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Test your basic knowledge |
Modern Material Science And Engineering 2
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Subject
:
engineering
Instructions:
Answer 50 questions in 15 minutes.
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Match each statement with the correct term.
Don't refresh. All questions and answers are randomly picked and ordered every time you load a test.
This is a study tool. The 3 wrong answers for each question are randomly chosen from answers to other questions. So, you might find at times the answers obvious, but you will see it re-enforces your understanding as you take the test each time.
1. Polymers that contain amide (- N-) groups in the chain
polyamides
isotactic dan
poly- p- phenylene benzobisoxazole PBO
oligomers
2. Part of the extrusion apparatus that contains a heated screw which is used to melt the polymer and the polymer forward into the next chamber
High volume thermoplastics HVTP
barrel
spinneret
plasticizers
3. Polymer in which more than 85% of the amide groups are bonded to two aromatic rings
aramid
dyes
High volume thermoplastics HVTP
poly- p- phenylene benzobisoxazole PBO
4. Long chain polymers that contain at least 85% of an ester of a substituted aromatic carboxylic acid. these fibers are strong and can dyed or made transpared
quenching
functionality
polyesters
hopper
5. Final step in the polymerization process - which causes the elongation of the polymer chain to come to an end
termination
rayon
quenching
addition polymerization/chain growth/free- radical polymerization
6. Refers to the spatial geometry of the main chain carbon and substituents that can be changed by rotation and flexural motion
poly- p- phenylene benzobisoxazole PBO
conformation
thermosets
quenching
7. Formation of side chains along the backbone; presence of branches disrupts the interactions beween adjacent chains; lowering the tensile strength - melting point - stiffness - crystallinity - and density
eclipsed conformation/ cis - conformation
viscose process
configuration
branching
8. Small chains of bonded monomers whose properties would be altered by the addition of one more monomer unit
weight average molecular weight Mw
vinyl monomer
spinneret
oligomers
9. Kevlar - Twaron - high tensile strength - lightweight - susceptible to uv degradation - nonconductive - bullet- resistant armor - sports equipment - fire resistance
polypphenylene terephyhalamide PPTA
degree of polymerization DPn
most common condensation/step- growth polymerization occur between....
structural unit
10. Porcess of breaking large organic hydrocarbons into smaller molecules
relative molecular mass RMM
acrylic
cracking
conformation
11. Pigments or dyes that change the way light is absorbed or reflected by a polymer
polyesters
coloring agents
primary bonding
blends
12. Type of polyamide in which less that 85% of the amide groups are bonded to the aromatic rings
nylon
isotactic dan
High volume thermoplastics HVTP
plasticizers
13. Configuration of a polymer in which the sucstituent is located on opposite sides of the molecule in each repeating unit
conformation
syndiotactic dyad
end groups
polymer backbone
14. First step in the process of polymerization - during which a free radical is formed
initiation
acrylic
mutual termination
secondary bonding
15. Formation of a plymer that occurs when two potentially reactive end groups on a polymer react to form a new covalent bond between the polymer chains. this reaction also forms a biproduct - usually water
termination
coloring agents
condensation/step- growth polymerization
homopolymer
16. Form of the molecular weight of a sample of polymer chains determined by dividing the mass of the specimen by total number of mols present; always less than weight average molecular weight; all molecules regardless of size correlate well with Mn
branching
eclipsed conformation/ cis - conformation
number average molecular weight Mn
staggered conformation
17. Is not asymetric and cannot have multiple configurations
hopper
copolymer
any carbon with double bonds or repeated substituents
secondary bonding
18. Polymers in which one chain of a particular monomer is attached as a side to a chain of another chain of monomer
plasticizers
tow
graft copolymers
homopolymer
19. Second stage of polymerization process during which the polymer chain begins to go as monomers are added to the chain
spinneret
functionality
polyviyl chloride PVC
propagation
20. Last step in the polymerization process - which occurs when the free radical of a polymer chain joins the free radical on an end group
primary termination
dyes
freeze line
homopolymer
21. Number of bonds a molecule has formed
syndiotactic dyad
functionality
solution spinning
aramid
22. Polymers that cannot be repeatedly melted and re- formed due to strong covalent bonding between chains
poly- p- phenylene benzobisoxazole PBO
thermosets
polymers
homopolymer
23. Term used to describe a polymer that contains significant numbers of both syndiotactic and isotactic dyads
weight average molecular weight Mw
atactic
dyes
polyurethanes
24. Covalent bonding of the polymer backbone and side groups
random copolymers
copolymer
primary bonding
asymetric
25. Technique used to make rayon - which involves treating cellulose from wood or cotton with alkali and extruding it through a spinneret
viscose process
any carbon with double bonds or repeated substituents
vinyl monomer
eclipsed conformation/ cis - conformation
26. Second- order thermodynamic transition in which the onset of large scale chain mobility occures in polymers. Bellow Tg the polymer is glasslike and brittle. above Tg the polymer becomes rubbery and flexible
primary bonding
monomers
glass transition temperature Tg
primary termination
27. Smallest repeating unit in a polymer. aka repeat unit
cracking
primary termination
structural unit
tow
28. Circular - stationary block with small holes through which molten polymer can flow to take the shape of a fiber
polypphenylene terephyhalamide PPTA
configuration
spinneret
termination
29. Double bounded organic molecule used to begin addition polymerization
random copolymers
addition polymerization/chain growth/free- radical polymerization
vinyl monomer
vulcanization
30. Term associate with blown - film apparatus - which indicated the point at which the molecules develop a more crystalline orientation around the bubble of air
freeze line
polyviyl chloride PVC
configuration
most common condensation/step- growth polymerization occur between....
31. Lightwieght polymer that absorbs water well; the first syntheric polymer ever constructed
fillers
petroleum
rayon
High volume thermoplastics HVTP
32. Polymers comprised of two or more different monomers - which attach to the polymer chain in no particular order of pattern
random copolymers
polymers
initiation
secondary bonding
33. Additives that improve a polymer's resistance to variable that cause bonds to rupture - such as heat and light
configuration
stabilizers
primary termination
secondary bonding
34. Polymers comprised of two or more different monomer units that attach to the chain in an alternating pattern A-B-A-B...
alternating copolymers
thermosets
melt spinning
termination
35. Specific arrangements of atoms that cause organic compounds to behave in predictable ways
polyurethanes
gauche conformation
functional groups
constitution
36. All issues related to bonding in polymers including primary and secondary bonding - branching - formations of networks - and end groups
quenching
petroleum
constitution
die
37. Occurs when substituent are directly aligned - causing substantial repulsion between the substituents and an unfavorable conformation.
condensation/step- growth polymerization
any carbon with double bonds or repeated substituents
thermoplastics
eclipsed conformation/ cis - conformation
38. On of the two most common reaction schemes used to create polymers - involving three steps: initiaition - propogation - and termination
branching
addition polymerization/chain growth/free- radical polymerization
trans - conformation
stabilizers
39. Conformation in which the largest substituents are offset by 180
block copolymers
trans - conformation
tow
most common condensation/step- growth polymerization occur between....
40. Relative configuration of adjecent asymmetric carbons
tacticity
functional groups
cracking
freeze line
41. Terminating a condensation/step- growth polymerization reaction by adding a material with only one functional group
plasticizers
quenching
eclipsed conformation/ cis - conformation
mutual termination
42. Covalently bonded atoms which are usualy carbon - that comprise the center of the polymer chain.
condensation/step- growth polymerization
free radical
thermosets
polymer backbone
43. Arrangement of the largest substituents where the substituets are offset by 120
staggered conformation
die
nylon
plyacrylonitrile PAN
44. High distance- dependent bonding between adjacent polymer chains; usually includes hydrogen bonding - dipoles - and van der waals
relative molecular mass RMM
pigments
secondary bonding
oligomers
45. Spatial arrangement of substituents around the main chain carbon atom that can be altered only by the breaking of bonds
freeze line
weight average molecular weight Mw
configuration
pigments
46. Specified weight of a polymer that is injected into the mold at the end of the barrel during the injection molding process
syndiotactic dyad
shot size
most common condensation/step- growth polymerization occur between....
block copolymers
47. Stiff and extremely inert polymer - low cost - chemical and moisture resistant - outdoor stability
rayon
High volume thermoplastics HVTP
polyviyl chloride PVC
trans - conformation
48. One of the two different types of termination in the polymerization process. during this type of termination - the free radicals from two different polymer chains join to end the propogation process
thermosets
degree of polymerization DPn
polymers
mutual termination
49. Configuration of a substituent in a polymer - in which the substituent is located on the same side of the polymer chain in all repeating units
elastomers
isotactic dan
mutual termination
thermoplastics
50. Number of repeat/structural units in a polymer chain
extruder
most common condensation/step- growth polymerization occur between....
weight average molecular weight Mw
degree of polymerization DPn
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