SUBJECTS
|
BROWSE
|
CAREER CENTER
|
POPULAR
|
JOIN
|
LOGIN
Business Skills
|
Soft Skills
|
Basic Literacy
|
Certifications
About
|
Help
|
Privacy
|
Terms
|
Email
Search
Test your basic knowledge |
GRE Chemistry Organic
Start Test
Study First
Subjects
:
gre
,
science
,
chemistry
Instructions:
Answer 50 questions in 15 minutes.
If you are not ready to take this test, you can
study here
.
Match each statement with the correct term.
Don't refresh. All questions and answers are randomly picked and ordered every time you load a test.
This is a study tool. The 3 wrong answers for each question are randomly chosen from answers to other questions. So, you might find at times the answers obvious, but you will see it re-enforces your understanding as you take the test each time.
1. Cis/trans Isomers
Acyl Chloride
Thioacetal
Geometrical isomer
Hg(OAc)2
2. Elimination to form alkene
1 -2 Dihalide + Zn
Pyridine
Geometrical isomer
Solvomercuration-demercuration
3. Anti-alignment required
Acyl Chloride
Oxidizes amine groups
E2 Elimination
Stereoisomers
4. Bound to adjacent atoms
Geminal
Vicinal
SN1
Tosylation
5. Reduces ketone to alkane
Clemmenson reaction
Saytzeff Product
Thioacetal
Benzene + CO + HCl (w/ AlCl3)
6. Highly reactive carbonyl
Acyl Chloride
Hg(OAc)2
Conformational Isomer
Clemmenson reaction
7. OCH3
Methoxy group
Meso compound
E2 Elimination
Stereoisomers
8. R-NH2 + NaNO2/HCl --> R-N=N+ Cl-
Geminal
RSH + KMnO4
Addition of Alkali Metal to alcohol
Diazotization
9. One carbon away from aryl group can be reduced with Pd / H2
Oxime
Enantiomer
Forms cyclopropane ring from alkene
Benzyl hydrogenolysis
10. Oxidize to -COOH
Nucleophilic Aromiatic Substitution
Birch reduction
Nucleophilic Addition
Chromic Acid
11. Ch2I2 - Zn(Cu)
NBS
KMnO4
Forms cyclopropane ring from alkene
Geminal
12. Aldehyde / ketone synthesis
Peroxyacid
Enantiomer
Anti-orientation
1 -3-dithiane + BuLi / R-OH
13. Reduces Ar-CH3 to -COOH
1 -2 Dihalide + Zn
SN1
KMnO4
C=O + Zn - Hg / HCl
14. Nucleophile adds to ketone (forming alcohol)
E2 Elimination
Pyridine
Nucleophilic Addition
O-P Directors
15. Donate electrons to aromatic ring
Methoxy group
O-P Directors
Acyl Chloride
Hg(OAc)2
16. CH2-
Conformational Isomer
Nitrile + H2O/H+
C=O + Zn - Hg / HCl
Oxirane
17. Reduces one bond of benzene ring
Anti-orientation
1 -3 Dihalide + Zn
Oxidizes amine groups
Birch reduction
18. Less substituted elimination; sterically hindered
Solvomercuration-demercuration
Hofmann Product
Enantiomer
Diazotization
19. Replaces thioacetal/ketal with carbonyl
RSH + KMnO4
H+ - HgCl2 - H2O
Aniline
Diazotization
20. Thionyl chloride
Peroxyacid
SOCl2
Acyl Chloride
1 -2 Dihalide + Zn
21. Uses Hg(OAc)2 + R'OH; forms ether from alkene
Solvomercuration-demercuration
Addition of Alkali Metal to alcohol
Methoxy group
Vicinal
22. Oxidize to -CHO
SN1
Methoxy group
Enantiomer
Pyridine
23. Less hindered carbon center; chiral inversion
Chromic Acid
SN2
Clemmenson reaction
Nucleophilic Addition
24. Ph-NH2
Hg(OAc)2
Methoxy group
HBr or HI cleavage
Aniline
25. Bound to same atom
Ozonolysis
Peroxyacid
Geminal
E1 Elimination
26. Alcohol closes ring to form oxirane
NBS
Halohydrin + Base
Benzene + CO + HCl (w/ AlCl3)
1 -2 Dihalide + Zn
27. 4-pi system + 2-pi system --> Ring formation
Oxirane
1 -3 Dihalide + Zn
Anti-orientation
Diels-Alder
28. R-SO3H
E1 Elimination
1 -3-dithiane + BuLi / R-OH
RSH + KMnO4
Stereoisomers
29. Benzaldehyde
1 -3 Dihalide + Zn
SN1
Benzene + CO + HCl (w/ AlCl3)
Nucleophilic Addition
30. Tertiary carbocation formed; relieved by deprotonation
1 -3 Dihalide + Zn
Meso compound
E1 Elimination
Clemmenson reaction
31. R2C=N-OH
Oxime
Conformational Isomer
Thioacetal
Methoxy group
32. H2O2
Vicinal
Oxidizes amine groups
Diazotization
Nucleophilic Aromiatic Substitution
33. Oxirane ring opening
O-P Directors
Anti-orientation
E1 Elimination
Forms cyclopropane ring from alkene
34. Non-superimposable mirror image
Solvomercuration-demercuration
Peroxyacid
Saytzeff Product
Enantiomer
35. Can protect a ketone
Diels-Alder
Thioacetal
SN2
Nucleophilic Aromiatic Substitution
36. Cycloformation
1 -2 Dihalide + Zn
H+ - HgCl2 - H2O
Conformational Isomer
1 -3 Dihalide + Zn
37. Attach tosyl group onto alcohol
SN1
Pyridine
Tosylation
H+ - HgCl2 - H2O
38. Differ in rotation about sigma bonds
Clemmenson reaction
Geminal
Conformational Isomer
Stereoisomers
39. Tertiary carbon center; racemic
SN1
Conformational Isomer
Methoxy group
1 -2 Dihalide + Zn
40. Cyclic ether
Oxirane
Saytzeff Product
Aniline
Conformational Isomer
41. Split an alkene into 2 carbonyls
Nitrile + H2O/H+
C=O + Zn - Hg / HCl
Thioacetal
Ozonolysis
42. More substituted elimination; more stable
SN2
Saytzeff Product
E1 Elimination
Oxidizes amine groups
43. Forms carboxylic acid; releases N
Thioacetal
Nitrile + H2O/H+
Diazotization
Constitutional Isomer
44. Differ in fixed geometrical arrangement of atoms
Nucleophilic Addition
Constitutional Isomer
Stereoisomers
Thioacetal
45. Chiral - with superimposable mirror image
Meso compound
KMnO4
Oxidizes amine groups
E2 Elimination
46. Splits an ether into alkyl halides
Solvomercuration-demercuration
Diazotization
Methoxy group
HBr or HI cleavage
47. Differ in position of atoms
Constitutional Isomer
SN1
E2 Elimination
Diazotization
48. Formation of ethoxide
SOCl2
Pyridine
Addition of Alkali Metal to alcohol
SN2
49. 2 Sulfide linkages in place of aldehyde
Addition of Alkali Metal to alcohol
Methoxy group
Hg(OAc)2
Thioacetal
50. Allylic Substitution
NBS
Oxime
Nitrile + H2O/H+
Enantiomer