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Test your basic knowledge |
CLEP Chemistry 1
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Subjects
:
clep
,
science
,
chemistry
Instructions:
Answer 50 questions in 15 minutes.
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.
Match each statement with the correct term.
Don't refresh. All questions and answers are randomly picked and ordered every time you load a test.
This is a study tool. The 3 wrong answers for each question are randomly chosen from answers to other questions. So, you might find at times the answers obvious, but you will see it re-enforces your understanding as you take the test each time.
1. The relatively weak attractive forces between molecules that are apparent only when the molecules approach one another closely (usually at low temperatures and high pressure).
kinetic molecular theory
Van der Waals
freezing point depression
decomposition
2. The enthalpy changes associated with the reactions that correspond to the formation of a substance from its free elements are called?
activation energy
base - acid
heats of formation
moles (Le Chatelier's principle)
3. **As we proceed to the right of the table - ______-forming properties decrease and _____-forming properties increase.
increasing
left (Le Chatelier's principle)
VSEPR
base - acid
4. A law stating that at a constant temperature - the volume of a gas in inversely proportiona to the pressure.
Boyles law
negative
system (thermodynamics)
combined gas law
5. The molecules in a gas collide with one another - but the collisions are perfectly elastic (they result in no net loss of energy).
kinetic molecular theory
first law of thermodynamics
combination
end point
6. *Molecules of ideal gases have no attraction for one another and have no intrinsic volume - they are ______ _____
Le Chatelier's principle
state functions (thermodynamics)
reversible
point particles
7. An increase in temperature causes the position of equilibrium of an exothermic reaction to be shifted to the _____ - while that of and endothermic reactions is shifted to the _______.
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8. A process that occurs whent eh system is maintained at constant pressure.
reversible reaction
melting point
isopiestic process (thermodynamics)
Avogrados law
9. The process of mixing different orbitals of the same atom to form a new set of equivalent orbitals.
equivalent point
temperature
hybridyzation
...
10. The particular portion of the universe on which we wish to focus our attention. Everything else is called the surroundings.
reversible
system (thermodynamics)
Van der Waals
double replacement/displacement
11. _______ has very little effect on the solubility of liquids or solids in liquid solvents.
pressure
Van der Waals
high
total pressure (Le Chatelier's principle)
12. A chemical reaction formed from the breakdown of a compound into its individual elements or compounds.
state (thermodynamics)
dynamic equilibrium
2
decomposition
13. This process occurs when the system is thermally isolated so that no heat enters or leaves.
adiabatic process (thermodynamics)
increases
positive charge
kinetic molecular theory
14. When the rate of evaporation equals the rate of condensation - the system is in __________.
positive charge
...
equilibrium
equation of state
15. Any spontaneous change in a chemical reaction will decrease the amount of free energy toward _______ as the process proceeds towards equilibrium.
zero
irreversible and reversible processes
positive charge
single replacement/displacement
16. A catalyst affects a chemical reaction by lowering the _____ _____ for both the forward and the reverse reactions equally.
electrolytic reactions
end point
adiabatic process (thermodynamics)
activation energy
17. Cells that convert electrical energy into chemical energy.
electrolytic cells
first law of thermodynamics
Van der Waals
right (Le Chatelier's principle)
18. A pure crystal of elemental metal consists of roughly Avogrado's number of atoms held together by ________ bonds.
first law of thermodynamics
metallic
negative
base - acid
19. The heat change during a process carried out at a constant pressure.
heats of formation
irreversible and reversible processes
specific heat
change in enthalpy
20. The freezing point is always lowered by addition of solute.
negative
metallic
enthalpy
freezing point depression
21. A state function in which it is the heat content of a substance.
vapor pressure
limiting law
enthalpy
activation energy barrier (Le Chatelier's principle)
22. **Five factors that affect reaction rates: 1. The nature of the reactants and products. 2. The surface area exposed. 3. The concentrations. 4. The temperature. 5. The catalyst.
...
equivalent point
decreases
total pressure (Le Chatelier's principle)
23. The law stating that change in internal energy is equal to the difference between the energy supplied toi the system as heat and the energy removed from the system as work performed on the surroundings.
kinetic molecular theory
system (thermodynamics)
double replacement/displacement
first law of thermodynamics
24. The maximum work derived from any change will be obtained only if the process is carried out in a reversible manner. All real - spontaneous changes are therefore not reversible - and the work that can be derived from an irreversible change is alway l
irreversible and reversible processes
decreases
colligative property law
saturated solution
25. The general shape of any molecule can be predicted from the number of bonding and non-bonding electron pairs in the valence shell of the central atom. nonbonded pairs of electrons (lone pairs) are more repellent than bonded pairs.
decomposition
VSEPR
zero
negative
26. Metals have electronegativities less than ____
2
dynamic equilibrium
combined gas law
isopiestic process (thermodynamics)
27. *The Concentration usually _____ the chemical reaction rate with increasing concentrations of the reactants.
hybridyzation
point particles
molar heat of sublimation
increases
28. *The hypothetical ideal gas obeys exactly the mathematical statement of the ideal gas law. This statement is also called the _____ ___ ____ of an ideal gas because it relates the variables (P - V - n - T) that specify properties of the gas.
equation of state
...
decreases
Avogrados law
29. This process occurs when the system is maintained at the same temperature throughout an experiment.
third law of thermodynamics
isothermal process (thermodynamics)
valence
saturated solution
30. When a system at equilibrium is disturbed by adding or removing one of hte substances - all the concentrations will change until a new equilibrium point is reached with the same value of Keq.
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31. Another way the second law is stated is that in any spontaneous change - the amount of free energy available ______.
...
increases
decreases
non-ideal
32. The change in enthalpy of an endothermic reaction is ________.
irreversible and reversible processes
change in enthalpy
...
positive
33. Deviations from Boyles law that occur with real gases represent _______ behavior.
equation of state
melting point
non-ideal
10 degrees
34. In an exothermic process - energy is released and ^E of reaction is ________.
activation energy barrier (Le Chatelier's principle)
positive
negative
electromotive force (emf)/ cell
35. The vapor pressure of an aqueous solution is always lowered by the additon of more solute - which causes the boiling point to be raised.
system (thermodynamics)
positive charge
decreases
boiling point elevation
36. Increasing the pressure on a system at equilibrium will cause a shift in the position of equilibrium in the direction of the fewest number of ______ of gaseous reactants or products.
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37. A law stating that the vapor pressure of a solution at a particular temperature is equal to teh mole fraction of the solvent in the liquid phase multiplied by the vapor pressure of the pure solvent at the same temperature.
Raoults law
crystallizes
Van der Waals
absorbs (in atomic spectra)
38. Real gases act in a less than ideal way - especially under conditions of increased pressure and/or decreased temperture. Real gas behavior approaches that of ideal gases as the gas pressure becomes very low. The ideal gas is thus considered a _____ _
limiting law
kinetic molecular theory
heats of formation
left (Le Chatelier's principle)
39. The energy required to remove an electron from an isolated atom in its ground state.
partial
ionization energy
heats of formation
phase equilibrium
40. In a closed system - when opposing changes are taking place at equal rates - the system is said to be in _____ _______.
electromotive force (emf)/ cell
dynamic equilibrium
state (thermodynamics)
Le Chatelier's principle
41. *The electrons found in the outermost shell are called _____ electrons. When these electrons are lost or partially lost through sharing - the oxidation state is assigned a positive value for the element. If valence electrons are gained or partially g
change in enthalpy
valence
kinetic molecular theory
Raoults law
42. _____ bonds are present in molecules containing double or triple bonds.
pi bonds
absorbs (in atomic spectra)
vapor pressure
saturated solution
43. The ______ of the system is some particular set of conditions of pressure - temperature - number of moles of each component - and their physical form (ex: gas - liquid - solid or crystalline form).
phase equilibrium
entropy
state (thermodynamics)
equilibrium
44. A theory of the hydrogen atom stating that the electron can exist in only certain stable energy levels and that when the electronic state of the atom changes - it must absorb or emit exactly that amound of energy equal to the difference betweent he f
heat capacity
high
bohr model
system (thermodynamics)
45. *Each wave function corresponds to a certain electron energy and describes a region about the nucleus (orbital) where an electron having that energy may be found.
catalysts
wave mechanical model
system (thermodynamics)
emits (in atomic spectra)
46. *The surface area exposed affect chemical reactions because most reactions depend on the reactants coming into contact - increasing the rate of the reaction.
reversible reaction
...
heats of formation
crystallizes
47. If this law was strictly obeyed - gases would not condense when they are cooled. This means that gases behave in an ideal fashion only at relatively high temperatures and low pressures.
kinetic molecular theory
Charles law
specific heat
hydrolysis
48. For most substances - when a hot concentrated solution is cooled - the excess solid ________. This is useful in purification of the solute.
anode rays
crystallizes
titration
kinetic molecular theory
49. The heat required to change 1mole of solid completely to vapor.
vapor pressure
equation of state
equivalent point
molar heat of sublimation
50. A law stating that at constant pressure - the volume of a given quantity of a gas varies directly with the temperature.
Van der Waals
Charles law
second law of thermodynamics
total pressure (Le Chatelier's principle)
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