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CLEP Chemistry 1
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Subjects
:
clep
,
science
,
chemistry
Instructions:
Answer 50 questions in 15 minutes.
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study here
.
Match each statement with the correct term.
Don't refresh. All questions and answers are randomly picked and ordered every time you load a test.
This is a study tool. The 3 wrong answers for each question are randomly chosen from answers to other questions. So, you might find at times the answers obvious, but you will see it re-enforces your understanding as you take the test each time.
1. The most active nonmetals are found in what corner of the periodic table?
titration
upper right corner
phase equilibrium
change in enthalpy
2. A principle stating that when a system at equilibrium is disturbed by the application of a stress (change in temperature - pressure - or concentration) it reacts to minimize the stress and attain a new equilibrium position.
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3. For a ________ reaction - the energy liberated in the exothermic reaction equals the energy absorbed in the endothermic reaction.
reversible reaction
single replacement/displacement
enthalpy
entropy
4. In a _______ expansion of a gas - the opposing pressure is virtually equal to the pressure exerted by the gas. It is ______ because any slight increase in the external pressure will reverse the process and cause compression to occure.
metallic
reversible
...
high
5. A hypothetical gas would follow Boyles law under all conditions and is called?
hybridyzation
increasing
ideal gas
state (thermodynamics)
6. A catalyst lowers the ______ _____ _____ that must be overcome in order for the reaction to proceed. It merely speeds the approach to equilibrium but does not change Keq at all.
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7. Cells that convert electrical energy into chemical energy.
adiabatic process (thermodynamics)
Van der Waals
electrolytic cells
Charles law
8. The pressure exerted by the gas molecules when they are in equilibrium with the liquid.
ideal gas
increasing
vapor pressure
kinetic molecular theory
9. A law stating that at a constant temperature - the volume of a gas in inversely proportiona to the pressure.
Boyles law
decreases
kinetic molecular theory
increases
10. *Each wave function corresponds to a certain electron energy and describes a region about the nucleus (orbital) where an electron having that energy may be found.
negative
partial
kinetic molecular theory
wave mechanical model
11. A chemical reaction where one substance is displacing another. ex: Fe + CuSo4 -> FeSo4 + Cu.
single replacement/displacement
electronegativity
kinetic molecular theory
increases
12. The freezing point is always lowered by addition of solute.
catalysts
Raoult's law
vapor pressure
freezing point depression
13. The law stating that in any spontaneous process there is an increase in the entropy of the universe.
base - acid
second law of thermodynamics
positive
absorbs (in atomic spectra)
14. Rays made up of electrons in basic electron charges.
cathode rays
sublimation
Van der Waals
third law of thermodynamics
15. The amount of heat energy required to raise the temperature 1g of a substance by 1 degree celcius.
limiting law
lower left corner
specific heat
entropy
16. When a hydrogen atom is bonded to a highly electronegative atom - it will become partially _____-charged - and will be attracted to neighboring electron pairs. This creates a hydrogen bond. The more polar the molecule - the more effective the hydroge
Daltons law
heats of formation
single replacement/displacement
positive charge
17. In a closed system - when the rates of evaporation and condensation are equal - the system is in ____ ______.
absorbs (in atomic spectra)
phase equilibrium
electronegativity
titration
18. The ________ of an element is a number that measerures the relative strength in which the atoms of the element attract valence electrons in a chemical bond - on a scale of 0-4.
electrolytic reactions
right (Le Chatelier's principle)
negative
electronegativity
19. A state function in which it is the heat content of a substance.
colligative property law
Nernst equation
enthalpy
titration
20. The general shape of any molecule can be predicted from the number of bonding and non-bonding electron pairs in the valence shell of the central atom. nonbonded pairs of electrons (lone pairs) are more repellent than bonded pairs.
kinetic molecular theory
Charles law
VSEPR
titration
21. Another way the second law is stated is that in any spontaneous change - the amount of free energy available ______.
double replacement/displacement
decreases
positive
dynamic equilibrium
22. For most substances - when a hot concentrated solution is cooled - the excess solid ________. This is useful in purification of the solute.
VSEPR
kinetic molecular theory
Van der Waals
crystallizes
23. A solution in which solid solute is in equilibrium with dissolved solute.
saturated solution
Charles law
limiting law
Avogrados law
24. This is due to the way positive charges of one molecule attract the negative charges of another molecule. Compounds of the solid state that are bound mainly by this type of attractive have soft crystals - are easily deformed - and vaporize easily.
Le Chatelier's principle
Van der Waals
VSEPR
wave mechanical model
25. The particular portion of the universe on which we wish to focus our attention. Everything else is called the surroundings.
electrolytic reactions
system (thermodynamics)
ideal gas
kinetic molecular theory
26. _____ bonds are present in molecules containing double or triple bonds.
combined gas law
pi bonds
boiling point elevation
temperature
27. A chemical reaction where there is an actual exchange of partners to form new compounds. ex: AgNO3 + NaCl -> AgCl + NaNO3.
catalysts
Raoults law
double replacement/displacement
high
28. The _____ speed up the rate of a chemical reaction but do not change the equilibrium constant - it simply speeds up the rate of approach to equilibrium.
left - right (Le Chatelier's principle)
catalysts
base - acid
wave mechanical model
29. The vapor pressure of an aqueous solution is always lowered by the additon of more solute - which causes the boiling point to be raised.
end point
state (thermodynamics)
boiling point elevation
Nernst equation
30. The enthalpy changes associated with the reactions that correspond to the formation of a substance from its free elements are called?
electromotive force (emf)/ cell
entropy
heats of formation
kinetic molecular theory
31. For a cell at concentrations and conditions other than standard - a potential can be calculated using this equation.
Nernst equation
boiling point elevation
ionization energy
activation energy barrier (Le Chatelier's principle)
32. When an electron moves from an excited state to the ground state - it _______ energy.
hydrolysis
emits (in atomic spectra)
ideal gas
electromotive force (emf)/ cell
33. In an exothermic process - energy is released and ^E of reaction is ________.
isothermal process (thermodynamics)
reversible reaction
negative
anode rays
34. This process occurs when the system is thermally isolated so that no heat enters or leaves.
enthalpy
adiabatic process (thermodynamics)
specific heat
positive charge
35. If an inert gas is introduced into a reaction vessel containing other gases at equilibrium - it will cause an increase in the ______ _____ within the container - but the increase will not affect the position of equilibrium.
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36. Electronegativities _______ as you go down a group.
decreases
2
base - acid
point particles
37. *The temperature affects chemical reactions with an increase of ___degrees C above room temperature - causing the reaction rate to double.
ideal gas
VSEPR
kinetic molecular theory
10 degrees
38. The change in enthalpy of an endothermic reaction is ________.
heat capacity
vapor pressure
positive
absorbs (in atomic spectra)
39. _______ has very little effect on the solubility of liquids or solids in liquid solvents.
catalysts
reversible reaction
crystallizes
pressure
40. Increasing the pressure on a system at equilibrium will cause a shift in the position of equilibrium in the direction of the fewest number of ______ of gaseous reactants or products.
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41. The normal boiling point of a liquid is the temperature at which its vapor pressure is 760mm Hg.
increasing
standard atmospheric pressure
electronegativity
equation of state
42. The relatively weak attractive forces between molecules that are apparent only when the molecules approach one another closely (usually at low temperatures and high pressure).
Van der Waals
ionization energy
molar heat of sublimation
ideal gas
43. The process of determining the amount of a solution of known concentration that is required to react completely with a certain amount of a sample that is being analyzed.
2
titration
molar heat of sublimation
...
44. The pressure of a gas is the result of collisions between the gas molecules and the walls of the container.
Raoults law
moles (Le Chatelier's principle)
increases
kinetic molecular theory
45. The heat change during a process carried out at a constant pressure.
change in enthalpy
increases
third law of thermodynamics
sublimation
46. The freezing point - boiling point - and vapor pressure of a solution differ from those of the pure solvent by amounts which are directly proportional to the molal concentration of the solute.
bohr model
10 degrees
heats of formation
colligative property law
47. The process of mixing different orbitals of the same atom to form a new set of equivalent orbitals.
hybridyzation
Boyles law
electrolytic cells
activation energy
48. The pressure exerted by each gas in a mixture is called its _____ pressure.
reversible reaction
hydrolysis
positive
partial
49. A process that occurs whent eh system is maintained at constant pressure.
saturated solution
state functions (thermodynamics)
isopiestic process (thermodynamics)
non-ideal
50. *The hypothetical ideal gas obeys exactly the mathematical statement of the ideal gas law. This statement is also called the _____ ___ ____ of an ideal gas because it relates the variables (P - V - n - T) that specify properties of the gas.
emits (in atomic spectra)
reversible
equation of state
boiling point elevation
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