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Test your basic knowledge |
GRE Chemistry Organic
Start Test
Study First
Subjects
:
gre
,
science
,
chemistry
Instructions:
Answer 50 questions in 15 minutes.
If you are not ready to take this test, you can
study here
.
Match each statement with the correct term.
Don't refresh. All questions and answers are randomly picked and ordered every time you load a test.
This is a study tool. The 3 wrong answers for each question are randomly chosen from answers to other questions. So, you might find at times the answers obvious, but you will see it re-enforces your understanding as you take the test each time.
1. Formation of ethoxide
Addition of Alkali Metal to alcohol
Enantiomer
Oxirane
Geminal
2. Elimination to form alkene
1 -2 Dihalide + Zn
Nucleophilic Aromiatic Substitution
Conformational Isomer
1 -3 Dihalide + Zn
3. Tertiary carbon center; racemic
1 -2 Dihalide + Zn
SN1
H+ - HgCl2 - H2O
Forms cyclopropane ring from alkene
4. Donate electrons to aromatic ring
O-P Directors
Nucleophilic Addition
Halohydrin + Base
SN1
5. One carbon away from aryl group can be reduced with Pd / H2
Benzyl hydrogenolysis
Nitrile + H2O/H+
Enantiomer
Solvomercuration-demercuration
6. Cyclic ether
Diazotization
HBr or HI cleavage
Oxirane
SN1
7. Differ in fixed geometrical arrangement of atoms
Methoxy group
HBr or HI cleavage
Forms cyclopropane ring from alkene
Stereoisomers
8. Ch2I2 - Zn(Cu)
Oxirane
Forms cyclopropane ring from alkene
Nitrile + H2O/H+
Benzyl hydrogenolysis
9. R2C=N-OH
Geminal
1 -2 Dihalide + Zn
Oxime
KMnO4
10. Best with electron withdrawing group ortho/para to substitution site
Birch reduction
Nucleophilic Aromiatic Substitution
Diazotization
SOCl2
11. Splits an ether into alkyl halides
Diels-Alder
HBr or HI cleavage
SN2
Nitrile + H2O/H+
12. H2O2
O-P Directors
Oxidizes amine groups
Anti-orientation
Addition of Alkali Metal to alcohol
13. Thionyl chloride
Ozonolysis
Hg(OAc)2
Oxirane
SOCl2
14. R-SO3H
Oxime
RSH + KMnO4
Meso compound
Geminal
15. Reduces Ar-CH3 to -COOH
KMnO4
SN2
Clemmenson reaction
Anti-orientation
16. Benzaldehyde
Methoxy group
Benzene + CO + HCl (w/ AlCl3)
Benzyl hydrogenolysis
Peroxyacid
17. Replaces thioacetal/ketal with carbonyl
H+ - HgCl2 - H2O
Saytzeff Product
Diazotization
Solvomercuration-demercuration
18. Oxidize to -COOH
HBr or HI cleavage
Chromic Acid
Methoxy group
Geometrical isomer
19. Cis/trans Isomers
Diels-Alder
Diazotization
Geometrical isomer
Nucleophilic Aromiatic Substitution
20. Oxidize to -CHO
Constitutional Isomer
Pyridine
Diels-Alder
Tosylation
21. 4-pi system + 2-pi system --> Ring formation
Diels-Alder
Ozonolysis
Addition of Alkali Metal to alcohol
Enantiomer
22. Non-superimposable mirror image
Stereoisomers
Enantiomer
E1 Elimination
SN2
23. Formation of salcohol from alkene
Halohydrin + Base
C=O + Zn - Hg / HCl
Hg(OAc)2
Oxidizes amine groups
24. Cycloformation
O-P Directors
1 -3 Dihalide + Zn
Acyl Chloride
Thioacetal
25. Can protect a ketone
Constitutional Isomer
Thioacetal
Peroxyacid
SN1
26. Oxirane ring opening
Diels-Alder
SOCl2
Vicinal
Anti-orientation
27. OCH3
Hg(OAc)2
Conformational Isomer
Methoxy group
Nitrile + H2O/H+
28. Nucleophile adds to ketone (forming alcohol)
Benzene + CO + HCl (w/ AlCl3)
Acyl Chloride
Nucleophilic Addition
RSH + KMnO4
29. Less substituted elimination; sterically hindered
Oxime
Oxirane
Tosylation
Hofmann Product
30. Bound to adjacent atoms
Thioacetal
Oxime
Anti-orientation
Vicinal
31. R-NH2 + NaNO2/HCl --> R-N=N+ Cl-
Diazotization
O-P Directors
Clemmenson reaction
Hg(OAc)2
32. Uses Hg(OAc)2 + R'OH; forms ether from alkene
Geminal
Solvomercuration-demercuration
Tosylation
1 -3 Dihalide + Zn
33. Reduces ketone to alkane
HBr or HI cleavage
Clemmenson reaction
Nitrile + H2O/H+
SN2
34. Less hindered carbon center; chiral inversion
Nucleophilic Addition
Enantiomer
SN2
Aniline
35. Anti-alignment required
Hofmann Product
Enantiomer
Oxidizes amine groups
E2 Elimination
36. More substituted elimination; more stable
Saytzeff Product
1 -2 Dihalide + Zn
Constitutional Isomer
Forms cyclopropane ring from alkene
37. 2 Sulfide linkages in place of aldehyde
Chromic Acid
Acyl Chloride
Thioacetal
Oxirane
38. Tertiary carbocation formed; relieved by deprotonation
Benzene + CO + HCl (w/ AlCl3)
Saytzeff Product
E1 Elimination
Clemmenson reaction
39. Reduces one bond of benzene ring
Birch reduction
Addition of Alkali Metal to alcohol
E1 Elimination
Aniline
40. Forms carboxylic acid; releases N
Nitrile + H2O/H+
C=O + Zn - Hg / HCl
Forms cyclopropane ring from alkene
Benzene + CO + HCl (w/ AlCl3)
41. Differ in rotation about sigma bonds
1 -3 Dihalide + Zn
RSH + KMnO4
Stereoisomers
Conformational Isomer
42. Aldehyde / ketone synthesis
1 -3-dithiane + BuLi / R-OH
Aniline
O-P Directors
Diazotization
43. Bound to same atom
Geminal
Aniline
NBS
Stereoisomers
44. Alcohol closes ring to form oxirane
SN1
Acyl Chloride
Halohydrin + Base
Birch reduction
45. CH2-
E1 Elimination
Benzyl hydrogenolysis
C=O + Zn - Hg / HCl
Solvomercuration-demercuration
46. Reacts with alkene to form oxirane
Oxirane
Constitutional Isomer
Peroxyacid
Enantiomer
47. Attach tosyl group onto alcohol
Tosylation
Aniline
SN2
E2 Elimination
48. Differ in position of atoms
Hg(OAc)2
Benzene + CO + HCl (w/ AlCl3)
Constitutional Isomer
Oxime
49. Allylic Substitution
NBS
Birch reduction
Halohydrin + Base
1 -3 Dihalide + Zn
50. Ph-NH2
Halohydrin + Base
Aniline
Tosylation
Benzene + CO + HCl (w/ AlCl3)