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CLEP Chemistry 1
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Subjects
:
clep
,
science
,
chemistry
Instructions:
Answer 50 questions in 15 minutes.
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study here
.
Match each statement with the correct term.
Don't refresh. All questions and answers are randomly picked and ordered every time you load a test.
This is a study tool. The 3 wrong answers for each question are randomly chosen from answers to other questions. So, you might find at times the answers obvious, but you will see it re-enforces your understanding as you take the test each time.
1. The relatively weak attractive forces between molecules that are apparent only when the molecules approach one another closely (usually at low temperatures and high pressure).
dynamic equilibrium
reversible reaction
Van der Waals
increases
2. The freezing point is always lowered by addition of solute.
increases
...
freezing point depression
kinetic molecular theory
3. *The Concentration usually _____ the chemical reaction rate with increasing concentrations of the reactants.
anode rays
increases
sublimation
Daltons law
4. *The nature of the reactants and products affect chemical reactions because some elements and compounds have bonds that when broken/formed - react more rapidly with each other than others.
Raoults law
heats of formation
...
kinetic molecular theory
5. The particular portion of the universe on which we wish to focus our attention. Everything else is called the surroundings.
system (thermodynamics)
anode rays
end point
heat capacity
6. This is due to the way positive charges of one molecule attract the negative charges of another molecule. Compounds of the solid state that are bound mainly by this type of attractive have soft crystals - are easily deformed - and vaporize easily.
wave mechanical model
Van der Waals
anode rays
reversible reaction
7. In a closed system - when the rates of evaporation and condensation are equal - the system is in ____ ______.
increases
high
phase equilibrium
Boyles law
8. The temperature at which the pressure of vapor escaping from the liquid equals atmospheric pressure.
cathode rays
...
Van der Waals
boiling point
9. Rays made up of positive electrodes in basic electron charges.
irreversible and reversible processes
anode rays
non-ideal
decreases
10. Electronegativities _______ as you go down a group.
Le Chatelier's principle
change in enthalpy
positive
decreases
11. The law stating that change in internal energy is equal to the difference between the energy supplied toi the system as heat and the energy removed from the system as work performed on the surroundings.
first law of thermodynamics
hybridyzation
sublimation
temperature
12. The energy required to remove an electron from an isolated atom in its ground state.
electrolytic cells
combined gas law
ionization energy
irreversible and reversible processes
13. In an exothermic process - energy is released and ^E of reaction is ________.
entropy
negative
specific heat
Avogrados law
14. The force with which the electrons flow from the negative electrode to the positive electrode through an external wire is called?
...
...
electromotive force (emf)/ cell
partial
15. A catalyst affects a chemical reaction by lowering the _____ _____ for both the forward and the reverse reactions equally.
state functions (thermodynamics)
absorbs (in atomic spectra)
activation energy
negative
16. A law stating that the vapor pressure of a solution at a particular temperature is equal to teh mole fraction of the solvent in the liquid phase multiplied by the vapor pressure of the pure solvent at the same temperature.
Raoults law
kinetic molecular theory
double replacement/displacement
...
17. Any spontaneous change in a chemical reaction will decrease the amount of free energy toward _______ as the process proceeds towards equilibrium.
ionization energy
electromotive force (emf)/ cell
Van der Waals
zero
18. In an endothermic process - energy is absorbed and ^E is _______.
positive
boiling point
kinetic molecular theory
2
19. In a closed system - when opposing changes are taking place at equal rates - the system is said to be in _____ _______.
decreases
catalysts
dynamic equilibrium
Boyles law
20. The _____ speed up the rate of a chemical reaction but do not change the equilibrium constant - it simply speeds up the rate of approach to equilibrium.
standard atmospheric pressure
base - acid
boiling point elevation
catalysts
21. A pure crystal of elemental metal consists of roughly Avogrado's number of atoms held together by ________ bonds.
change in enthalpy
emits (in atomic spectra)
metallic
VSEPR
22. The molecules in a gas collide with one another - but the collisions are perfectly elastic (they result in no net loss of energy).
negative
molar heat of sublimation
increases
kinetic molecular theory
23. *Molecules of ideal gases have no attraction for one another and have no intrinsic volume - they are ______ _____
point particles
temperature
electronegativity
molar heat of sublimation
24. Because of the low intermolecular forces - the melting points are low and evaporation takes place so easily that it may occur at room temperature.
standard atmospheric pressure
equation of state
point particles
Van der Waals
25. For a solution in which a nonvolatile solute is dissolved in a solvent - the vapor pressure is due only to the vapor of the solvent above the solution. This vapor pressure is given by _______ law.
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26. In a _______ expansion of a gas - the opposing pressure is virtually equal to the pressure exerted by the gas. It is ______ because any slight increase in the external pressure will reverse the process and cause compression to occure.
increases
catalysts
reversible
combined gas law
27. A chemical reaction formed from the union of its elements.
increases
emits (in atomic spectra)
boiling point elevation
combination
28. Increase in the concentrations of reactants shifts the equilibrium to the ______ - thus increasing the amount of products formed.
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29. State ________ depend only on the present state of the substance and not on the path by which the present state was attained. Enthalpy - energy - Gibbs free energy - and entropy are examples.
saturated solution
specific heat
state functions (thermodynamics)
equation of state
30. A chemical reaction where one substance is displacing another. ex: Fe + CuSo4 -> FeSo4 + Cu.
Le Chatelier's principle
first law of thermodynamics
Daltons law
single replacement/displacement
31. This process occurs when the system is maintained at the same temperature throughout an experiment.
bohr model
isothermal process (thermodynamics)
Le Chatelier's principle
Raoults law
32. **Five factors that affect reaction rates: 1. The nature of the reactants and products. 2. The surface area exposed. 3. The concentrations. 4. The temperature. 5. The catalyst.
temperature
...
anode rays
emits (in atomic spectra)
33. The enthalpy changes associated with the reactions that correspond to the formation of a substance from its free elements are called?
first law of thermodynamics
increases
third law of thermodynamics
heats of formation
34. When the rate of evaporation equals the rate of condensation - the system is in __________.
melting point
state (thermodynamics)
first law of thermodynamics
equilibrium
35. When an electron moves from an excited state to the ground state - it _______ energy.
decreases
Valence Shell Electron Pair Repulsion (VSEPR)
equilibrium
emits (in atomic spectra)
36. **Proceeding across a period from left to right - the ionization energy _______.
cathode rays
kinetic molecular theory
catalysts
increases
37. This process occurs when the system is thermally isolated so that no heat enters or leaves.
irreversible and reversible processes
adiabatic process (thermodynamics)
catalysts
VSEPR
38. A theory of the hydrogen atom stating that the electron can exist in only certain stable energy levels and that when the electronic state of the atom changes - it must absorb or emit exactly that amound of energy equal to the difference betweent he f
double replacement/displacement
third law of thermodynamics
activation energy
bohr model
39. A process that occurs whent eh system is maintained at constant pressure.
isopiestic process (thermodynamics)
positive charge
lower left corner
ionization energy
40. For a ________ reaction - the energy liberated in the exothermic reaction equals the energy absorbed in the endothermic reaction.
reversible reaction
Le Chatelier's principle
positive
catalysts
41. The most active nonmetals are found in what corner of the periodic table?
kinetic molecular theory
emits (in atomic spectra)
isopiestic process (thermodynamics)
upper right corner
42. When solids are heated at certain perssures - some solids vaporize directly without passing through the liquid phase.
sublimation
emits (in atomic spectra)
left (Le Chatelier's principle)
decreases
43. Deviations from Boyles law that occur with real gases represent _______ behavior.
system (thermodynamics)
kinetic molecular theory
non-ideal
combination
44. Increasing the pressure on a system at equilibrium will cause a shift in the position of equilibrium in the direction of the fewest number of ______ of gaseous reactants or products.
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45. A state function in which it is the heat content of a substance.
pi bonds
end point
enthalpy
non-ideal
46. The heat change during a process carried out at a constant pressure.
molar heat of sublimation
limiting law
change in enthalpy
electronegativity
47. A law that states that for a given mass of gas - the volume is proportional to the pressure and absolute temperature.
left - right (Le Chatelier's principle)
adiabatic process (thermodynamics)
Le Chatelier's principle
combined gas law
48. _______ has very little effect on the solubility of liquids or solids in liquid solvents.
limiting law
left - right (Le Chatelier's principle)
standard atmospheric pressure
pressure
49. A chemical reaction where there is an actual exchange of partners to form new compounds. ex: AgNO3 + NaCl -> AgCl + NaNO3.
positive
double replacement/displacement
kinetic molecular theory
combined gas law
50. The heat required to change 1mole of solid completely to vapor.
molar heat of sublimation
non-ideal
vapor pressure
positive
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