyde at the first carbon position
2 things about the cyclic form of a sugar as an acetal
1. presence of strong acids 2. proteolytic enzymes
aldose
stereoisomers
36. 1. it requires an enzyme to linearize and mutarotate 2. it is not a reducing sugar and give negative Benedict's test
lipases
serine - threonine - asparagine - glutamine - cysteine - tyrosine
anomers
2 things about the cyclic form of a sugar as an acetal
37. 3 carbon triol that forms backbone of triacylglycerol
glucose - beta -1 -4- glucose
pI
CH3COOH
glycerol
38. 1.has partial double bond character due to resonance 2. it cannot rotate 3. amide H is someWhat acidic and can H bond
parallel beta sheet
triacylglycerol
Characteristics of the peptide bond
glucose - beta -1 -4- glucose
39. Storage form of fatty acid that is composed of 3 esterified fatty acid to a glycerol molecule
all acidic - basic - and polar amino acids
triacylglycerol
3 things about the cyclic form of a sugar as a hemiacetal
NH2CONH2
40. Fxn of cholesterol in the membrane?
glycine - alanine - valine - methionine - leucine - isoleucine - proline - phenylalanine - tryptophan
only achiral amino acid
modulates fluidity and seeks to maintain optimal fluidity
lipases
41. Adjacent polypeptide strands running in opposite directions in Beta pleated sheet structure
Characteristics of the peptide bond
CH3COOH
Ka
antiparallel beta sheet
42. Sugar with a carbonyl group at the 2 carbon position
mutarotation
ketose
pI
the basic precursor of the molecule (L or D glyceraldehyde)
43. Molecule can act as a base and as an acid
amphoteric
long chain of unsubstituted alkanes that end in a carboxylic acid - making them amphipathic
have alkyl or aromatic side chains and tend to associate w/ each other - rather than water
epimers
44. Fatty acid w/ no double bonds and maximum number of hydrogens
3 things about the cyclic form of a sugar as a hemiacetal
antiparallel beta sheet
saturated fatty acid
have acidic carboxylic acid on side chains - w/ pKa around 4
45. Glyceraldehyde
lipases
C3H6O3 - with one chiral center
isoelectric point
glycogen
46. Separation is due to charge - with negative charge moving toward positive electrode and positive charge moving toward negative electrode
Cause of Amino acid separation in gel electrophoresis
all acidic - basic - and polar amino acids
serine - threonine - asparagine - glutamine - cysteine - tyrosine
isoelectric point
47. Characteristics of polar amino acids
have an R group that is polar enough to H bond - but does no acts an acid or a base
van der Waal forces of hydrophobic tails
1. presence of urea 2. extreme pH 3. extreme temperature 4. changes in salinity
galactose - beta -1 -4- glucose
48. Glycosidic linkage of maltose
antiparallel beta sheet
D- glyceraldehyde
glucose - alpha -1 -4- glucose
Characteristics of the peptide bond
49. Amino group placed on the left of a fischer projection is a?
lipases
L- amino acid
pyranose
histidine - arginine - lysine
50. Characteristic of basic amino acids
have amino group in their side chains
anomers
glycine - alanine - valine - methionine - leucine - isoleucine - proline - phenylalanine - tryptophan
parallel beta sheet