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Test your basic knowledge |
CLEP Chemistry 1
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Subjects
:
clep
,
science
,
chemistry
Instructions:
Answer 50 questions in 15 minutes.
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.
Match each statement with the correct term.
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This is a study tool. The 3 wrong answers for each question are randomly chosen from answers to other questions. So, you might find at times the answers obvious, but you will see it re-enforces your understanding as you take the test each time.
1. Heat added to a system and work done by a system are considered _________ quantities.
moles (Le Chatelier's principle)
positive
heats of formation
enthalpy
2. When the rate of evaporation equals the rate of condensation - the system is in __________.
standard atmospheric pressure
kinetic molecular theory
partial
equilibrium
3. In a _______ expansion of a gas - the opposing pressure is virtually equal to the pressure exerted by the gas. It is ______ because any slight increase in the external pressure will reverse the process and cause compression to occure.
equation of state
increases
kinetic molecular theory
reversible
4. A chemical reaction where one substance is displacing another. ex: Fe + CuSo4 -> FeSo4 + Cu.
crystallizes
kinetic molecular theory
electromotive force (emf)/ cell
single replacement/displacement
5. *The temperature affects chemical reactions with an increase of ___degrees C above room temperature - causing the reaction rate to double.
zero
10 degrees
total pressure (Le Chatelier's principle)
equilibrium
6. The energy required to remove an electron from an isolated atom in its ground state.
ionization energy
high
...
kinetic molecular theory
7. The maximum work derived from any change will be obtained only if the process is carried out in a reversible manner. All real - spontaneous changes are therefore not reversible - and the work that can be derived from an irreversible change is alway l
dynamic equilibrium
irreversible and reversible processes
combined gas law
wave mechanical model
8. The process of mixing different orbitals of the same atom to form a new set of equivalent orbitals.
kinetic molecular theory
increases
hybridyzation
colligative property law
9. *Molecules of ideal gases have no attraction for one another and have no intrinsic volume - they are ______ _____
right (Le Chatelier's principle)
point particles
positive charge
Charles law
10. The average kinetic energy of all the molecules collectively is directly proportional to the absolute temperature of the gas. The average kinetic energy of equal numbers of molecules of any gas is the same at the same temperature.
kinetic molecular theory
third law of thermodynamics
electronegativity
combined gas law
11. The change in enthalpy of an exothermic reaction is ________.
molar heat of sublimation
increases
negative
enthalpy
12. *The hypothetical ideal gas obeys exactly the mathematical statement of the ideal gas law. This statement is also called the _____ ___ ____ of an ideal gas because it relates the variables (P - V - n - T) that specify properties of the gas.
Van der Waals
upper right corner
equation of state
Raoult's law
13. For a cell at concentrations and conditions other than standard - a potential can be calculated using this equation.
total pressure (Le Chatelier's principle)
lower left corner
Nernst equation
kinetic molecular theory
14. A state function in which it is the heat content of a substance.
Le Chatelier's principle
kinetic molecular theory
enthalpy
decreases
15. The action of salts of weak acids or bases with water to form acidic or basic solutions.
adiabatic process (thermodynamics)
hydrolysis
Nernst equation
activation energy barrier (Le Chatelier's principle)
16. The temperature at which the pressure of vapor escaping from the liquid equals atmospheric pressure.
increases
reversible reaction
boiling point
electromotive force (emf)/ cell
17. A chemical reaction where there is an actual exchange of partners to form new compounds. ex: AgNO3 + NaCl -> AgCl + NaNO3.
combination
kinetic molecular theory
catalysts
double replacement/displacement
18. *The electrons found in the outermost shell are called _____ electrons. When these electrons are lost or partially lost through sharing - the oxidation state is assigned a positive value for the element. If valence electrons are gained or partially g
third law of thermodynamics
isothermal process (thermodynamics)
equivalent point
valence
19. *The surface area exposed affect chemical reactions because most reactions depend on the reactants coming into contact - increasing the rate of the reaction.
Van der Waals
...
molar heat of sublimation
Charles law
20. The heat required to change 1mole of solid completely to vapor.
molar heat of sublimation
point particles
ideal gas
first law of thermodynamics
21. This process occurs when the system is maintained at the same temperature throughout an experiment.
isothermal process (thermodynamics)
absorbs (in atomic spectra)
isopiestic process (thermodynamics)
third law of thermodynamics
22. A law that states that under conditions of constant temperature and pressure - equal volumes of different gases contain equal numbers of molecules.
enthalpy
Avogrados law
activation energy
end point
23. If this law was strictly obeyed - gases would not condense when they are cooled. This means that gases behave in an ideal fashion only at relatively high temperatures and low pressures.
Charles law
single replacement/displacement
change in enthalpy
total pressure (Le Chatelier's principle)
24. Another way the second law is stated is that in any spontaneous change - the amount of free energy available ______.
reversible reaction
Daltons law
phase equilibrium
decreases
25. An increase in temperature causes the position of equilibrium of an exothermic reaction to be shifted to the _____ - while that of and endothermic reactions is shifted to the _______.
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26. **As we proceed to the right of the table - ______-forming properties decrease and _____-forming properties increase.
standard atmospheric pressure
colligative property law
base - acid
heat capacity
27. In an endothermic process - energy is absorbed and ^E is _______.
VSEPR
kinetic molecular theory
positive
second law of thermodynamics
28. _____ bonds are present in molecules containing double or triple bonds.
Charles law
emits (in atomic spectra)
pi bonds
combined gas law
29. A catalyst affects a chemical reaction by lowering the _____ _____ for both the forward and the reverse reactions equally.
non-ideal
positive
point particles
activation energy
30. The amount of heat energy required to raise the temperature 1g of a substance by 1 degree celcius.
increases
specific heat
positive
electronegativity
31. This is due to the way positive charges of one molecule attract the negative charges of another molecule. Compounds of the solid state that are bound mainly by this type of attractive have soft crystals - are easily deformed - and vaporize easily.
molar heat of sublimation
positive
Charles law
Van der Waals
32. The ________ of an element is a number that measerures the relative strength in which the atoms of the element attract valence electrons in a chemical bond - on a scale of 0-4.
electronegativity
phase equilibrium
reversible reaction
positive charge
33. The change in enthalpy of an endothermic reaction is ________.
Charles law
Raoult's law
2
positive
34. Gases are composed of tiny - invisible molecules that are widely separated from one another in otherwise empty space.
pressure
kinetic molecular theory
third law of thermodynamics
lower left corner
35. A hypothetical gas would follow Boyles law under all conditions and is called?
ideal gas
boiling point elevation
right (Le Chatelier's principle)
positive
36. The enthalpy changes associated with the reactions that correspond to the formation of a substance from its free elements are called?
heats of formation
electrolytic cells
ideal gas
entropy
37. For most substances - when a hot concentrated solution is cooled - the excess solid ________. This is useful in purification of the solute.
end point
Raoult's law
crystallizes
activation energy barrier (Le Chatelier's principle)
38. A law stating that the vapor pressure of a solution at a particular temperature is equal to teh mole fraction of the solvent in the liquid phase multiplied by the vapor pressure of the pure solvent at the same temperature.
decomposition
Raoults law
positive charge
metallic
39. When solids are heated at certain perssures - some solids vaporize directly without passing through the liquid phase.
sublimation
phase equilibrium
saturated solution
decreases
40. A solution in which solid solute is in equilibrium with dissolved solute.
melting point
saturated solution
Boyles law
10 degrees
41. Rays made up of positive electrodes in basic electron charges.
decreases
heat capacity
specific heat
anode rays
42. The pressure exerted by each gas in a mixture is called its _____ pressure.
partial
bohr model
dynamic equilibrium
Valence Shell Electron Pair Repulsion (VSEPR)
43. When a system at equilibrium is disturbed by adding or removing one of hte substances - all the concentrations will change until a new equilibrium point is reached with the same value of Keq.
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44. A pure crystal of elemental metal consists of roughly Avogrado's number of atoms held together by ________ bonds.
lower left corner
metallic
bohr model
Van der Waals
45. When a hydrogen atom is bonded to a highly electronegative atom - it will become partially _____-charged - and will be attracted to neighboring electron pairs. This creates a hydrogen bond. The more polar the molecule - the more effective the hydroge
positive charge
crystallizes
Avogrados law
metallic
46. State ________ depend only on the present state of the substance and not on the path by which the present state was attained. Enthalpy - energy - Gibbs free energy - and entropy are examples.
specific heat
first law of thermodynamics
state functions (thermodynamics)
single replacement/displacement
47. This law states that the total pressure exerted by a mixture of gases is equal to the sum of the partial pressures of the gases in mixture.
first law of thermodynamics
Daltons law
Van der Waals
limiting law
48. When an electron moves from an excited state to the ground state - it _______ energy.
sublimation
emits (in atomic spectra)
left (Le Chatelier's principle)
electromotive force (emf)/ cell
49. In titration - this is the point at which a particular indicator changes color.
end point
high
wave mechanical model
colligative property law
50. The particular portion of the universe on which we wish to focus our attention. Everything else is called the surroundings.
increases
Raoult's law
system (thermodynamics)
sublimation
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