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CLEP Chemistry 1
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Subjects
:
clep
,
science
,
chemistry
Instructions:
Answer 50 questions in 15 minutes.
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.
Match each statement with the correct term.
Don't refresh. All questions and answers are randomly picked and ordered every time you load a test.
This is a study tool. The 3 wrong answers for each question are randomly chosen from answers to other questions. So, you might find at times the answers obvious, but you will see it re-enforces your understanding as you take the test each time.
1. Deviations from Boyles law that occur with real gases represent _______ behavior.
enthalpy
non-ideal
decomposition
10 degrees
2. _____ bonds are present in molecules containing double or triple bonds.
Boyles law
freezing point depression
double replacement/displacement
pi bonds
3. A chemical reaction where one substance is displacing another. ex: Fe + CuSo4 -> FeSo4 + Cu.
entropy
10 degrees
single replacement/displacement
third law of thermodynamics
4. The process of determining the amount of a solution of known concentration that is required to react completely with a certain amount of a sample that is being analyzed.
Van der Waals
titration
saturated solution
equivalent point
5. Metals have electronegativities less than ____
valence
2
Daltons law
titration
6. A law stating that at constant pressure - the volume of a given quantity of a gas varies directly with the temperature.
equilibrium
Charles law
irreversible and reversible processes
pi bonds
7. When an electron moves from an excited state to the ground state - it _______ energy.
hybridyzation
heat capacity
emits (in atomic spectra)
VSEPR
8. This process occurs when the system is thermally isolated so that no heat enters or leaves.
adiabatic process (thermodynamics)
decomposition
zero
kinetic molecular theory
9. Rays made up of positive electrodes in basic electron charges.
electrolytic reactions
anode rays
first law of thermodynamics
electronegativity
10. The freezing point is always lowered by addition of solute.
freezing point depression
activation energy barrier (Le Chatelier's principle)
positive
electrolytic reactions
11. A process that occurs whent eh system is maintained at constant pressure.
temperature
high
sublimation
isopiestic process (thermodynamics)
12. Heat added to a system and work done by a system are considered _________ quantities.
Daltons law
increases
positive
moles (Le Chatelier's principle)
13. *The nature of the reactants and products affect chemical reactions because some elements and compounds have bonds that when broken/formed - react more rapidly with each other than others.
...
negative
increases
high
14. A law stating that at a constant temperature - the volume of a gas in inversely proportiona to the pressure.
Boyles law
freezing point depression
melting point
upper right corner
15. The general shape of any molecule can be predicted from the number of bonding and non-bonding electron pairs in the valence shell of the central atom. nonbonded pairs of electrons (lone pairs) are more repellent than bonded pairs.
electrolytic cells
activation energy
VSEPR
partial
16. In titration - this point occurs when equal numbers of equivalents of acid and base have been reacted. The solution at this point is neutral because neither of the ions of the salt in solution undergoes hydrolysis.
electrolytic cells
equivalent point
Van der Waals
Raoult's law
17. The amount of heat energy required to raise the temperature 1g of a substance by 1 degree celcius.
combined gas law
specific heat
VSEPR
enthalpy
18. A law that states that for a given mass of gas - the volume is proportional to the pressure and absolute temperature.
non-ideal
VSEPR
combined gas law
Daltons law
19. The _____ speed up the rate of a chemical reaction but do not change the equilibrium constant - it simply speeds up the rate of approach to equilibrium.
temperature
catalysts
reversible reaction
electromotive force (emf)/ cell
20. A chemical reaction where there is an actual exchange of partners to form new compounds. ex: AgNO3 + NaCl -> AgCl + NaNO3.
Van der Waals
molar heat of sublimation
right (Le Chatelier's principle)
double replacement/displacement
21. The pressure of a gas is the result of collisions between the gas molecules and the walls of the container.
left - right (Le Chatelier's principle)
adiabatic process (thermodynamics)
electronegativity
kinetic molecular theory
22. A valence theory that permits the geometric arrangement of atoms - or groups of atoms - about some central atom to be determined solely by considering the repulsions between the electron pairs present in the valence shell of the central atom.
bohr model
heat capacity
kinetic molecular theory
Valence Shell Electron Pair Repulsion (VSEPR)
23. If this law was strictly obeyed - gases would not condense when they are cooled. This means that gases behave in an ideal fashion only at relatively high temperatures and low pressures.
melting point
absorbs (in atomic spectra)
Charles law
heat capacity
24. When the electron moves from the ground state to an excited state - it ______ energy.
10 degrees
specific heat
absorbs (in atomic spectra)
Van der Waals
25. The vapor pressure increases with increasing _____.
boiling point
temperature
increases
equilibrium
26. In titration - this is the point at which a particular indicator changes color.
end point
electrolytic cells
equivalent point
freezing point depression
27. *The Concentration usually _____ the chemical reaction rate with increasing concentrations of the reactants.
increases
ionization energy
total pressure (Le Chatelier's principle)
absorbs (in atomic spectra)
28. A law that states that under conditions of constant temperature and pressure - equal volumes of different gases contain equal numbers of molecules.
VSEPR
electronegativity
sublimation
Avogrados law
29. Any spontaneous change in a chemical reaction will decrease the amount of free energy toward _______ as the process proceeds towards equilibrium.
upper right corner
kinetic molecular theory
zero
dynamic equilibrium
30. A catalyst affects a chemical reaction by lowering the _____ _____ for both the forward and the reverse reactions equally.
activation energy
base - acid
Daltons law
pi bonds
31. The pressure exerted by the gas molecules when they are in equilibrium with the liquid.
cathode rays
isothermal process (thermodynamics)
vapor pressure
kinetic molecular theory
32. Cells that convert electrical energy into chemical energy.
hydrolysis
electrolytic cells
positive
Avogrados law
33. The law stating that change in internal energy is equal to the difference between the energy supplied toi the system as heat and the energy removed from the system as work performed on the surroundings.
isothermal process (thermodynamics)
entropy
hydrolysis
first law of thermodynamics
34. *Molecules of ideal gases have no attraction for one another and have no intrinsic volume - they are ______ _____
Nernst equation
equivalent point
point particles
reversible
35. *The surface area exposed affect chemical reactions because most reactions depend on the reactants coming into contact - increasing the rate of the reaction.
double replacement/displacement
...
third law of thermodynamics
equation of state
36. In a closed system - when opposing changes are taking place at equal rates - the system is said to be in _____ _______.
state functions (thermodynamics)
boiling point
dynamic equilibrium
zero
37. For a solution in which a nonvolatile solute is dissolved in a solvent - the vapor pressure is due only to the vapor of the solvent above the solution. This vapor pressure is given by _______ law.
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38. A law stating that the vapor pressure of a solution at a particular temperature is equal to teh mole fraction of the solvent in the liquid phase multiplied by the vapor pressure of the pure solvent at the same temperature.
left (Le Chatelier's principle)
negative
Raoults law
heat capacity
39. A state function in which it is the heat content of a substance.
negative
Boyles law
enthalpy
saturated solution
40. A catalyst lowers the ______ _____ _____ that must be overcome in order for the reaction to proceed. It merely speeds the approach to equilibrium but does not change Keq at all.
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41. *The temperature affects chemical reactions with an increase of ___degrees C above room temperature - causing the reaction rate to double.
10 degrees
positive
electromotive force (emf)/ cell
melting point
42. *Each wave function corresponds to a certain electron energy and describes a region about the nucleus (orbital) where an electron having that energy may be found.
wave mechanical model
kinetic molecular theory
boiling point elevation
electrolytic cells
43. The amount of heat energy required to raise the temperature of a given quantity of a substance one degree celcius.
Raoult's law
second law of thermodynamics
heat capacity
catalysts
44. _______ has very little effect on the solubility of liquids or solids in liquid solvents.
hybridyzation
dynamic equilibrium
pressure
isothermal process (thermodynamics)
45. The average kinetic energy of all the molecules collectively is directly proportional to the absolute temperature of the gas. The average kinetic energy of equal numbers of molecules of any gas is the same at the same temperature.
single replacement/displacement
decreases
dynamic equilibrium
kinetic molecular theory
46. The ________ of an element is a number that measerures the relative strength in which the atoms of the element attract valence electrons in a chemical bond - on a scale of 0-4.
increases
...
electronegativity
equivalent point
47. An increase in temperature causes the position of equilibrium of an exothermic reaction to be shifted to the _____ - while that of and endothermic reactions is shifted to the _______.
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48. Decreasing the concentrations of reactants shifts the equilibrium to the ______ - thus decreasing the concentration of products formed.
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49. A pure crystal of elemental metal consists of roughly Avogrado's number of atoms held together by ________ bonds.
state functions (thermodynamics)
metallic
valence
VSEPR
50. In an endothermic process - energy is absorbed and ^E is _______.
...
positive
Van der Waals
Le Chatelier's principle
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